38612-13-4

Basic information

• Product Name: 4-bromobenzyl benzoate
• Synonyms: 4-bromobenzyl benzoate
• CAS NO: 38612-13-4
• Molecular Weight: 291.144
• Mol File: 38612-13-4.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 4-bromobenzyl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-bromobenzyl benzoate(38612-13-4)
• EPA Substance Registry System: 4-bromobenzyl benzoate(38612-13-4)

Safety Data

• Hazardous Substances Data: 38612-13-4(Hazardous Substances Data)

Upstream product

• 532-32-1 sodium benzoate 
• 589-15-1 1-bromomethyl-4-bromobenzene 
• 1005-01-2 benzoic-acid-d1 
• 6274-57-3 (4-bromobenzyl)dimethylamine 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 65-85-0 benzoic acid 
• 873-75-6 4-bromobenzenemethanol 
• 614-16-4 Benzoylacetonitrile 
• 106-38-7 para-bromotoluene 
• 4393-06-0 1-Phenyl-2-propen-1-ol 
• 10533-83-2 N-benzoyl-N-methyl-4-methylbenzenesulfonamide 
• 85909-02-0 N-benzyl-N-(tert-butoxycarbonyl)-benzamide 
• 57477-93-7 hydrazone of p-bromobenzaldehyde 
• 100-53-8 phenylmethanethiol 

Downstream Products

• 1215298-35-3 methyl 2-ethoxy-1-({2′-[1-(phenylmethyl)-1H-tetrazol-5-yl][1,1′-biphenyl]-4-yl}methyl)-1H-benzimidazole-7-carboxylate 
• 1307853-85-5 1-{[(cyclohexyloxy)carbonyl]oxy}ethyl 1-({4-[2-(1-benzyl-1H-1,2,3,4-tetrazol-5-yl)phenyl]phenyl}methyl)-2-ethoxy-1H-1,3-benzodiazole-7-carboxylate 
• 145040-37-5 candesartan cilexetil 
• 137863-17-3 methyl N-((2’-(1H-tetrazol-5-yl)-[1,1’-biphenyl]-4-yl)methyl)-N-pentanoyl-L-valinate 
• 207400-81-5 (1-{[2′-(1-benzyl-1H-tetrazol-5-yl)-1,1′-biphenyl-4-yl]methyl}-2-butyl-4-chloro-1H-imidazol-5-yl)methanol 
• 1307853-80-0 methyl 2-(N-tert-butoxycarbonyl-N-{(2'-[1-benzyl-1H-tetrazol-5-yl]biphenyl-4-yl)methyl}amino)-3-nitrobenzoate 
• 1215298-30-8 methyl 2-[({2'-[1-benzyl-1H-tetrazol-5-yl]biphenyl-4-yl}methyl)amino]-3-nitrobenzoate 
• 1307853-81-1 methyl 2-[({2'-[1-benzyl-1H-tetrazol-5-yl]biphenyl-4-yl}methyl)amino]-3-aminobenzoate 

Relevant articles and documents

Catalytic conversion of ketones to esters: Via C(O)-C bond cleavage under transition-metal free conditions

The catalytic conversion of ketones to esters via C(O)-C bond cleavage under transition-metal free conditions is reported. This catalytic process proceeds under solvent-free conditions and offers an easy operational procedure, broad substrate scope with excellent selectivity, and reaction scalability. This journal is

Cesium Carbonate Catalyzed Esterification of N-Benzyl- N-Boc-amides under Ambient Conditions

We report a general activated amide to ester transformation catalyzed by Cs2CO3. Using this approach, esterification proceeds under relatively mild conditions and without the need for a transition metal catalyst. This method exhibits broad substrate scope and represents a practical alternative to existing esterification strategies. The synthetic utility of this protocol is demonstrated via the facile synthesis of crown ether derivatives and the late-stage modification of a representative natural product and several sugars in reasonable yields.

Copper-catalyzed cross-coupling of thiols, alcohols, and oxygen for the synthesis of esters

Copper-catalyzed, one-pot, three-component coupling reactions using thiols, alcohols, and oxygen to form a variety of esters in good yields were studied. In the presence of easily oxidized benzylic and allylic alcohols, thiols were selectively oxidized to form thionoesters, which underwent facile S/O exchange to afford esters. Thiols may be used as an alternative benzoyl source under mild aerobic conditions.