3975-14-2Relevant articles and documents
Process for continuously preparing acetals of alpha, beta-dicarbonyl compounds
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Page 3, (2008/06/13)
The present invention relates to a process for preparing acetals of α,β-dicarbonyl compounds of the general formula (R″O)2CRCR′(OR″)2 which are obtained by continuous reaction of α,β-dicarbonyl compounds R—CO—CO—R′ with alcohols R″OH or HO—X—OH in countercurrent.
THE MONOACETALIZATION OF GLYOXAL: A DIRECT SYNTHESIS OF 2,2-DIMETHOXY AND DIETHOXY ETHANALS
Sangsari, Farid Hamedi,Chastrette, Francine,Chastrette, Maurice
, p. 1343 - 1348 (2007/10/02)
Direct monoacetalization of glyoxal by methanol or ethanol is described.Yields of 50 to 70percent are obtained.
DISSYMETRATION DE LA MOLECULE DU GLYOXAL 1-SYNTHESE ET REACTIVITE DE L'ACETOXY-1 TRIETHOXY-1,2,2 ETHANE
Stambouli, A.,Chastrette, F.,Amouroux, R.,Chastrette, M.,Mattioda, G.,Blanc, A.
, p. 4149 - 4152 (2007/10/02)
Acetoxy-1 triethoxy-1,2,2 ethane, a dissymetric derivative of glyoxal, is prepared and reacted with various bases and nucleophiles, as amines, cyanotrimethylsilane, organometallic and WITTIG reagents.Various acetals are obtained, leading to α-fonctionalized aldehydes.