38862-78-1Relevant academic research and scientific papers
A novel method for the synthesis of dichloroalkenes
Nenajdenko,Shastin,Muzalevskii,Balenkova
, p. 2647 - 2649 (2004)
A novel convenient method for the synthesis of dichloroalkenes was developed. The method involves catalytic olefination of hydrazones of aliphatic carbonyl compounds with bromo(trichloro)methane.
Electrochemical Wittig reaction. Part I. Synthesis of gem-dichloroalkenes
Jubault, Philippe,Feasson, Christian,Collignon, Noel
, p. 1001 - 1006 (2007/10/02)
Two-electron electrochemical reduction of trichloromethyl tris(dimethylamino)phosphonium tetrafluoroborate led to dichloromethylene tris(dimethylamino)phosphorane, which was reacted with an aromatic or aliphatic aldehyde, to give gem-dichloroalkenes in go
The electrochemical Wittig-Horner reaction; evidence of a stepwise cleavage of a four-membered ring Wittig intermediate
Tilborg, W. J. M. van,Smit, C. J.
, p. 202 - 206 (2007/10/02)
Electro-reduction of diethyl(trichloromethyl)phosphonate in the presence of aldehydes or ketones relpaces the oxygen atom of the carbonyl group by a dichloromethylene group.The yield of 1,1-dichloroethene product decreases subtantially if the carbonyl com
