3739-64-8

Basic information

• Product Name: ALLYL BUTYL ETHER
• Synonyms: 3-Butoxy-1-propene;Ether, allyl butyl;BUTYL ALLYL ETHER;ALLYL N-BUTYL ETHER;ALLYL BUTYL ETHER;1-(allyloxy)butane;1-(2-Propenyloxy)butane;1-prop-2-enoxybutane
• CAS NO: 3739-64-8
• Molecular Formula: C₇H₁₄O
• Molecular Weight: 114.19
• EINECS: 223-122-8
• Product Categories: Allyl Monomers;Monomers;Polymer Science
• Mol File: 3739-64-8.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 117-118 °C
• Flash Point: 58 °F
• Appearance: /
• Density: 0.783 g/mL at 25 °C(lit.)
• Vapor Pressure: 19.1mmHg at 25°C
• Refractive Index: n20/D 1.406(lit.)
• BRN: 1699588
• CAS DataBase Reference: ALLYL BUTYL ETHER(CAS DataBase Reference)
• NIST Chemistry Reference: ALLYL BUTYL ETHER(3739-64-8)
• EPA Substance Registry System: ALLYL BUTYL ETHER(3739-64-8)

Safety Data

• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 16-26-36
• RIDADR: UN 3271 3/PG 2
• WGK Germany: 3
• HazardClass: 3.1
• PackingGroup: II
• Hazardous Substances Data: 3739-64-8(Hazardous Substances Data)

Usage

Purification Methods

Check the IR for the presence of OH str vibrations; if so then wash it well with H2O, dry it with CaCl2 and distil it through a good fractionating column. The liquid is an irritant. [Watanabe et al. J Org Chem 23 1666 1958, Schueler & Hanna J Am Chem Soc 73 3528 1951, Beilstein 1 IV 2084.]

InChI:InChI=1/C7H14O/c1-3-5-7-8-6-4-2/h4H,2-3,5-7H2,1H3

Upstream product

• 107-18-6 allyl alcohol 
• 71-36-3 butan-1-ol 
• 106-95-6 allyl bromide 
• 109-65-9 1-bromo-butane 
• 591-87-7 Allyl acetate 
• 32338-77-5 3-butoxypropyl-1,2-episulfide 
• 2426-08-6 glycidyl n-butyl ether 
• 15921-15-0 magnesium di-n-butanolate 
• 107-05-1 3-chloroprop-1-ene 
• 142-28-9 1,3-Dichloropropane 
• 10129-44-9 1-(prop-2-en-1-yl)-pyridinium bromide 
• 557-40-4 Allyl ether 
• 1826-67-1 vinyl magnesium bromide 
• 2351-69-1 1-(chloromethoxy)butane 

Downstream Products

• 6044-68-4 3,3-dimethoxyprop-1-ene 
• 106521-18-0 3-n-butyloxy-3-methoxy-1-propene 
• 6213-94-1 trimethylsiloxyethene 
• 50300-19-1 (Z)-1-trimethylsilyloxy-1-heptene 
• 76966-14-8 3-(trimethylsilyloxy)hept-1-ene 
• 123-86-4 acetic acid butyl ester 
• 431-03-8 dimethylglyoxal 
• 141-32-2 acrylic acid n-butyl ester 
• 71-36-3 butan-1-ol 
• 7748-07-4 butyl (1-propenyl) ether 
• 13002-10-3 propionaldehyde dibutylacetal 
• 60340-28-5 1-phenylhex-5-en-3-ol 
• 77383-06-3 2-phenylhex-5-en-3-ol 
• 80735-94-0 1-Phenyl-3-buten-1-ol 

Relevant articles and documents

Technological method for preparation of allyl ether compounds

The invention discloses a technological method for preparation of allyl ether compounds; the technological method can obtain the high-purity allyl ether compounds in low cost and high yield, has the advantages of high selectivity of the allyl ether compounds, less side reaction, easy separation and purification of the products, friendly technological process environment and the like, and is suitable for large-scale industrialized production.

1,3,2,4-diazadiphosphetidine-based phosphazane oligomers as source of P(III) atom economy reagents: Conversion of epoxides to vic -haloalcohols, vic -dihalides, and alkenes in the presence of halogen sources

1,3,2,4-Diazadiphosphetidines (P1-P3), as easily prepared, stable, and heterogeneous P(III) compounds, were used for the efficient conversion of epoxides to vic-halohydrins, vic-dihalides, or alkenes in the presence of different halogen sources in CH3CN. Of these phosphazanes, P3 is most suitable and contains 4 phosphorous atoms with the advantage of having greater atom economy and its phosphorus oxide byproduct can be easily separated from the reaction mixture by simple filtration. The nitrogen atoms in this molecule can also act as acid scavengers in the reaction.

Allylation of Alcohols and Carboxylic Acids with Allyl Acetate Catalyzed by [Ir(cod)2]+BF4- Complex

A facile method for the synthesis of allyl alkyl ethers from alcohols with allyl acetate was developed by the use of [Ir(cod)2] +BF4- complex. For instance, the reaction of allyl acetate with n-octyl alcohol in the presence of a catalytic amount of [Ir(cod)2]+BF4- complex afforded allyl octyl ether in quantitative yield. Allyl carboxylates were also prepared by the exchange reaction between carboxylic acids and allyl acetate in good yields. The [Ir(cod)2]+BF4- complex catalyzed the reaction of alkyl and aromatic amines with allyl acetate to lead to the corresponding allylamines in fair to good yields.