38282-01-8

Basic information

• Product Name: 2-Propen-1-amine, N,N-diethyl-3-phenyl-, (2E)-
• Synonyms: N-[(E)-3-phenyl-2-propenyl]diethylamine;(E)-Cinnamyldiethylamine;trans-Cinnamyl-diaethylamin;trans-3-diethylamino-1-phenylpropene
• CAS NO: 38282-01-8
• Molecular Formula: C13H19N
• Molecular Weight: 189.301
• Mol File: 38282-01-8.mol
• Article Data: 23

Chemical Properties

• CAS DataBase Reference: 2-Propen-1-amine, N,N-diethyl-3-phenyl-, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propen-1-amine, N,N-diethyl-3-phenyl-, (2E)-(38282-01-8)
• EPA Substance Registry System: 2-Propen-1-amine, N,N-diethyl-3-phenyl-, (2E)-(38282-01-8)

Safety Data

• Hazardous Substances Data: 38282-01-8(Hazardous Substances Data)

Upstream product

• 22396-72-1 diethyl-(3-phenyl-prop-2-ynyl)-amine 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 109-89-7 diethylamine 
• 4392-24-9 Cinnamyl bromide 
• 300-57-2 allylbenzene 
• 102-92-1 Cinnamoyl chloride 
• 27829-46-5 (E)-N,N-diethyl-3-phenylacrylamide 
• 106625-69-8 ethyl (E)-3-phenyl-2-propenyl carbonate 
• 1402556-66-4 [Pd(η¹-3-PhC3H4)(N,1-bis[2-(diphenylphosphino)phenyl]methanimine)]BF4 
• 764-42-1 1,2-Dicyanoethylene 
• 7217-71-2 1-phenyl-2-propenyl acetate 
• 536-74-3 phenylacetylene 
• 14371-10-9 (E)-3-phenylpropenal 
• 21040-45-9 Cinnamyl acetate 

Downstream Products

• 1205-84-1 ethyl (E)-4-phenylbut-3-enoate 
• 103896-68-0 (E)-N,N-diethyl-4-phenyl-3-butenamide 
• 3412-44-0 (1E)-1,3-diphenylpropene 
• 21924-11-8 1-(3-phenylpropanoyl)piperidine 
• 10264-10-5 N-benzyl-3-phenylpropanamide 
• 71231-24-8 N-(2-methylphenyl)-3-phenylpropanamide 
• 152189-81-6 N-(4-chlorophenyl)-3-phenylpropanamide 
• 3271-81-6 hydrocinnamanilide 
• 314284-69-0 1-(indolin-1-yl)-3-phenylpropan-1-one 
• 61751-42-6 N-benzyl-N-methyl-3-phenylpropionamide 
• 5830-31-9 N,N-dimethyl-3-phenylpropanamide 
• 61123-44-2 1-morpholino-4-phenylbutan-1-one 
• 17077-46-2 4-(3-phenyl-propionyl)-morpholine 

Relevant articles and documents

Functionalized hyperbranched grafts on polyethylene powder for support of Pd(0)-phosphine catalyst

Hyperbranched grafts of poly(acrylic acid) have been modified with phosphine ligands for support of Pd(0) for use in allylic substitution chemistry.

Terminally functionalized polyisobutylene oligomers as soluble supports in catalysis

A new phase selective hydrocarbon soluble polymer support is described.

C-N Bond Formation from Allylic Alcohols via Cooperative Nickel and Titanium Catalysis

Amination of allylic alcohols is facilitated via cooperative catalysis. Catalytic Ti(O-i-Pr)4 is shown to dramatically increase the rate of nickel-catalyzed allylic amination, and mechanistic experiments confirm activation of the allylic alcohol by titanium. Aminations of primary and secondary allylic alcohols are demonstrated with a variety of amine nucleophiles. Diene-containing substrates also cyclize onto the nickel allyl intermediate prior to amination, generating carbocyclic amine products. This tandem process is only achieved under our cooperative catalytic system.

Anti-Markovnikov rearrangement in sulfur mediated allylic C-H amination of olefins

Cationic rearrangement reactions usually follow Markovnikov's rule to give more substituted carbocations as stable intermediates. During our study on sulfur mediated allylic C-H amination of olefins, very rare cases of anti-Markovnikov rearrangement from secondary carbocations toward primary carbocations or primary triflates were observed.