4282-28-4

Usage

Uses

Used in Polymer and Plastics Industry:
FDCA is used as a monomer for the production of bio-based plastics, aiming to reduce reliance on non-renewable resources and decrease environmental impact. Its versatile chemical properties make it a promising candidate for creating sustainable and eco-friendly products in this industry.
Used in Material Science:
FDCA is utilized as a platform chemical for developing new materials with improved properties, such as biodegradability and reduced environmental footprint. Its potential applications in material science include the creation of innovative, sustainable materials for various industries.
Used in Chemical Research:
FDCA serves as a subject of study for researchers exploring its potential applications and properties. Its unique structure and renewable nature make it an interesting compound for developing new chemical processes and products that contribute to a circular economy.

InChI:InChI=1/C6H4O5/c7-5(8)3-1-4(6(9)10)11-2-3/h1-2H,(H,7,8)(H,9,10)

Upstream product

• 89677-39-4 5-acetylfuran-3-carboxylic acid 
• 42933-07-3 methyl 3-bromo-2-oxo-2H-pyran-5-carboxylate 
• 32365-55-2 2,4-dicarbethoxyfuran 
• 98556-04-8 furan-2,3,5-tricarboxylic acid 
• 121-33-5 vanillin 
• 60965-54-0 4-sulfo-furan-2-carboxylic acid 
• 141-53-7 sodium formate 
• 488-93-7 3-Furoic acid 
• 6018-41-3 methyl coumalate 
• 20842-02-8 potassium furan-2-carboxylate 
• 124-38-9 carbon dioxide 
• 20416-04-0 furantetracarboxylic acid 
• 109512-89-2 γ-Formyl-α-ketoglutarsaeure-diaethylester-diaethylketal 
• 64-19-7 acetic acid 

Downstream Products

• 1710-13-0 dimethyl furan-2,4-dicarboxylate 
• 32365-55-2 2,4-dicarbethoxyfuran 
• 488-93-7 3-Furoic acid 
• 859077-01-3 3-Diacetoxymethyl-furan 
• 6132-33-8 5-nitro-furan-3-carboxylic acid ethyl ester 
• 770-07-0 5-nitro-furan-3-carboxylic acid 
• 60162-44-9 furfuraldehyde phenylhydrazone 
• 72918-24-2 5-nitro-furan-3-carbaldehyde 
• 61759-72-6 4-Methyl-2-nitro-furan 
• 58832-36-3 5-bromofuran-3-carboxylic acid 
• 614-98-2 ethyl 3-furancarboxylate 
• 26214-65-3 furan-3-carbonyl chloride 
• 498-60-2 furan-3-carboxaldehyde 

Relevant academic research and scientific papers

GREEN, COPPER-CATALYZED DISPROPORTIONATION OF AROMATIC AND HETEROAROMATIC CARBOXYLATES TO DICARBOXYLATES

The present application relates to a process for preparation of a compound of Formula (I) and Formula (IV): wherein is as described herein; and wherein and R are as described herein.

Process For The Production Of The Mixture 2,4 Furandicarboxylic Acid (FDCA) And 2,5 Furandicarboxylic Acid Via Disproportionation Reaction, Mixture Of 2,4-FDCA And 2,5-FDCA As A Result Of Disproportination Reaction, 2,4-FDCA Obtained By The Disproportionation Reaction Process And Use Of 2,4-FDCA

The present invention refers to a process for production of a mixture including 2,4-furandicarboxylic acid (2,4-FDCA) and 2,5 furandicarboxylic acid (2,5-FDCA) through the disproportionation route, using as base compounds oxidation products of furfural. This invention also relates to a process for production of 2,4-FDCA as a result of a disproportionation route and the use of 2,4-FDCA as a monomer or comonomer to synthesize esters or any compounds which can generate macromolecules, such as polyesters.

Concurrent formation of furan-2,5- and furan-2,4-dicarboxylic acid: Unexpected aspects of the Henkel reaction

The concurrent formation of furan-2,5- and furan-2,4-dicarboxylic acid under solvent free conditions via a disproportionation reaction is described. By reacting potassium-2-furoate at 260 °C in the presence of 22 mol% of (Lewis acidic) catalysts like CdI2 or ZnCl2, potassium-2-furoate is disproportionated to furan and furandicarboxylic acids. Besides furan and furan-2,5-dicarboxylic acid (2,5-FDCA) as the main products, furan-2,4-dicarboxylic acid (2,4-FDCA) is also formed as a by-product. Experimental evidence has been obtained that, under the reaction conditions applied, 2,5-FDCA and 2,4-FDCA are formed by separate reaction pathways. Selectivity towards the different FDCA isomers is affected by the type of catalyst used. Single-crystal X-ray analysis shows that 2,4-FDCA has a more 'linear' character compared to 2,5-FDCA and hence is structurally more comparable to terephthalic acid (TA), making it an interesting monomer for synthetic polyesters.

PROCESS FOR THE PRODUCTION OF A MIXTURE OF 2,4- FURANDICARBOXYLIC ACID AND 2,5- FURANDICARBOXYLIC ACID (FDCA) VIA DISPROPORTIONATION REACTION, MIXTURE OF 2,4-FDCA AND 2, 5 - FDCA OBTAINABLE THEREBY, 2, 4 - FDCA OBTAINABLE THEREBY AND USE OF 2,4- FDCA

The present invention refers to a process for production of a mix? ture comprising 2,4-furandicarboxyiic acid (2,4-FDCA) and 2,5 furandicar- boxyiic acid (2,5-FDCA) through the disproportionation route, using as base compounds oxidation products of furfural. This invention also relates to a process for production of 2,4-FDCA as a result of a disproportionation route and the use of 2,4- FDCA as a monomer or comonomer to synthesize esters or any compounds which can generate macromolecules, such as polyesters.