Welcome to LookChem.com Sign In|Join Free
  • or

375-22-4

Post Buying Request

375-22-4 Suppliers

Recommended suppliersmore

Product FOB Price Min.Order Supply Ability Supplier
Heptafluorobutyric acid Manufacturer/High quality/Best price/In stock
Cas No: 375-22-4
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High quality Heptafluorobutyric acid supplier in China
Cas No: 375-22-4
No Data No Data Metric Ton/Day Simagchem Corporation Contact Supplier
Heptafluorobutyric acid Manufacturer/High quality
Cas No: 375-22-4
USD $ 1.0-3.0 / Metric Ton 1 Metric Ton 10 Metric Ton/Day Hebei yanxi chemical co.,LTD. Contact Supplier
Heptafluorobutyric acid
Cas No: 375-22-4
No Data 1 Kilogram 20 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier
Heptafluorobutyric acid
Cas No: 375-22-4
No Data 10 Gram 1 Metric Ton/Month Wuhan Kemi-Works Chemical Co., Ltd Contact Supplier
2,2,3,3,4,4,4-heptafluorobutanoate
Cas No: 375-22-4
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
Heptafluorobutyric acid
Cas No: 375-22-4
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
Heptafluorobutyric acid-
Cas No: 375-22-4
No Data 1 Kilogram 1 Metric Ton/Month Henan Tianfu Chemical Co., Ltd. Contact Supplier
BLOOM TECH Advanced API/Technology support Heptafluorobutyric acid CAS 375-22-4
Cas No: 375-22-4
No Data 1 Gram 3 Metric Ton/Month Shaanxi BLOOM TECH Co.,Ltd Contact Supplier
Butanoic acid,2,2,3,3,4,4,4-heptafluoro-
Cas No: 375-22-4
No Data No Data No Data Shandong Hanjiang Chemical Co., Ltd. Contact Supplier

375-22-4 Usage

Purification Methods

Fractionally distil the acid twice in an Oldershaw column (p 10) with an automatic vapour-dividing head, the first distillation being in the presence of conc H2SO4 as a drying agent. (Take care with the hot acid.) [Beilstein 2 IV 810.]

Chemical Properties

Clear colorless to faintly yellow liquid

Definition

ChEBI: A monocarboxylic acid that is perfluorinated butyric acid.
InChI:InChI=1/C4HF7O2/c5-2(6,1(12)13)3(7,8)4(9,10)11/h(H,12,13)/p-1

375-22-4 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Sigma (77249)  Heptafluorobutyricacid  ≥99.0% (GC) 375-22-4 77249-50ML 6,669.00CNY Detail
Sigma (77249)  Heptafluorobutyricacid  ≥99.0% (GC) 375-22-4 77249-10ML 1,932.84CNY Detail
Sigma-Aldrich (52411)  Heptafluorobutyricacid  for ion chromatography, ≥99.5% (GC) 375-22-4 52411-25ML-F 1,078.74CNY Detail
Sigma-Aldrich (52411)  Heptafluorobutyricacid  for ion chromatography, ≥99.5% (GC) 375-22-4 52411-5ML-F 318.24CNY Detail
Sigma-Aldrich (52411)  Heptafluorobutyricacid  for ion chromatography, ≥99.5% (GC) 375-22-4 52411-INTR-F 0.00CNY Detail
Alfa Aesar (A14907)  Heptafluorobutyric acid, 99%    375-22-4 500g 6670.0CNY Detail
Alfa Aesar (A14907)  Heptafluorobutyric acid, 99%    375-22-4 100g 1477.0CNY Detail
Alfa Aesar (A14907)  Heptafluorobutyric acid, 99%    375-22-4 25g 498.0CNY Detail
TCI America (H0024)  Heptafluorobutyric Acid  >98.0%(GC)(T) 375-22-4 100g 1,240.00CNY Detail
TCI America (H0024)  Heptafluorobutyric Acid  >98.0%(GC)(T) 375-22-4 25g 530.00CNY Detail

375-22-4Synthetic route

6,6,6-Trichlor-perfluor-capronsaeure-chlorid-(1,1-dichlor-heptafluor-butylimid)
14154-45-1

6,6,6-Trichlor-perfluor-capronsaeure-chlorid-(1,1-dichlor-heptafluor-butylimid)

water
7732-18-5

water

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

6,6,6-Trichloro-2,2,3,3,4,4,5,5-octafluoro-hexanoic acid

6,6,6-Trichloro-2,2,3,3,4,4,5,5-octafluoro-hexanoic acid

Conditions
ConditionsYield
With H2SO4 concd. H2SO4;A n/a
B 95%
sodium heptafluorobutyrate
2218-54-4

sodium heptafluorobutyrate

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

Conditions
ConditionsYield
With sulfuric acid at 120℃;92%
Dimethyl phosphite
868-85-9

Dimethyl phosphite

heptafluorobutyric anhydride
336-59-4

heptafluorobutyric anhydride

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

[1-(Dimethoxy-phosphoryloxy)-3,3,4,4,5,5,5-heptafluoro-1-heptafluoropropyl-2-oxo-pentyl]-phosphonic acid dimethyl ester

[1-(Dimethoxy-phosphoryloxy)-3,3,4,4,5,5,5-heptafluoro-1-heptafluoropropyl-2-oxo-pentyl]-phosphonic acid dimethyl ester

Conditions
ConditionsYield
Ambient temperature;A n/a
B 85%
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane
423-39-2

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

Conditions
ConditionsYield
With disodium hydrogenphosphate; potassium dihydrogenphosphate; lipoxygenase; oct-2-yne at 25 - 30℃;83%
With oxygen In N,N-dimethyl-formamide Kinetics; Mechanism; galvanostatic electrolysis; also with perfluoro-octyliodide;
With oxygen In N,N-dimethyl-formamide Rate constant; Mechanism; electrolysis at a carbon cathode;
nonafluoro-n-butanesulfenic acid
1606143-50-3

nonafluoro-n-butanesulfenic acid

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

Conditions
ConditionsYield
In water; toluene at 20℃; for 2h;75%
With water In toluene at 20℃; for 2h;75%
sodium 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfinate
102061-82-5

sodium 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfinate

allyl bromide
106-95-6

allyl bromide

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

4,4,5,5,6,6,7,7,7-nonafluoro-1-heptene
129846-67-9

4,4,5,5,6,6,7,7,7-nonafluoro-1-heptene

Conditions
ConditionsYield
With ammonium peroxydisulfate In N,N-dimethyl-formamide at 40℃; for 4h;A 10%
B 72%
phosphonic acid diethyl ester
762-04-9

phosphonic acid diethyl ester

heptafluorobutyric anhydride
336-59-4

heptafluorobutyric anhydride

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

1-(diethoxyphosphinyl)heptafluoro-1-(heptafluorobutyryl)butyl diethyl phosphate

1-(diethoxyphosphinyl)heptafluoro-1-(heptafluorobutyryl)butyl diethyl phosphate

Conditions
ConditionsYield
Ambient temperature;A n/a
B 70%
trichlorfon
52-68-6

trichlorfon

heptafluorobutyric anhydride
336-59-4

heptafluorobutyric anhydride

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

C8H7Cl3F7O5P
169469-22-1

C8H7Cl3F7O5P

Conditions
ConditionsYield
In 1,2-dichloro-ethane at 40℃; for 2h;A n/a
B 68%
oct-2-yne
2809-67-8

oct-2-yne

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane
423-39-2

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

2-(perfluorobutyl)-2-octene
113999-55-6

2-(perfluorobutyl)-2-octene

Conditions
ConditionsYield
With disodium hydrogenphosphate; potassium dihydrogenphosphate; catalase at 25 - 30℃; for 720h;A 67%
B 10%
carbon dioxide
124-38-9

carbon dioxide

(heptafluoro n-propyl) magnesiumiodide
423-25-6

(heptafluoro n-propyl) magnesiumiodide

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

Conditions
ConditionsYield
In diethyl ether introduction of CO2 during formation of the grignard compound at -20°C;;65%
In diethyl ether introduction of CO2 during formation of the grignard compound at -20°C;;65%
In diethyl ether introduction of CO2 after formation of the grignard compound at -20°C;;59%
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane
423-39-2

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

4-methoxy-aniline
104-94-9

4-methoxy-aniline

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

1-methoxy-4-(1,1,2,2,3,3,4,4,4-nonafluorobutyl)benzene
153910-98-6

1-methoxy-4-(1,1,2,2,3,3,4,4,4-nonafluorobutyl)benzene

Conditions
ConditionsYield
Stage #1: 4-methoxy-aniline With tert.-butylnitrite; sulfuric acid; water In acetonitrile for 0.25h; Cooling with ice; Schlenk technique;
Stage #2: 1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane With copper; hydroquinone In acetonitrile at 20℃; for 0.5h; Inert atmosphere; Schlenk technique;
A 27%
B 65%
di-n-propyl phosphonate
1809-21-8

di-n-propyl phosphonate

heptafluorobutyric anhydride
336-59-4

heptafluorobutyric anhydride

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

[1-(Dipropoxy-phosphoryloxy)-3,3,4,4,5,5,5-heptafluoro-1-heptafluoropropyl-2-oxo-pentyl]-phosphonic acid dipropyl ester

[1-(Dipropoxy-phosphoryloxy)-3,3,4,4,5,5,5-heptafluoro-1-heptafluoropropyl-2-oxo-pentyl]-phosphonic acid dipropyl ester

Conditions
ConditionsYield
Ambient temperature;A n/a
B 64%
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane
423-39-2

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

phenylacetylene
536-74-3

phenylacetylene

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

(E)-(3,3,4,4,5,5,6,6,6-nonafluoro-1-hexen-1-yl)benzene
80967-16-4, 95452-53-2, 87384-88-1

(E)-(3,3,4,4,5,5,6,6,6-nonafluoro-1-hexen-1-yl)benzene

Conditions
ConditionsYield
With disodium hydrogenphosphate; potassium dihydrogenphosphate; catalase at 25 - 30℃; for 240h;A 3%
B 64%
4,4,5,5,6,6,6-heptafluoro-1-phenyl-hexane-1,3-dione
53580-21-5

4,4,5,5,6,6,6-heptafluoro-1-phenyl-hexane-1,3-dione

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

2-diazo-acetophenone
3282-32-4

2-diazo-acetophenone

Conditions
ConditionsYield
With 4-toluenesulfonyl azide; triethylamine In dichloromethane for 5h;A n/a
B 61%
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane
423-39-2

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

allyl bromide
106-95-6

allyl bromide

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

nonafluorobutane
375-17-7

nonafluorobutane

C

4,4,5,5,6,6,7,7,7-nonafluoro-1-heptene
129846-67-9

4,4,5,5,6,6,7,7,7-nonafluoro-1-heptene

Conditions
ConditionsYield
With potassium hydroxide; 2,2'-azobis(isobutyronitrile) at 80℃; for 56h; Substitution;A n/a
B n/a
C 57%
allyl iodid
556-56-9

allyl iodid

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane
423-39-2

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

nonafluorobutane
375-17-7

nonafluorobutane

C

4,4,5,5,6,6,7,7,7-nonafluoro-1-heptene
129846-67-9

4,4,5,5,6,6,7,7,7-nonafluoro-1-heptene

Conditions
ConditionsYield
With potassium hydroxide; 2,2'-azobis(isobutyronitrile) at 80℃; for 56h; Substitution;A n/a
B n/a
C 55%
n-octyne
629-05-0

n-octyne

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane
423-39-2

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

(E)-1-(perfluorobutyl)-1-octene
113999-54-5

(E)-1-(perfluorobutyl)-1-octene

Conditions
ConditionsYield
With disodium hydrogenphosphate; potassium dihydrogenphosphate; catalase at 25 - 30℃; for 336h;A 25%
B 46%
perfluorobutyryl fluoride
335-42-2

perfluorobutyryl fluoride

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

Conditions
ConditionsYield
Stage #1: perfluorobutyryl fluoride With potassium hydroxide In water
Stage #2: With sulfuric acid; silica gel at 100℃; for 3h;
45%
With water
With water
sodium 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfinate
102061-82-5

sodium 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfinate

propargyl bromide
106-96-7

propargyl bromide

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

4,4,5,5,6,6,7,7,7-nonafluoro-1,2-heptadiene
132673-98-4

4,4,5,5,6,6,7,7,7-nonafluoro-1,2-heptadiene

Conditions
ConditionsYield
With ammonium peroxydisulfate In N,N-dimethyl-formamide at 40℃; for 4h;A 10%
B 42%
2C4F9(1-)*Ag(1+)*Cu(1+)

2C4F9(1-)*Ag(1+)*Cu(1+)

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

Conditions
ConditionsYield
With water; triphenylphosphine at 20℃; for 12h; Inert atmosphere;37%
1-Phenylprop-1-yne
673-32-5

1-Phenylprop-1-yne

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane
423-39-2

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

1-phenyl-2-(perfluorobutyl)propene
113999-53-4

1-phenyl-2-(perfluorobutyl)propene

Conditions
ConditionsYield
With disodium hydrogenphosphate; potassium dihydrogenphosphate; catalase at 25 - 30℃; for 720h;A 33%
B 26%
heptafluorobutyric anhydride
336-59-4

heptafluorobutyric anhydride

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

3,3,4,4,5,5,5-heptafluoro-1-phenylpentan-2-one
559-96-6

3,3,4,4,5,5,5-heptafluoro-1-phenylpentan-2-one

C

1,1,1,2,2,3,3-heptafluoro-4-phenylbutane
81664-99-5

1,1,1,2,2,3,3-heptafluoro-4-phenylbutane

D

2-Benzyl-3,3,4,4,5,5,5-heptafluoro-1-phenyl-pentan-2-ol
112631-03-5

2-Benzyl-3,3,4,4,5,5,5-heptafluoro-1-phenyl-pentan-2-ol

Conditions
ConditionsYield
In diethyl ether; 1,1,2-Trichloro-1,2,2-trifluoroethane Ambient temperature; Yield given;A n/a
B 21%
C 24%
D 11%
In diethyl ether; 1,1,2-Trichloro-1,2,2-trifluoroethane Ambient temperature;A n/a
B 21%
C 24%
D 11%
heptafluorobutyric anhydride
336-59-4

heptafluorobutyric anhydride

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

3,3,4,4,5,5,5-heptafluoro-1-phenylpentan-2-one
559-96-6

3,3,4,4,5,5,5-heptafluoro-1-phenylpentan-2-one

C

1,1,1,2,2,3,3-heptafluoro-4-phenylbutane
81664-99-5

1,1,1,2,2,3,3-heptafluoro-4-phenylbutane

D

2-Benzyl-3,3,4,4,5,5,5-heptafluoro-1-phenyl-pentan-2-ol
112631-03-5

2-Benzyl-3,3,4,4,5,5,5-heptafluoro-1-phenyl-pentan-2-ol

E

C3F7CH2C6H4C3F7

C3F7CH2C6H4C3F7

Conditions
ConditionsYield
In 1,1,2-Trichloro-1,2,2-trifluoroethane Mechanism; Ambient temperature; various nucleophilic substrates investigated;A n/a
B 21%
C 24%
D 11%
E n/a
3,3,4,4,5,5,5-heptafluoro-1-iodopentene
376-97-6

3,3,4,4,5,5,5-heptafluoro-1-iodopentene

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

Conditions
ConditionsYield
With potassium hydroxide; potassium permanganate
heptafluorobutyryl chloride
375-16-6

heptafluorobutyryl chloride

silver(I) cyanide
506-64-9

silver(I) cyanide

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

heptafluoropropyl-hydroxy-malonic acid diamide
356-10-5

heptafluoropropyl-hydroxy-malonic acid diamide

Conditions
ConditionsYield
und Behandeln des als ein Dimeres des Heptafluor-2-oxo-valeronitrils angesehenen Reaktionsprodukts mit konz.wss.Salzsaeure;
1,1,1,2,2,3,3-heptafluoro-3-iodo-propane
754-34-7

1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

carbon dioxide
124-38-9

carbon dioxide

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

Conditions
ConditionsYield
(i) nBuLi, Et2O, (ii) /BRN= 1900390/; Multistep reaction;
styrene
292638-84-7

styrene

bis(heptafluorobutyryl) peroxide
336-64-1

bis(heptafluorobutyryl) peroxide

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

(E)-(3,3,4,4,5,5,5-heptafluoropent-1-enyl)benzene
87384-87-0

(E)-(3,3,4,4,5,5,5-heptafluoropent-1-enyl)benzene

C

2,2,3,3,4,4,4-Heptafluoro-butyric acid 3,3,4,4,5,5,5-heptafluoro-1-phenyl-pentyl ester
99930-45-7

2,2,3,3,4,4,4-Heptafluoro-butyric acid 3,3,4,4,5,5,5-heptafluoro-1-phenyl-pentyl ester

Conditions
ConditionsYield
In 1,1,2-Trichloro-1,2,2-trifluoroethane at 40℃; for 3h; in degassed and sealed tube;A n/a
B 7 % Chromat.
C 89 % Chromat.
bis(heptafluorobutyryl) peroxide
336-64-1

bis(heptafluorobutyryl) peroxide

di-tert-butyl nitroxide
2406-25-9, 44871-19-4

di-tert-butyl nitroxide

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

t-butylnitrite
917-95-3

t-butylnitrite

C

tetradecafluorohexane
355-42-0

tetradecafluorohexane

D

carbon dioxide
124-38-9

carbon dioxide

E

bis(pentadecafluoro-octanoyl) peroxide
34434-27-0

bis(pentadecafluoro-octanoyl) peroxide

Conditions
ConditionsYield
With in an ESR tube In 1,1,2-Trichloro-1,2,2-trifluoroethane at -30℃; for 0.5h; Product distribution; the reaction mixture was analyzed quantitatively by ESR, by NMR and GC;
t-butyl heptafluoroperoxybutyrate
91481-65-1

t-butyl heptafluoroperoxybutyrate

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

2-Methoxypropene
116-11-0

2-Methoxypropene

C

acetic acid methyl ester
79-20-9

acetic acid methyl ester

D

2-(1-methoxy-1-methylethoxy)-2-methylpropane

2-(1-methoxy-1-methylethoxy)-2-methylpropane

Conditions
ConditionsYield
In pyridine at 50℃; for 12h; Product distribution;A 0.91 % Turnov.
B 0.46 % Turnov.
C 0.03 % Turnov.
D 0.21 % Turnov.
t-butyl heptafluoroperoxybutyrate
91481-65-1

t-butyl heptafluoroperoxybutyrate

A

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

B

2-Methoxypropene
116-11-0

2-Methoxypropene

C

tert-butyl heptafluorobutyrate
425-24-1

tert-butyl heptafluorobutyrate

D

2,2-dimethoxy-propane
77-76-9

2,2-dimethoxy-propane

E

1-methoxy-1-methylethyl heptafluorobutyrate

1-methoxy-1-methylethyl heptafluorobutyrate

Conditions
ConditionsYield
In nitrobenzene at 70℃; for 7h; Product distribution;A 0.90 % Turnov.
B 0.19 % Turnov.
C 0.02 % Turnov.
D 0.06 % Turnov.
E 0.05 % Turnov.
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

bis(tri-n-butyltin)oxide
56-35-9

bis(tri-n-butyltin)oxide

Tributyl-heptafluorbutyroxy-zinn
23716-72-5

Tributyl-heptafluorbutyroxy-zinn

Conditions
ConditionsYield
byproducts: H2O;100%
byproducts: H2O;100%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

4-nitro-3-methylaniline
611-05-2

4-nitro-3-methylaniline

4-n-heptafluoropropylcarbonylamino-2-methylnitrobenzene
942062-07-9

4-n-heptafluoropropylcarbonylamino-2-methylnitrobenzene

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 0 - 20℃; for 12h;100%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

ethyl α-diazo-α-(4-bromophenyl)acetate
758692-47-6

ethyl α-diazo-α-(4-bromophenyl)acetate

C14H10BrF7O4

C14H10BrF7O4

Conditions
ConditionsYield
With air In dichloromethane at 20℃; Irradiation;99%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

triphenylantimony
603-36-1

triphenylantimony

μ2-oxobis(heptafluorobutanoatetriphenylantimony)

μ2-oxobis(heptafluorobutanoatetriphenylantimony)

Conditions
ConditionsYield
In diethyl ether at 20℃; for 24h;98%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

cyclomaltooctaose
17465-86-0

cyclomaltooctaose

octakis (6-O-perfluorobutanoyl)-γ-cyclodextrin

octakis (6-O-perfluorobutanoyl)-γ-cyclodextrin

Conditions
ConditionsYield
at 110℃; for 9h;96%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

(1S,2S,3aR,6aR)-2-benzamido-N-(tert-butyl)-1-(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)octahydropentalene-2-carboxamide

(1S,2S,3aR,6aR)-2-benzamido-N-(tert-butyl)-1-(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)octahydropentalene-2-carboxamide

C12H22BNO4*C4HF7O2

C12H22BNO4*C4HF7O2

Conditions
ConditionsYield
Stage #1: (1S,2S,3aR,6aR)-2-benzamido-N-(tert-butyl)-1-(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)octahydropentalene-2-carboxamide With hydrogenchloride; water; acetic acid at 130℃; for 0.5h; Inert atmosphere;
Stage #2: heptafluorobutyric Acid With trifluoroacetic acid In water; acetonitrile Inert atmosphere;
96%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

tri-p-fluorophenylstibine
33756-42-2

tri-p-fluorophenylstibine

bis(heptafluorobutyrato)[tris(4-fluorophenyl)antimony]

bis(heptafluorobutyrato)[tris(4-fluorophenyl)antimony]

Conditions
ConditionsYield
With tert.-butylhydroperoxide In diethyl ether; water at 20℃; for 24h;96%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

Rh2(O2CCH3)2[(C6H4)PPh2]2*(HO2CCH3)2

Rh2(O2CCH3)2[(C6H4)PPh2]2*(HO2CCH3)2

(M)-Rh2(OC(O)(CF2)2CF3)2(C6H4P(C6H5)2)2
887305-64-8, 172989-20-7

(M)-Rh2(OC(O)(CF2)2CF3)2(C6H4P(C6H5)2)2

Conditions
ConditionsYield
With N-((4-methylphenyl)sulfonyl)-L-proline In dichloromethane; acetone to soln. racemic Rh complex was added N-((4-methylphenyl)sulfonyl)-L-proline and rfluxed for 2 h, diastereomers were separated, crude product was dissolved in acetone, carboxylic acid in CH2Cl2 was added and stirred for 1/2 h; soln. was concd. and chromed.;95%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

yttrium(III) carbonate trihydrate

yttrium(III) carbonate trihydrate

yttrium(III) perfluorobutyrate dihydrate

yttrium(III) perfluorobutyrate dihydrate

Conditions
ConditionsYield
In toluene refluxed for 24; ppt. filtered, recrystd (diethyl ether); elem. anal.;95%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

tert-butyl ((2S)-4-methyl-1-((2R)-2-methyloxirane-2-yl)-1-oxopentan-2-yl)carbamate
247068-82-2

tert-butyl ((2S)-4-methyl-1-((2R)-2-methyloxirane-2-yl)-1-oxopentan-2-yl)carbamate

C9H17NO2*C4HF7O2

C9H17NO2*C4HF7O2

Conditions
ConditionsYield
In dichloromethane at 0 - 23℃; for 2h; Inert atmosphere;94%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

tris(2-methoxy-5-bromophenyl)antimony

tris(2-methoxy-5-bromophenyl)antimony

bis(heptafluorobutylato)tris(5-bromo-2-metoxyphenyl)antimony

bis(heptafluorobutylato)tris(5-bromo-2-metoxyphenyl)antimony

Conditions
ConditionsYield
With tert.-butylhydroperoxide In diethyl ether; water at 20℃; for 24h;94%
dirhodium tetraacetate

dirhodium tetraacetate

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

heptafluorobutyric anhydride
336-59-4

heptafluorobutyric anhydride

dirhodium(II) tetrakis(perfluorobutyrate)

dirhodium(II) tetrakis(perfluorobutyrate)

Conditions
ConditionsYield
In neat (no solvent) refluxing, distn. off excess of perfluorobutyric acide;; cooling to 25°C, then to -20°C for several hours, filtn. of dark blue-green Rh-complex, washing (cold pentane), drying in vac., recrystn. (benzene), elem. anal.;91%
dirhodium tetraacetate

dirhodium tetraacetate

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

heptafluorobutyric anhydride
336-59-4

heptafluorobutyric anhydride

rhodium(II) perfluorobutyrate

rhodium(II) perfluorobutyrate

Conditions
ConditionsYield
refluxing a soln. of 2 g Rh2(CH3CO2)4 in perfluorobutyric acid and perfluorobutyric anhydride for a few min; half of solvent distd. off; cooling to room temperature and then to -20°C for several hours;; filtration; washing with pentane; drying; recrystallization from purified benzene; stored in base-free desiccator over P2O5 in vac.; elem. anal.;;91%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

2-heptafluoropropyl-1H-benzoimidazole
559-37-5

2-heptafluoropropyl-1H-benzoimidazole

Conditions
ConditionsYield
at 120℃; for 4h;90%
In neat (no solvent) at 120℃; for 4h; Product distribution; further perfluoroalkanecarboxylic acids or anhydrides; presence of polyphosphoric acid; variation of temperature and time;90%
With hydrogenchloride In benzene for 16h; Heating;32%
With hydrogenchloride
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

N-(4-methoxy-2-methylphenyl)-2,2,3,3,4,4,4-heptafluorobutanimidoyl chloride

N-(4-methoxy-2-methylphenyl)-2,2,3,3,4,4,4-heptafluorobutanimidoyl chloride

Conditions
ConditionsYield
With tetrachloromethane; triethylamine; triphenylphosphine for 3h; Heating;90%
With triethylamine; triphenylphosphine In tetrachloromethane for 3h; Heating;90%
1,3-cyclopentadione
3859-41-4

1,3-cyclopentadione

heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

2-(2,2,3,3,4,4,4-heptafluorobutanoyl)cyclopentane-1,3-dione

2-(2,2,3,3,4,4,4-heptafluorobutanoyl)cyclopentane-1,3-dione

Conditions
ConditionsYield
With 1H-imidazole; 1,1'-carbonyldiimidazole In chloroform at 20℃; for 4h;90%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

2-(1H,1H,2H,2H-perfluorooctylthio)-1-methylimidazole

2-(1H,1H,2H,2H-perfluorooctylthio)-1-methylimidazole

2-(1H,1H,2H,2H-perfluorooctylthio)-1-methylimidazolium perfluorobutanoate

2-(1H,1H,2H,2H-perfluorooctylthio)-1-methylimidazolium perfluorobutanoate

Conditions
ConditionsYield
In water at 20℃;90%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

pentaphenylantimony
2170-05-0

pentaphenylantimony

tetraphenylantimony heptafluorobutanate

tetraphenylantimony heptafluorobutanate

Conditions
ConditionsYield
In benzene at 20℃; for 24h;90%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

cyclohexene
110-83-8

cyclohexene

trans-2-iodocyclohexyl heptafluorobutyrate

trans-2-iodocyclohexyl heptafluorobutyrate

Conditions
ConditionsYield
With N-Jod-p-nitrobenzamid In dichloromethane for 16h; Ambient temperature;89%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

ortho-ethylaniline
578-54-1

ortho-ethylaniline

N-(2-ethylphenyl)-2,2,3,3,4,4,4-heptafluorobutanimidoyl chloride

N-(2-ethylphenyl)-2,2,3,3,4,4,4-heptafluorobutanimidoyl chloride

Conditions
ConditionsYield
With tetrachloromethane; triethylamine; triphenylphosphine for 3h; Heating;89%
With triethylamine; triphenylphosphine In tetrachloromethane for 3h; Heating;89%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

diethylzinc
557-20-0

diethylzinc

EtZn(O2CC3F7)TMEDA
1430808-85-7

EtZn(O2CC3F7)TMEDA

Conditions
ConditionsYield
In hexane at -78 - 20℃; Inert atmosphere; Schlenk technique;89%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

penta(p-tolyl)antimony(V)
13328-67-1, 51017-91-5

penta(p-tolyl)antimony(V)

tetra-papa-tolylantimony heptafluorobutanate

tetra-papa-tolylantimony heptafluorobutanate

Conditions
ConditionsYield
In benzene at 20℃; for 24h;88%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

MeZn(O2CC3F7)TMEDA
1430808-83-5

MeZn(O2CC3F7)TMEDA

Conditions
ConditionsYield
In hexane at -78 - 20℃; Inert atmosphere; Schlenk technique;87%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

isopropyl alcohol
67-63-0

isopropyl alcohol

isopropyl 2,2,3,3,4,4,4-heptafluorobutyrate
425-23-0

isopropyl 2,2,3,3,4,4,4-heptafluorobutyrate

Conditions
ConditionsYield
for 2h; Reflux;87%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

perfluorobutyryl fluoride
335-42-2

perfluorobutyryl fluoride

Conditions
ConditionsYield
With N-(2-chloro-1,1,2-trifluoroethyl)diethylamine86.5%
With N-(2-chloro-1,1,2-trifluoroethyl)diethylamine; sodium fluoride at -78℃; for 0.25h;84%
at 300℃; Reaktion des Kupfer(II)-Salzes.Pyrolysis;
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

heptafluorobutyric anhydride
336-59-4

heptafluorobutyric anhydride

bis-heptafluoropropyldihydrazide
648-19-1

bis-heptafluoropropyldihydrazide

Conditions
ConditionsYield
by stirring at 0°C;86%
by stirring at 0°C;86%
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

3-dimethylaminoacrylonitrile
2407-68-3

3-dimethylaminoacrylonitrile

3-dimethylamino-2-(heptafluoropropylcarbonyl)acrylonitrile
1037593-84-2

3-dimethylamino-2-(heptafluoropropylcarbonyl)acrylonitrile

Conditions
ConditionsYield
With phosgene; triethylamine In toluene at 6 - 20℃; Inert atmosphere; Cooling with ice;86%
With phosgene; triethylamine In toluene at 6 - 20℃; Cooling with ice; Inert atmosphere;
heptafluorobutyric Acid
375-22-4

heptafluorobutyric Acid

1-phenyl-1-(2-amino-3-methoxyphenyl)ethylene
189252-16-2

1-phenyl-1-(2-amino-3-methoxyphenyl)ethylene

8-methoxy-2-(perfluoropropyl)-4-phenylquinoline

8-methoxy-2-(perfluoropropyl)-4-phenylquinoline

Conditions
ConditionsYield
In neat (no solvent) at 140℃; for 24h; Sealed tube;86%

Please post your buying leads,so that our qualified suppliers will soon contact you!

*Required Fields