637-51-4

Basic information

• Product Name: N-Phenylthioformamide
• Synonyms: N-Phenylformthioamide;N-Phenylthioformamide
• CAS NO: 637-51-4
• Molecular Formula: C₇H₇NS
• Molecular Weight: 137.2
• Mol File: 637-51-4.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 213.8°C at 760 mmHg
• Flash Point: 83.1°C
• Appearance: /
• Density: 1.202g/cm³
• Vapor Pressure: 0.161mmHg at 25°C
• Refractive Index: 1.684
• CAS DataBase Reference: N-Phenylthioformamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-Phenylthioformamide(637-51-4)
• EPA Substance Registry System: N-Phenylthioformamide(637-51-4)

Safety Data

• Hazardous Substances Data: 637-51-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C7H7NS/c9-6-8-7-4-2-1-3-5-7/h1-6H,(H,8,9)

Upstream product

• 4472-10-0 dithioformic acid 
• 103-72-0 phenyl isothiocyanate 
• 108-88-3 toluene 
• 75-15-0 carbon disulfide 
• 62-53-3 aniline 
• 1457-85-8 Ethyl oxanilate 
• 6890-75-1 Phenylaminothioxoacetic Acid 
• 1197040-29-1 phenyl isocyanate 
• 7783-06-4 hydrogen sulfide 
• 864131-95-3 N,N'-diphenylformamidine 
• 103-70-8 Formanilid 
• 29392-46-9 ethyl thioformate 
• 1783-25-1 N₁,N₁-dimethyl-N₂-phenylformamidine 
• 30962-16-4 potassium dithioformate 

Downstream Products

• 58065-75-1 C₁₀H₁₅NSSi 
• 54150-53-7 N-Phenyl-thioformimidic acid methyl ester 
• 1360813-71-3 C₁₇H₁₉N₃O₄S 
• 885917-50-0 C₁₄H₁₁Cl₂N₃OS 
• 701211-17-8 C₁₄H₉Cl₂N₃O 
• 1148-89-6 2-phenylamino-5-phenyl-1,3,4-oxadiazole 
• 13153-01-0 1-benzoyl-4-phenyl-3-thiosemicarbazide 
• 1360813-69-9 C₁₆H₁₇N₃OS 
• 1360813-46-2 C₁₆H₁₅N₃O 
• 6780-42-3 N-phenyl-thioformimidic acid ethyl ester 
• 331631-15-3 1-[2-(1H-indol-3-yl)-ethyl]-3-phenyl thiourea 
• 72726-89-7 4-(2-Methoxycarbonylethylthio)-1,3,3-triphenyl-2-azetidinone 
• 72726-88-6 3-(N-Phenyl-formimidoylsulfanyl)-propionic acid methyl ester 

Relevant articles and documents

B(C6F5)3- And HB(C6F5)2-mediated transformations of isothiocyanates

This contribution reports on the reactivity of isothiocyanates towards the boranes B(C6F5)3and HB(C6F5)2. The reactions of alkyl-substituted isothiocyanates with B(C6F5)3were found to result in rearrangement reactions to yield stable thiocyanate-B(C6F5)3adducts. Treatment of isothiocyanates with HB(C6F5)2leads to 1,2-hydroboration and thus, B,N,C,S heterocycles are formed, which react further under non-inert conditions. Hydrolysis of the hydroboration products leads to a new access to thioformamides.

A new convenient synthesis of 5-aryl-2-(arylamino)-1,3,4-oxadiazole derivatives

Electrical energy offers numerous benefits for conducting a synthesis, including increased reaction rates, yield enhancements and cleaner chemistries. 5-Aryl-2-(arylamino)-1,3,4-oxadiazoles were synthesized directly from acylthiosemicarbazide on the plati

Novel reduction of isothiocyanates to thioformamides with SmI2 and tert-butyl alcohol in the presence of HMPA

Isocyanates react with SmI2 and tert-butyl alcohol in the presence of HMPA to give thioformamides in excellent yields under mild conditions.