4115-33-7

Basic information

• Product Name: N-thiobenzoyl benzamidine
• Synonyms: N-thiobenzoyl benzamidine
• CAS NO: 4115-33-7
• Molecular Weight: 240.329
• Mol File: 4115-33-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-thiobenzoyl benzamidine(CAS DataBase Reference)
• NIST Chemistry Reference: N-thiobenzoyl benzamidine(4115-33-7)
• EPA Substance Registry System: N-thiobenzoyl benzamidine(4115-33-7)

Safety Data

• Hazardous Substances Data: 4115-33-7(Hazardous Substances Data)

Upstream product

• 637-51-4 isothiocyanatobenzene 
• 100-47-0 benzonitrile 
• 637-53-6 thioacetanilide 
• 860723-67-7 N-(naphthalen-2-yl)benzothioamide 
• 96963-47-2 N-(naphthalen-1-yl)benzothioamide 
• 2227-79-4 benzenecarbothioamide 
• 7791-25-5 sulfuryl dichloride 
• 60-29-7 diethyl ether 
• 56-23-5 tetrachloromethane 
• 10028-15-6 ozone 
• 7647-01-0 hydrogenchloride 
• 10319-80-9 thioacetic acid 1-naphthyl amide 
• 99988-93-9 thioacetic acid 2-naphthylamide 
• 507-09-5 thioacetic acid 

Downstream Products

• 4476-07-7 bis-benzimidoyl-amine 
• 4115-15-5 3,5-diphenyl-[1,2,4]thiadiazole 
• 4194-36-9 N-<(Phenylthioxo)-methyl>benzamide 

Relevant articles and documents

Aerobic Visible-Light Induced Intermolecular S?N Bond Construction: Synthesis of 1,2,4-Thiadiazoles from Thioamides under Photosensitizer-Free Conditions

Aerobic visible-light induced intermolecular S?N bond construction has been achieved without the addition of photosensitizer, metal, or base. With this strategy, 1,2,4-thiadiazoles can be obtained from thioamides. Preliminary mechanistic investigation suggested that the excited state of thioamides undergoes a single-electron-transfer (SET) process to afford thioamidyl radicals, which can be further transformed into a 1,2,4-thiadiazole through desulfurization and oxidative cyclization. The reaction has good functional group tolerance and represents a green method for the construction of S?N bonds.