4250-46-8

Basic information

• Product Name: dichloro-(4-chloro-phenyl)-borane
• Synonyms: dichloro-(4-chloro-phenyl)-borane
• CAS NO: 4250-46-8
• Molecular Weight: 193.268
• Mol File: 4250-46-8.mol

Chemical Properties

• CAS DataBase Reference: dichloro-(4-chloro-phenyl)-borane(CAS DataBase Reference)
• NIST Chemistry Reference: dichloro-(4-chloro-phenyl)-borane(4250-46-8)
• EPA Substance Registry System: dichloro-(4-chloro-phenyl)-borane(4250-46-8)

Safety Data

• Hazardous Substances Data: 4250-46-8(Hazardous Substances Data)

Upstream product

• 1802-38-6 4-chlorophenylmercury chloride 
• 10294-34-5 boron trichloride 
• 1679-18-1 4-Chlorophenylboronic acid 
• 6944-25-8 tris(4-chlorophenyl)stilbane 
• 1359224-18-2 Me₂NTol*BCl₃ 
• 108-90-7 chlorobenzene 
• 10026-13-8 phosphorus pentachloride 
• 109409-95-2 (i-C₄H₉O)2B(C₆H₄-4-Cl) 
• 15799-48-1 tetra(p-chlorophenyl)tin 
• 19287-45-7 diborane 

Downstream Products

• 23279-09-6 2,4,6-tris(4-chlorophenyl)borazine 
• 14062-24-9 4-chloro-benzeneacetic acid, ethyl ester 
• 6113-62-8 2-(4-chlorophenyl)benzo[d][1,3,2]dioxaborole 
• 5804-84-2 2-(4-chloro-phenyl)-naphtho[2,3-d][1,3,2]dioxaborole 
• 195062-61-4 4-chlorophenylboronic acid pinacol ester 
• 827605-29-8 2-(4-chloro-phenyl)-5,5-dimethyl-[1,3,2]dioxaborinane 
• 24382-97-6 1-(4-chlorophenyl)naphthalene 
• 134-85-0 4-chlorobenzophenone 

Relevant articles and documents

Substituent Effects in the Cyclization of Yne-Diols Catalyzed by Gold Complexes Featuring L2/Z-Type Diphosphinoborane Ligands

Gold(I) complexes featuring Z-type ligands introducing electron-withdrawing groups (EWG), Au(DPBF)Cl (4a) and Au(DPBCl)Cl (4b) (DPB = diphosphine-boron), have been synthesized and structurally characterized. These studies suggest tha

Synthesis of arylboronates by boron-induced ipso-deantimonation of triarylstibanes with boron trihalides and its application in one-pot two-step transmetallation/cross-coupling reactions

The reaction of triarylstibanes (1) with boron trihalides (BCl3, and BBr3) afforded arylboron dihalides (2) by utilizing all the three aryl groups on the antimony. Boron intermediates (2) were transformed to arylboronates (3) in good to excellent yields by treatment with methanol and 1,3-propanediol. Further, the Pd-catalyzed reactions of 2 with organic halides such as 1-bromonaphthalene and benzoyl chloride in the presence of H2O afforded the corresponding cross-coupling products, unsymmetrical biaryls (4) and ketones (5), in moderate to good yields. The potential energy surfaces for the transmetallations of triarylstibanes (1) with BCl3 affording 2 were determined by molecular orbital calculations. The analyses of substituent effects on theoretically calculated reactivities showed the importance of the resonance effects of the ring substituents on these transmetallations.

Regioselective electrophilic borylation of haloarenes

Haloarenes undergo direct borylation using amine:BCl3:AlCl3 in the ratio of 1:1:2. After esterification the pinacol boronate esters are isolated in good yield with regioselectivity controlled by steric and electronic effects.

A New Borylation Method for Alkylbenzene and Polystyrene

The borylation of alkylbenzenes by Hal2BH (Hal = F, Cl, Br) gives H2 and a mixture of m- and p-alkyl(dihaloboryl)benzenes.In the case of bulky alkyl groups, such as isopropyl, tert-butyl, these are partially split off as R - H and RBHal2.The phenyl groups in polystyrene-divinylbenzene copolymers undergo borylation with Br2BH in a 55percent yield.