14717-56-7

Basic information

• Product Name: ZIRCONIUM(IV) ISOPROPOXIDE ISOPROPANOL
• Synonyms: ZIRCONIUM(IV) ISOPROPOXIDE ISOPROPANOL;ZIRCONIUM(IV) ISOPROPOXIDE ISOPROPANOL C OMPLEX, 99.9%;Zirconium(IV)i-propoxide(isopropanoladduct)(99.9%-Zr);Zirconium(Ⅳ) Isopropoxide isopropanol complex;Zirconium(IV) isopropoxide isopropanol adduct;Isopropanoltetrakis(isopropanolato)zirconium;Isopropyl alcohol compd. with zirconium isopropoxide;ZirconiuM(IV) isopropoxide isopropanol coMplex 99.9% trace Metals basis
• CAS NO: 14717-56-7
• Molecular Formula: C₁₅H₃₆O₅Zr
• Molecular Weight: 387.668
• EINECS: 218-522-4
• Product Categories: Micro/Nanoelectronics;Solution Deposition Precursors;Zirconium;metal alkoxide
• Mol File: 14717-56-7.mol
• Article Data: 1

Chemical Properties

• Appearance: white/crystal
• Solubility: Soluble in hot isopropanol, warm hexane and toluene. Tends to pr
• Sensitive: Moisture Sensitive
• CAS DataBase Reference: ZIRCONIUM(IV) ISOPROPOXIDE ISOPROPANOL(CAS DataBase Reference)
• NIST Chemistry Reference: ZIRCONIUM(IV) ISOPROPOXIDE ISOPROPANOL(14717-56-7)
• EPA Substance Registry System: ZIRCONIUM(IV) ISOPROPOXIDE ISOPROPANOL(14717-56-7)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• RIDADR: UN3180
• WGK Germany: 3
• HazardClass: 4.1
• PackingGroup: II
• Hazardous Substances Data: 14717-56-7(Hazardous Substances Data)

Usage

Uses

Different sources of media describe the Uses of 14717-56-7 differently. You can refer to the following data:
1. Zirconium(IV) Isopropoxide Isopropanol Complex are efficient and good catalysts for the ring-opening polymerization of rac-lactides and ε-caprolactone as well as δ-valerolactone, rac-β-butyrolactone, ethylene and propylene.
2. Convenient precursor for the synthesis of olefin-functionalized zirconium-containing monomers, which have potential for the generation of hybrid zirconium-containing polymers.

Synthetic route

zirconium(IV) chloride (10026-11-6) + isopropyl alcohol (67-63-0) → zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7)

Conditions	Yield
In not given N2 atmosphere;

zirconium (7440-67-7) + isopropyl alcohol (67-63-0) → zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7)

Conditions	Yield
In isopropyl alcohol according Shreider, Turevskaya, Kozlova, Turova; Izv. Akad. Nauk SSR. Ser. Khim., No.8, 1687-1692 (1981);; recrystd. in i-PrOH;;;
In not given Electrolysis; Zr anode, Zr cathode, Ar-atmosphere, stirring, 110 V/0.23 A, 15 h; soln.contg. various salts (Bu4NBr, Bu4NBF4, NaBr or other); crystn. on cooling; elem. anal.;
With Bu4NBr In neat (no solvent) byproducts: H2; Electrochem. Process; Ar, at 110 V for 15 h; recrystd. from alcohol; elem. anal.;
With LiCl In isopropyl alcohol Electrochem. Process; anodic dissoln. in anhyd. alcohol (supporting electrolyte LiCl), according to: V. A. Shreider, E. P. Turevskaya, N. I. Kozlova, N. Ya. Turova, Inorg. Chim. Acta 53 (1981) 73; recrystn. (isopropanol);

2-Hydroxymethylpyridine (586-98-1) + zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) → C18H26N2O4Zr (1346523-15-6)

Conditions	Yield
In cyclohexane at 20℃; Schlenk technique; Inert atmosphere;	100%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + tris(tert-butoxy)silanol (18166-43-3) → [Zr(O-i-Pr)3(OSi(O-t-Bu)3)] (1392309-85-1)

Conditions	Yield
In benzene soln. (HOSi(O-t-Bu)3) in benzene was added to soln.(Zr(O-i-Pr)4*i-PrOH) in benzene (1:1), refluxed for 4 h; react. mixt. was concd. in vacuo; elem. anal.;	99%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + tris(tert-butoxy)silanol (18166-43-3) → [Zr(O-i-Pr)2(OSi(O-t-Bu)3)2] (36809-78-6)

Conditions	Yield
In benzene soln. (HOSi(O-t-Bu)3) in benzene was added to soln.(Zr(O-i-Pr)4*i-PrOH) in benzene (2:1), refluxed for 8 h; react. mixt. was concd. in vacuo; elem. anal.;	99%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + C34H55NO2 (1421333-41-6) → C40H67NO4Zr (1443147-83-8)

Conditions	Yield
In diethyl ether at -35 - 20℃; for 2h; Inert atmosphere; Schlenk technique; Glovebox;	99%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + C33H53NO2 (1304495-31-5) → C42H74NO5Zr (1443147-85-0)

Conditions	Yield
In diethyl ether at -35 - 0℃; for 2h; Inert atmosphere; Glovebox; Schlenk technique;	99%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + Hf(OiPr)4·HOiPr (1070655-38-7) → C42H74HfNO5 (1443147-87-2)

Conditions	Yield
In diethyl ether at -35 - 0℃; for 4h; Inert atmosphere; Glovebox; Schlenk technique;	99%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + triethanolamine (102-71-6) → zirconium bis(triethanolaminate) (151767-62-3)

Conditions	Yield
In benzene byproducts: i-PrOH; 2 equiv. of triethanolamine was added to C6H6 soln. of Zr-complex, reflux for 12 h with recovering of i-PrOH as azeotrope; mixt. was allowed to stand to room temp., volatiles were removed in vac., elem. anal.;	97%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + furan-2-carboxylic acid (444777-27-9) → Zr(4+)*3C4H5OCOO(1-)*(CH3)2CHO(1-)=Zr(C4H5OCOO)3(OCH(CH3)2)

Conditions	Yield
In benzene byproducts: iPrOH; to soln. of Zr compd. ligand added (1:3), refluxed for 8 h; stood, washed with EtOH, dried (E-2 torr, 4 h); elem. anal.;	96%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + furan-2-carboxylic acid (444777-27-9) → Zr(4+)*C4H5OCOO(1-)*3(CH3)2CHO(1-)=Zr(C4H5OCOO)(OCH(CH3)2)3

Conditions	Yield
In benzene byproducts: iPrOH; to soln. of Zr compd. ligand added (1:1), refluxed for 6 h; stood, washed with EtOH, dried (E-2 torr, 4 h); elem. anal.;	96%

indole-3-acetic acid (87-51-4) + zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) → Zr(4+)*2C8H6NCH2COO(1-)*2(CH3)2CHO(1-)=Zr(C8H6NCH2COO)2((CH3)2CHO)2

Conditions	Yield
In benzene byproducts: iPrOH; to soln. of Zr compd. ligand added (1:2), refluxed for 6 h; stood, washed with EtOH, dried (E-2 torr, 4 h); elem. anal.;	94%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + 4-Methylbenzyl alcohol (589-18-4) → [Zr(O-CH2-4-MeC6H4)4]2 (1266659-65-7)

Conditions	Yield
In toluene byproducts: isopropanol; Schlenk techniques or glovebox used under Ar, soln. of Zr(O-iPr)4(HO-iPr) (0.26 mmol) in toluene added to soln. of 4-MeC6H4CH2OH (1.03 mmol) in toluene at -25 °C, allowed to reach ambient temp., stirred for 24h; solvent removed under vac., crystd. from toluene at -25 °C, filtrated, dried in vac.; elem. anal.;	93%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + 2-amino-3-((E)-(3-(tert-butyl)-2-hydroxy-5-methylbenzylidene)amino)maleonitrile → C44H60N8O6Zr2

Conditions	Yield
In toluene at 20℃; for 24h; Inert atmosphere;	93%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + 2-[(2,6-diisopropylphenyl)imino]methyl-4,6-dibromophenole (210882-81-8) → C44H54Br4N2O4Zr

Conditions	Yield
In toluene at -25 - 20℃; for 30h; Glovebox; Inert atmosphere;	92%

Pentachlorophenol (87-86-5) + zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) → [Zr(O-C6Cl5)4(HO-iPr)]2 (1266659-63-5)

Conditions	Yield
In toluene byproducts: isopropanol; Schlenk techniques or glovebox used under Ar, soln. of Zr(O-iPr)4(HO-iPr) (0.26 mmol) in toluene added to soln. of C6Cl5OH (1.03 mmol) in toluene at -25 °C, allowed to reach ambient temp., stirred for 24 h; solvent removed under vac., crystd. from toluene at -25 °C, filtrated, dried in vac.; elem. anal.;	91%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + 4-Iodophenol (540-38-5) → [Zr(O-4-IC6H4)4(HO-iPr)]2 (1266659-61-3)

Conditions	Yield
In toluene byproducts: isopropanol; Schlenk techniques or glovebox used under Ar, soln. of Zr(O-iPr)4(HO-iPr) (0.26 mmol) in toluene added to soln. of 4-IC6H4OH (1.03 mmol) in toluene at -25 °C, allowed to reach ambient temp., stirred for 24 h; solvent removed under vac., crystd. from toluene at -25 °C, filtrated, dried in vac.; elem. anal.;	91%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + furan-2-carboxylic acid (444777-27-9) → Zr(4+)*2C4H5OCOO(1-)*2(CH3)2CHO(1-)=Zr(C4H5OCOO)2(OCH(CH3)2)2

Conditions	Yield
In benzene byproducts: iPrOH; to soln. of Zr compd. ligand added (1:2), refluxed for 6 h; stood, washed with EtOH, dried (E-2 torr, 4 h); elem. anal.;	90%

indole-3-acetic acid (87-51-4) + zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) → Zr(4+)*3C8H6NCH2COO(1-)*(CH3)2CHO(1-)=Zr(C8H6NCH2COO)3((CH3)2CHO)

Conditions	Yield
In benzene byproducts: iPrOH; to soln. of Zr compd. ligand added (1:3), refluxed for 8 h; stood, washed with EtOH, dried (E-2 torr, 4 h); elem. anal.;	90%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + 4-indol-3-yl-butyric acid (133-32-4) → Zr(4+)*3C8H6N(CH2)3COO(1-)*(CH3)2CHO(1-)=Zr(C8H6N(CH2)3COO)3((CH3)2CHO)

Conditions	Yield
In benzene byproducts: iPrOH; to soln. of Zr compd. ligand added (1:3), refluxed for 10 H; stood, washed with EtOH, dried (E-2 torr, 4 h); elem. anal.;	90%

4-Fluorophenol (371-41-5) + zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) → [Zr(O-4-FC6H4)4(HO-iPr)]2 (1266659-60-2)

Conditions	Yield
In toluene byproducts: isopropanol; Schlenk techniques or glovebox used under Ar, soln. of Zr(O-iPr)4(HO-iPr) (0.26 mmol) in toluene added to soln. of 4-FC6H4OH (1.03 mmol) in toluene at -25 °C, allowed to reach ambient temp., stirred for 24 h; solvent removed under vac., crystd. from toluene at -25 °C, filtrated, dried in vac.; elem. anal.;	90%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + 2-fluorophenol (367-12-4) → [Zr(O-2-FC6H4)4(HO-iPr)]2 (1266659-53-3)

Conditions	Yield
In toluene byproducts: isopropanol; Schlenk techniques or glovebox used under Ar, soln. of Zr(O-iPr)4(HO-iPr) (0.26 mmol) in toluene added to soln. of 2-FC6H4OH (1.03 mmol) in toluene at -25 °C, allowed to reach ambient temp., stirred for 24 h; solvent removed under vac., crystd. from toluene at -25 °C, filtrated, dried in vac.; elem. anal., XRD;	90%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + 2-amino-3-((E)-(2-hydroxy-3,5-dimethylbenzylidene)amino)maleonitrile → C38H48N8O6Zr2

Conditions	Yield
In toluene at 20℃; for 24h; Inert atmosphere;	90%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + para-tert-butylphenol (98-54-4) → [Zr(O-4-tBuC6H4)4]2 (1266659-59-9)

Conditions	Yield
In toluene byproducts: isopropanol; Schlenk techniques or glovebox used under Ar, soln. of Zr(O-iPr)4(HO-iPr) (0.26 mmol) in toluene added to soln. of 4-tBuC6H4OH (1.03 mmol) in toluene at -25 °C, allowed to reach ambient temp., stirred for 24 h; solvent removed under vac., crystd. from toluene at -25 °C, filtrated, dried in vac.; elem. anal.;	89%

p-cresol (106-44-5) + zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) → [Zr(O-4-MeC6H4)4]2

Conditions	Yield
In toluene byproducts: isopropanol; Schlenk techniques or glovebox used under Ar, soln. of Zr(O-iPr)4(HO-iPr) (0.26 mmol) in toluene added to soln. of 4-MeC6H4OH (1.03 mmol) in toluene at -25 °C, allowed to reach ambient temp., stirred for 24 h; solvent removed under vac., crystd. from toluene at -25 °C, filtrated, dried in vac.; elem. anal.;	89%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + 4-indol-3-yl-butyric acid (133-32-4) → Zr(4+)*C8H6N(CH2)3COO(1-)*3(CH3)2CHO(1-)=Zr(C8H6N(CH2)3COO)((CH3)2CHO)3

Conditions	Yield
In benzene byproducts: iPrOH; to soln. of Zr compd. ligand added (1:1), refluxed for 8 h; stood, washed with EtOH, dried (E-2 torr, 4 h); elem. anal.;	88%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + 4-Methoxybenzyl alcohol (105-13-5) → [Zr(O-CH2-4-OMeC6H4)4]2 (1266659-66-8)

Conditions	Yield
In toluene byproducts: isopropanol; Schlenk techniques or glovebox used under Ar, soln. of Zr(O-iPr)4(HO-iPr) (0.26 mmol) in toluene added to soln. of 4-MeOC6H4CH2OH (1.03 mmol) intoluene at -25 °C, allowed to reach ambient temp., stirred for 2 4 h; solvent removed under vac., crystd. from toluene at -25 °C, filtrated, dried in vac.; elem. anal.;	88%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + 3-Trifluoromethylphenol (98-17-9) → [Zr(O-3-CF3C6H4)4(HO-iPr)]2 (1266659-57-7)

Conditions	Yield
In toluene byproducts: isopropanol; Schlenk techniques or glovebox used under Ar, soln. of Zr(O-iPr)4(HO-iPr) (0.26 mmol) in toluene added to soln. of 3-CF3C6H4OH (1.03 mmol) in toluene at -25 °C, allowed to reach ambient temp., stirred for 24 h; solvent removed under vac., crystd. from toluene at -25 °C, filtrated, dried in vac.; elem. anal.;	88%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + 2-monochlorophenol (95-57-8) → [Zr(O-2-ClC6H4)4(HO-iPr)]2 (1266659-54-4)

Conditions	Yield
In toluene byproducts: isopropanol; Schlenk techniques or glovebox used under Ar, soln. of Zr(O-iPr)4(HO-iPr) (0.26 mmol) in toluene added to soln. of 2-ClC6H4OH (1.03 mmol) in toluene at -25 °C, allowed to reach ambient temp., stirred for 24 h; solvent removed under vac., crystd. from toluene at -25 °C, filtrated, dried in vac.; elem. anal., XRD;	88%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + (2Z)-2-Amino-3-{[(1E)-(2-hydroxyphenyl)methylidene]-amino}but-2-enedinitrile (946529-82-4) → C34H40N8O6Zr2

Conditions	Yield
In toluene at 20℃; for 24h; Inert atmosphere;	88%

zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) + 2-(((3,5-di-tert-butyl-2-hydroxybenzyl)(2-hydroxyethyl)amino)methyl)-4,6-di-tert-butylphenol (910613-45-5) + toluene (108-88-3) → C70H110N2O8Zr2*C7H8

Conditions	Yield
for 12h; Glovebox; Schlenk technique; Inert atmosphere;	87.5%

2,5-dimethyl-2,5-hexanediol (110-03-2) + zirconium(IV) tetraisopropoxide 2-propanol (14717-56-7) → Zr(O(CH3)2CCH2CH2C(CH3)2O)(O(CH3)2CCH2CH2C(CH3)2OH)2

Conditions	Yield
In benzene byproducts: isopropyl alcohol; to a benzene soln. of Zr(OPr-i)4 was added a soln. of glycol in benzene,the mixt. was refluxed for 12 h, cooled to room temp.; isopropanol was sepd. during the reaction azeotropically, the volatiles were removed at room temp. under reduced pressure, recrystd. from toluene-hexane at -20°C; elem. anal.;	87%

Upstream product

• 10026-11-6 zirconium(IV) chloride 
• 67-63-0 isopropyl alcohol 
• 7440-67-7 zirconium 

Downstream Products

• 7440-67-7 zirconium(IV) oxide 
• 131135-98-3 triisopropoxy(1,3-dihydro-1,3-dioxo-α(benzyl)-2H-isoindole-2-acetato)zirconium (IV) 
• 151041-49-5 {Zr(OCH(CH₃)2)2(O(CH(CH₃)2)2C₆H₃)2} 
• 74437-17-5 Zr(isopropanolate)3(ethyl-β-oxy-β-phenylpropionate) 
• 74437-18-6 Zr(isopropanolate)2(ethyl-β-oxy-β-phenylpropionate)2 
• 74437-20-0 Zr(ethyl-β-oxy-β-phenylpropionate)4 
• 74437-19-7 Zr(isopropanolate)(ethyl-β-oxy-β-phenylpropionate)3 
• 74437-23-3 Zr(isopropanolate)(ethyl-β-oxy-β-phenylbutyrate)3 
• 74437-24-4 Zr(ethyl-β-oxy-β-phenylbutyrate)4 
• 74437-22-2 Zr(isopropanolate)2(ethyl-β-oxy-β-phenylbutyrate)2 

Relevant articles and documents

Preparation and Properties of Novel Titanio- and Zirconiosiloxane Compounds

Syntheses and characterization of titaniosiloxane and zirconiosiloxane compounds were investigated.Titaniosiloxane and zirconiosiloxane compounds were prepared by the reaction of di-t-butoxymethoxysilanol with titanium or zirconium alkoxides.DBMS was subjected to the reaction with bis(acetylacetonato)titanium diisopropoxide and titanium tetraisopropoxide to give titaniosiloxane compounds TS12 and TS14, respectively.Titaniosiloxane compounds were isolated by distillation or sublimation.TS12 was estimated to be cis-form from its 13C NMR spectrum in CDCl3.TS14 was stable in solution, but apt to decompose after isolation.ZS12 and ZS14 were prepared by the reaction of DBMS with bis(acetylacetonato)zirconium diisopropoxide and zirconium tetraisopropoxide, respectively.The isolation of ZS12 and ZS14 by distillation or recrystallization was difficult because of decomposition and high solubility, and the formation of ZS12 and ZS14 was confirmed by 1H, 13C, and 29Si NMR and IR spectra.