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2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole UV absorber UV-327

    Cas No: 3864-99-1

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  • 3864-99-1 Structure
  • Basic information

    1. Product Name: 2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole
    2. Synonyms: 2-(2’-hydroxy-3’,5’-ditertbutylphenyl)-5-chloro-benzotrizole;2-(5-chloro-2h-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)-pheno;4-di-tert-butyl-6-(5-chloro-2h-benzo-triazol-2-;Phenol,2-(5-chloro-2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)-;5-CHLORO-2-(3,5-DI-TERT-BUTYL-2-HYDROXYPHENYL)BENZOTRIAZOLE;2-(3,5-DI-TERT-BUTYL-2-HYDROXYPHENYL)-5-CHLORO-2H-BENZOTRIAZOLE;2-(3',5'-DI-TERT-BUTYL-2'-HYDROXYPHENYL)-5-CHLOROBENZOTRIAZOLE;2-(3,5-DI-TERT-BUTYL-2-HYDROXYPHENYL)-5-CHLOROBENZOTRIAZOLE
    3. CAS NO:3864-99-1
    4. Molecular Formula: C20H24ClN3O
    5. Molecular Weight: 357.88
    6. EINECS: 223-383-8
    7. Product Categories: Organics;Polymer Additives;Polymer Science;Stabilizers;Polymer Additives;Polymer Science
    8. Mol File: 3864-99-1.mol
  • Chemical Properties

    1. Melting Point: 150-153 °C(lit.)
    2. Boiling Point: 469.2 °C at 760 mmHg
    3. Flash Point: 234°C
    4. Appearance: /
    5. Density: 1,26 g/cm3
    6. Vapor Pressure: 2E-09mmHg at 25°C
    7. Refractive Index: 1.596
    8. Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
    9. Solubility: Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly)
    10. PKA: 9.23±0.48(Predicted)
    11. CAS DataBase Reference: 2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole(CAS DataBase Reference)
    12. NIST Chemistry Reference: 2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole(3864-99-1)
    13. EPA Substance Registry System: 2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)-5-chlorobenzotriazole(3864-99-1)
  • Safety Data

    1. Hazard Codes: Xi
    2. Statements: 36/37/38
    3. Safety Statements: 26-36
    4. RIDADR: 3077
    5. WGK Germany: 2
    6. RTECS: 3425000
    7. TSCA: Yes
    8. HazardClass: 9
    9. PackingGroup: N/A
    10. Hazardous Substances Data: 3864-99-1(Hazardous Substances Data)

3864-99-1 Usage

Uses

2,4-Di-tert-butyl-6-(5-chloro-2H-benzotriazol-2-yl)phenol is a UV absorber.

Check Digit Verification of cas no

The CAS Registry Mumber 3864-99-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,8,6 and 4 respectively; the second part has 2 digits, 9 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 3864-99:
(6*3)+(5*8)+(4*6)+(3*4)+(2*9)+(1*9)=121
121 % 10 = 1
So 3864-99-1 is a valid CAS Registry Number.
InChI:InChI=1/C20H24ClN3O/c1-19(2,3)12-9-14(20(4,5)6)18(25)17(10-12)24-22-15-8-7-13(21)11-16(15)23-24/h7-11,25H,1-6H3

3864-99-1 Well-known Company Product Price

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  • Aldrich

  • (423327)  2,4-Di-tert-butyl-6-(5-chloro-2H-benzotriazol-2-yl)phenol  98%

  • 3864-99-1

  • 423327-5G

  • 505.44CNY

  • Detail

3864-99-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-(3,5-Di-Tert-Butyl-2-Hydroxyphenyl)-5-Chlorobenzotriazole

1.2 Other means of identification

Product number -
Other names 2,4-Di-tert-butyl-6-(5-chloro-2-benzotriazolyl)phenol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3864-99-1 SDS

3864-99-1Synthetic route

2-nitro-4-chloro-2'-hydroxy-3',5'-di-tert-butylazobenzene
52184-29-9

2-nitro-4-chloro-2'-hydroxy-3',5'-di-tert-butylazobenzene

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
With hydrogen; potassium hydroxide; sodium hydroxide In 1,4-dioxane; water at 100℃; under 750.075 Torr; Autoclave;97.95%
With borane-ammonia complex In toluene at 50℃; for 5h;95.6%
With sodium hydroxide; thiourea dioxide In ethanol at 85 - 90℃; for 1h;80%
2-(6-chloro-1-oxido-2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)phenol
84755-45-3

2-(6-chloro-1-oxido-2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)phenol

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
With sodium hydroxide In tetrahydrofuran; water electrolysis, Pt cathode and anode;97%
With potassium hydroxide; lithium perchlorate In tetrahydrofuran; water at 20℃; Reduction; Electrolysis;97%
With sodium hydroxide; bakers' yeast In ethanol 1.) r.t., 30 min, 2.) 80-85 deg C, 24 h;89%
2,4-Di-tert-butyl-6-(4-chloro-2-nitro-phenylazo)-phenol
52184-29-9

2,4-Di-tert-butyl-6-(4-chloro-2-nitro-phenylazo)-phenol

A

2-(6-chloro-1-oxido-2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)phenol
84755-45-3

2-(6-chloro-1-oxido-2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)phenol

B

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
With sodium hydroxide; thiourea S,S-dioxide In water; isopropyl alcohol for 3h; Heating;A 0.3%
B 95%
With sodium hydroxide; Beakers' yeast In ethanol at 85℃; for 24h; Product distribution; various amounts of bakers' yeast and NaOH; various times; pH; reagents;A 29%
B 65%
C20H26ClN3O2

C20H26ClN3O2

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
With sodium phosphite; hydrogen; dibutylamine at 60℃; under 7500.75 Torr; for 12h; Reagent/catalyst; Temperature; Pressure; Autoclave;94.2%
C20H24ClN3O2

C20H24ClN3O2

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
With platinum on activated charcoal; hydrogen at 50 - 75℃; under 3750.38 - 6000.6 Torr; Autoclave;92.4%
2-Nitro-4-chloro-2'-hydroxy-3',5'-di-tert-butyl-azobenzene

2-Nitro-4-chloro-2'-hydroxy-3',5'-di-tert-butyl-azobenzene

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
With sodium hydroxide In tetrahydrofuran; water electrolysis, Pt cathode and anode;92%
With sodium hydroxide; zinc In water at 90℃; for 1h;90%
75%
With samarium diiodide In tetrahydrofuran for 2.7h; Ambient temperature;84 % Spectr.
Multi-step reaction with 2 steps
1: 0.4 M LiClO4 / methanol; CH2Cl2 / electrolysis, Pt cathode and anode using a devised H cell
2: 97 percent / 0.2 M NaOH / tetrahydrofuran; H2O / electrolysis, Pt cathode and anode
View Scheme
2,4-Di-tert-butyl-6-(4-chloro-2-nitro-phenylazo)-phenol
52184-29-9

2,4-Di-tert-butyl-6-(4-chloro-2-nitro-phenylazo)-phenol

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
With sodium hydroxide; bakers' yeast In ethanol 1.) r.t., 30 min, 2.) 80-85 deg C, 40 h;85%
With sodium hydroxide In isopropyl alcohol at 85℃; for 24h; Reduction; Cyclization; Irradiation;83%
Multi-step reaction with 2 steps
1: 29 percent / Beakers' yeast, aq. NaOH / ethanol / 24 h / 85 °C / various amounts of bakers' yeast and NaOH; various times; pH; reagents
2: 89 percent / aq. NaOH, bakers' yeast / ethanol / 1.) r.t., 30 min, 2.) 80-85 deg C, 24 h
View Scheme
Multi-step reaction with 2 steps
1: 85 percent / aq. NaOH, bakers' yeast / ethanol / 1.) r.t., 30 min, 2.) 80-85 deg C, 4 h
2: 89 percent / aq. NaOH, bakers' yeast / ethanol / 1.) r.t., 30 min, 2.) 80-85 deg C, 24 h
View Scheme
C20H24Cl2N2O

C20H24Cl2N2O

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
With sodium azide; triethylamine; copper(I) bromide In DMF (N,N-dimethyl-formamide) at 80℃; for 4h;84%
2-(5-chloro-1-oxido-2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)phenol
94102-13-3

2-(5-chloro-1-oxido-2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)phenol

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
With tributyl-amine; aluminum nickel In water; hydrogen; toluene79.2%
1,5-diazabicyclo [5.4.0] undecene

1,5-diazabicyclo [5.4.0] undecene

2-(5-chloro-1-oxido-2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)phenol
94102-13-3

2-(5-chloro-1-oxido-2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)phenol

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
With hydrogen; aluminum nickel In nitrogen; toluene79%
2-nitro-5-chloro-2'-hydroxy-3',5'-di-tert-butylazobenzene

2-nitro-5-chloro-2'-hydroxy-3',5'-di-tert-butylazobenzene

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
With samarium diiodide In tetrahydrofuran for 0.666667h; Ambient temperature;91 % Spectr.
2-nitro-4-chloro-2'-hydroxy-3',5'-di-tert-butylazobenzene
52184-29-9

2-nitro-4-chloro-2'-hydroxy-3',5'-di-tert-butylazobenzene

A

4-Chloro-1,2-phenylenediamine
95-83-0

4-Chloro-1,2-phenylenediamine

B

2-amino-4,6-di-tertbutylphenol
1643-39-6

2-amino-4,6-di-tertbutylphenol

C

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
With 2-bromo-2-nitropropane; zinc In methanol; dichloromethane for 4h; Ambient temperature;A n/a
B n/a
C 88 % Chromat.
2,4-di-tert-butyl-6-(5-chloro-2-nitro-phenylazo)-phenol

2,4-di-tert-butyl-6-(5-chloro-2-nitro-phenylazo)-phenol

A

4-Chloro-1,2-phenylenediamine
95-83-0

4-Chloro-1,2-phenylenediamine

B

2-amino-4,6-di-tertbutylphenol
1643-39-6

2-amino-4,6-di-tertbutylphenol

C

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
With 2-bromo-2-nitropropane; zinc In methanol; dichloromethane for 3.5h; Ambient temperature;A n/a
B n/a
C 79 % Chromat.
2,4-di-tert-butyl-6-(5-chloro-2-nitro-phenylazo)-phenol

2,4-di-tert-butyl-6-(5-chloro-2-nitro-phenylazo)-phenol

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
With sodium hydroxide; lithium perchlorate In tetrahydrofuran; water at 20℃; Cyclization; Electrolysis;98 % Chromat.
2,4-di-tert-Butylphenol
96-76-4

2,4-di-tert-Butylphenol

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 2.) 1N HCl, sodium lauryl sulfate / 1.) diazotation, 2.) 45 deg C, 6 h
2: 84 percent / glucose, 2N NaOH / ethanol / 1 h / Heating
3: 88 percent / Zn, 2N NaOH / ethanol / 1 h / Ambient temperature
View Scheme
4-Chloro-2-nitroaniline
89-63-4

4-Chloro-2-nitroaniline

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 2.) 1N HCl, sodium lauryl sulfate / 1.) diazotation, 2.) 45 deg C, 6 h
2: 84 percent / glucose, 2N NaOH / ethanol / 1 h / Heating
3: 88 percent / Zn, 2N NaOH / ethanol / 1 h / Ambient temperature
View Scheme
7H-benz[d,e]anthracene-7-one
82-05-3

7H-benz[d,e]anthracene-7-one

acetaldehyde
75-07-0

acetaldehyde

2-(5-chloro-1-oxido-2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)phenol
94102-13-3

2-(5-chloro-1-oxido-2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)phenol

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
With sodium hydroxide In methanol; water
With sodium hydroxide In methanol; water
diethylene glycol diethyl ether

diethylene glycol diethyl ether

2-Nitro-4-chloro-2'-hydroxy-3',5'-di-tert-butyl-azobenzene

2-Nitro-4-chloro-2'-hydroxy-3',5'-di-tert-butyl-azobenzene

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
With hydrogenchloride; sodium hydroxide; nitrogen; hydrazine hydrate In water
2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

methyl iodide
74-88-4

methyl iodide

2-[3,5-bis(1,1-dimethylethyl)-2-methoxyphenyl]-5-chloro-2H-benzotriazole
271788-60-4

2-[3,5-bis(1,1-dimethylethyl)-2-methoxyphenyl]-5-chloro-2H-benzotriazole

Conditions
ConditionsYield
With potassium carbonate In acetone at 45℃; for 72h;99.8%
2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

2-bromo-4-(tert-butyl)-6-(5-chloro-2H-benzo[d][1,2,3]triazol-2-yl)phenol

2-bromo-4-(tert-butyl)-6-(5-chloro-2H-benzo[d][1,2,3]triazol-2-yl)phenol

Conditions
ConditionsYield
With bromine; trifluoroacetic acid at 65℃; for 2h;99%
4-trifluoromethylphenylboronic acid
128796-39-4

4-trifluoromethylphenylboronic acid

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

C27H28F3N3O

C27H28F3N3O

Conditions
ConditionsYield
With O4P(3-)*3K(1+)*5H2O; tris(1-adamantyl)phosphine; C28H26N2O8Pd2S2; potassium tert-butylate In tetrahydrofuran at 70℃; for 5h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;96%
With O4P(3-)*3K(1+)*5H2O; tris(1-adamantyl)phosphine; {2-[((acetyl-κO)amino)phenyl-κC](tri-1-adamantylphosphine)palladium}(p-toluenesulfonate); potassium tert-butylate In tetrahydrofuran at 70℃; for 5h; Suzuki-Miyaura Coupling; Inert atmosphere;96%
di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

carbonic acid tert-butyl ester 2,4-di-tert-butyl-6-(5-chlorobenzotriazol-2-yl)phenyl ester

carbonic acid tert-butyl ester 2,4-di-tert-butyl-6-(5-chlorobenzotriazol-2-yl)phenyl ester

Conditions
ConditionsYield
With pyridine for 2h; Heating;93.4%
sodium tungstate

sodium tungstate

thiophenol
108-98-5

thiophenol

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

5-benzenesulfonyl-2-(2-hydroxy-3,5-di-tert-butylphenyl)-2H-benzotriazole

5-benzenesulfonyl-2-(2-hydroxy-3,5-di-tert-butylphenyl)-2H-benzotriazole

Conditions
ConditionsYield
With 1-methyl-pyrrolidin-2-one; hydrogenchloride; potassium hydroxide; formic acid; dihydrogen peroxide In methanol; 5,5-dimethyl-1,3-cyclohexadiene; water88.6%
zirconium(IV) tetraisopropoxide 2-propanol
14717-56-7

zirconium(IV) tetraisopropoxide 2-propanol

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

C80H92Cl4N12O4Zr
1491152-54-5

C80H92Cl4N12O4Zr

Conditions
ConditionsYield
In toluene at 70℃; for 36h; Schlenk technique; Inert atmosphere;84%
2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

2-(6-chloro-1-oxido-2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)phenol
84755-45-3

2-(6-chloro-1-oxido-2H-benzotriazol-2-yl)-4,6-bis(1,1-dimethylethyl)phenol

Conditions
ConditionsYield
With sodium hydroxide; thiourea dioxide In ethanol at 80℃; for 1h;80%
zirconium(IV) tetraisopropoxide 2-propanol
14717-56-7

zirconium(IV) tetraisopropoxide 2-propanol

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

C58H88Cl2N6O8Zr2
1491152-51-2

C58H88Cl2N6O8Zr2

Conditions
ConditionsYield
In toluene at -24℃; Schlenk technique; Inert atmosphere;80%
hafnium(IV) tert-butoxide

hafnium(IV) tert-butoxide

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

C80H92Cl4HfN12O4
1491152-57-8

C80H92Cl4HfN12O4

Conditions
ConditionsYield
In toluene at 70℃; for 24h; Schlenk technique; Inert atmosphere;79%
benzoyl chloride
98-88-4

benzoyl chloride

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

benzoic acid 2,4-di-tert-butyl-6-(5-chlorobenzotriazol-2-yl)phenyl ester

benzoic acid 2,4-di-tert-butyl-6-(5-chlorobenzotriazol-2-yl)phenyl ester

Conditions
ConditionsYield
With pyridine for 2h; Heating;77%
tantalum pentachloride
7721-01-9

tantalum pentachloride

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

C20H23Cl5N3OTa

C20H23Cl5N3OTa

Conditions
ConditionsYield
Stage #1: tantalum pentachloride; 2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol In toluene at 0℃; Inert atmosphere; Schlenk technique; Glovebox;
Stage #2: In toluene at 20℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox;
76%
niobium pentachloride
10026-12-7

niobium pentachloride

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

C20H23Cl5N3NbO

C20H23Cl5N3NbO

Conditions
ConditionsYield
Stage #1: niobium pentachloride; 2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol In toluene at 0℃; Inert atmosphere; Schlenk technique; Glovebox;
Stage #2: In toluene at 20℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox;
75%
2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

2-(2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3846-71-7

2-(2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
With sodium hydroxide; zinc In ethanol for 5h; Heating;73%
2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

2-(2'-hydroxy-phenyl)-5-chlorobenzotriazole
23624-49-9

2-(2'-hydroxy-phenyl)-5-chlorobenzotriazole

Conditions
ConditionsYield
With aluminium trichloride; nitromethane In toluene for 7h; Heating;71%
2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol
3864-99-1

2-(5'-chloro-2'H-benzotriazol-2'-yl)-4,6-di-tert-butylphenol

2-hydroxyethanethiol
60-24-2

2-hydroxyethanethiol

C22H29N3O2S

C22H29N3O2S

Conditions
ConditionsYield
With potassium iodide; potassium hydroxide In 1-methyl-pyrrolidin-2-one at 100℃; for 6h;43%

3864-99-1Relevant articles and documents

Preparation method of benzotriazole ultraviolet light absorber

-

Paragraph 0179; 0182-0183; 0193, (2021/04/14)

The invention relates to a preparation method of a benzotriazole ultraviolet absorbent. The method comprises the following steps: under the action of a magnesium oxide supported metal catalyst, carrying out transfer hydrogenation reaction on an azo intermediate shown in a formula I and a hydrogen donor to obtain a target product shown in a formula III. The method provided by the invention is small in catalyst dosage, the raw material conversion rate can reach 100%, and the target product selectivity is 90% or above.

NOVEL PROCEDURE FOR THE FORMATION OF 2H-BENZOTRIAZOLE BODIES AND CONGENERS

-

Page/Page column 26; 27; 33, (2020/07/05)

The present invention relates to a process for the preparation of 2H-benzotriazole compounds and congeners, novel 2H-benzotriazole compounds and congeners and their use as UV absorbers in coatings and bulk plastics.

A benzo triazole ultraviolet absorbing agent preparation method (by machine translation)

-

Paragraph 0062; 0063; 0064; 0065, (2018/06/15)

The invention discloses a benzo triazole ultraviolet absorbing agent preparation method, including the raw material compound and alkali is dissolved in the solvent, is configured to raw material is added to the reaction device; then the Fe3 O4 /Catalyst is added to the raw material liquid in the graphene, access hydrogen, keeping the pressure 0.1 - 5 mpa, temperature 40 - 120 °C; in the reaction process using high performance liquid chromatography to real-time monitoring of the reaction solution, after the reaction, cooling, the restoration of normal pressure and recovering the catalyst after treatment, be benzo triazole ultraviolet absorbent. The method of this invention simple process, environmental protection, low cost, mild reaction conditions, product yield and quality is high, is suitable for industrial production, Fe used therein3 O4 /Graphene catalyst economic and environmental protection, stable properties, is recycled. (by machine translation)

A benzotriazole compound synthesis method (by machine translation)

-

Paragraph 0041; 0042; 0043; 0044, (2018/03/26)

The invention discloses a synthetic method of a benzotriazoles compound. The synthetic method comprises the following steps: loading a bifunctional catalyst of hydrogenation-solid alkali into a fixed bed reactor; continuously leading a solution of a compound represented by the formula (I) into the fixed bed reactor, leading hydrogen, and performing heating; enabling the reaction liquid to continuously flow out from a lower end of the fixed bed reactor; cooling the effluent reaction liquid to the room temperature; performing gas-liquid separation, liquid filtration, and filtrate condensation to remove the solvent; and performing purification to obtain the benzotriazoles compound represented by the formula (II). The bifunctional catalyst of hydrogenation-solid alkali is adopted for catalytic hydrogenation to synthesize the benzotriazoles compound. The bifunctional catalyst has catalytic performance of solid alkali during catalytic hydrogenation, so that insufficient addition of alkali liquor is effectively avoided in the prior art. The bifunctional catalyst is high in catalytic activity and is convenient to recycle and reuse. Post-treatment of synthesizing the benzotriazoles compound is simplified, and the problem of environmental pollution resulting from post-treatment of the alkali liquor is effectively avoided. The synthetic method is efficient, and is low in cost and easy and simple to operate.

Preparation method of ultraviolet absorbent containing chlorobenzotriazole

-

Paragraph 0072-0097, (2017/07/20)

The invention relates to a preparation method of an ultraviolet absorbent containing chlorobenzotriazole. Azobenzene, sodium hydroxide and toluene are stirred and mixed, the temperature is controlled to 60-80 DEG C, water and hydrazine are dropwise added at a constant speed, heat preservation reaction is performed after the completion of dropping, hydrochloric acid is added to perform neutralization to reach the pH of 6-7 after completion of hydrazine reduction, washing is performed, and an oil phase, namely nitrogen oxide, is obtained; the nitrogen oxide solution, alkali, a framework nickel catalyst and a catalyst promoter sodium phosphite are put into an autoclave, and hydrogen is led to perform constant-pressure constant-temperature reaction after nitrogen displacement; after reaction is completed, reaction liquid filtration and washing are performed, an organic phase evaporated solvent is obtained, and recrystallization, filtration and drying are conducted on the methanol and toluene mixed solvent to obtain the ultraviolet absorbent containing chlorobenzotriazole. Compared with an existing synthetic method, the preparation method has the advantages of being good in reaction selectivity, inhibiting a dechlorination phenomenon in the hydrogenation process, producing few by-products and the like and meanwhile does not produce wastewater containing zinc and aluminum, subsequent processing is simple, and the 'three wastes' problem produced in the secondary reduction process is solved.

Preparation method of benzotriazole light stabilizer

-

Paragraph 0023; 0024, (2017/01/17)

The invention discloses a preparation method of a benzotriazole ultraviolet light stabilizer. The method comprises the following steps: adding an azo dye intermediate represented by formula I to hydrazine hydrate, carrying out reduction to form an intermediate nitrogen oxide represented by formula II, and reducing the intermediate nitrogen oxide represented by formula II with hydrogen to prepare the benzotriazole ultraviolet light stabilizer represented by formula III, wherein the formula I, the formula II and the formula III are respectively shown in the description, and R in the formulas is C(CH3)3 or CH3. The preparation method allows wastewater generated in the invention to be environmentally-friendly.

Preparation of 2-aryl-2H-benzotriazoles by zinc-mediated reductive cyclization of o-nitrophenylazophenols in aqueous media without the use of organic solvents

Liu, Guo-Bin,Zhao, Hong-Yun,Yang, Hong-Jie,Gao, Xiang,Li, Miao-Kui,Thiemann, Thies

, p. 1637 - 1640 (2008/02/11)

Zinc powder-mediated reductive cyclization of o-nitrophenylazophenols in alkaline solution affords the corresponding 2-aryl-2H-benzotriazoles in high yields under mild reaction conditions. No organic solvents are used in the reaction and only minimal amounts in the work-up.

Process for the preparation of benzotriazoles

-

Page 12, (2010/02/05)

A process for the preparation of compounds of formula (I): wherein the general symbols are as defined in claim 1, which comprises reacting a compound of formula (V): wherein R1, R2, R3, R4, R5, R6, R7, R8, R9 and R18 are as defined in claim 1, and R18 is especially nitro, chlorine or bromine, with an azide compound of formula (IX): wherein M and n are as defined in claim 1, especially with sodium azide.

Processes for the preparation of benzotriazole UV absorbers

-

, (2008/06/13)

Provided is a process for preparing 2H-benzotriazole UV absorbers containing a perfluoroalkyl moiety at the 5-position of the benzo ring, for example a trifluoromethyl group, which involves diazotizing the perfluoroalkyl substituted o-nitroaniline using concentrated sulfuric acid plus sodium nitrite or nitrosylsulfuric acid to form the corresponding monoazobenzene intermediate via the diazonium salt intermediate which is reduced to the corresponding 5-perfluoroalkyl substituted 2H-benzotriazole UV absorber compound by conventional reduction means. Also provided is a novel one-pot, multiphase reaction for the preparation of 2(2-nitrophenylazo) substituted phenols, which are precursors for 2H-benzotriazole UV absorbers.

2-(2′-hydroxyphenyl)benzotriazoles used as U.V. stabilizers

-

, (2008/06/13)

2-(2′-hydroxyphenyl)benzotriazoles having general formula (I). The above 2-(2′-hydroxyphenyl)benzotriazoles are useful as light stabilizers for organic polymers.

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