1453-21-0Relevant articles and documents
Conversion of Alcohols to Methylene Acetals by Reaction with Dimethyl sulfoxide-Bromine
Munavu, Raphael M.
, p. 3341 - 3343 (1980)
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Hanessian,S. et al.
, p. 8929 - 8931 (1972)
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Dimethyl sulfoxide as a "methylene" source: Ru(ii) photo-catalysed facile synthesis of acetals from alcohols
Talukdar, Ranadeep
supporting information, p. 13334 - 13338 (2019/09/06)
Acetals are important molecules with versatile reactivity and uses. For the first time a simple photo-catalysed facile synthesis of formaldehyde acetals is documented herein upon the reaction of alcohols with dimethyl sulfoxide under very mild conditions in the presence of air. The reactions require only 1 mol% of RuII(bpy)3Cl2 photocatalyst under blue LED irradiation (λ = 445 nm) to give good to excellent yields of the corresponding acetal products. Here DMSO acts as a "methylene" source.
Simple synthesis of N-alkoxymethyl derivatives of anilides
Danikiewicz,Szmigielski
, p. 3047 - 3054 (2007/10/03)
Facile, two-step synthesis of N-alkoxymethyl derivatives of anilides consisting of the methoxymethylation of the appropriate anilides with chlomethyl methyl ether followed by heating with an alcohol in the presence of an acid is described.
Montmorillonite, an efficient catalyst for the preparation of dialkoxymethanes
Deshmukh,Gumaste,Bhawal
, p. 3939 - 3944 (2007/10/03)
The reaction of various alcohols with paraformaldehyde in presence of montmorillonite to give dialkoxymethanes (2a-g) in very good yield is described.
