4333-76-0

Basic information

• Product Name: Benzene, 1-bromo-4-(1-phenylethenyl)-
• CAS NO: 4333-76-0
• Molecular Formula: C14H11Br
• Molecular Weight: 259.145
• Mol File: 4333-76-0.mol
• Article Data: 36

Chemical Properties

• CAS DataBase Reference: Benzene, 1-bromo-4-(1-phenylethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-bromo-4-(1-phenylethenyl)-(4333-76-0)
• EPA Substance Registry System: Benzene, 1-bromo-4-(1-phenylethenyl)-(4333-76-0)

Safety Data

• Hazardous Substances Data: 4333-76-0(Hazardous Substances Data)

Upstream product

• 15832-69-6 1-(4-bromo-phenyl)-1-phenyl-ethanol 
• 536-74-3 phenylacetylene 
• 2170-06-1 1-Phenyl-2-(trimethylsilyl)acetylene 
• 19372-00-0 1-(trimethylsilyl)-2-phenylethene 
• 20566-57-8 4-bromobenzenediazonium hexafluorophosphate 
• 673-40-5 4-bromobenzenediazonium tetrafluoroborate 
• 90-90-4 (4-bromophenyl)(phenyl)methanone 
• 18006-13-8 methyltriisopropoxytitanium(IV) 
• 99-90-1 para-bromoacetophenone 
• 100-58-3 phenylmagnesium bromide 
• 6888-79-5 4-bromo-α-methylstyrene 
• 122948-58-7 1-(4-bromophenyl)vinyl trifluoromethanesulfonate 
• 71-43-2 benzene 
• 100-42-5 styrene 

Downstream Products

• 15832-69-6 1-(4-bromo-phenyl)-1-phenyl-ethanol 
• 880763-58-6 1-bromo-4-(2-bromo-1-phenylvinyl)benzene 
• 877455-35-1 4-(dichloromethylsilyl)diphenylethylene 
• 56913-50-9 1-(4-bromophenyl)-1-phenylethane 
• 1443780-56-0 4-(4-bromophenyl)-4-phenylbut-3-en-2-one 

Relevant articles and documents

Investigation of the Locked-Unlocked Mechanism in Living Anionic Polymerization Realized with 1-(Tri-isopropoxymethylsilylphenyl)-1-phenylethylene

Reported is an intriguing advance in living anionic polymerization (LAP) by a “locked-unlocked” mechanism in which the living anionic species can be quantitatively locked by end-capping with 1-(tri-isopropoxymethylsilylphenyl)-1-phenylethylene (DPE-Si(O-i

Visible-Light-Induced Meerwein Fluoroarylation of Styrenes

An unprecedented approach for assembling a broad range of 1,2-diarylethane derivatives with fluorine-containing fully substituted carbon centers was developed. The protocol features straightforward operation, proceeds under metal-free condition, and accommodates a large variety of synthetically useful functionalities. The critical aspect to the success of this novel transformation lies in using aryldiazonium salts as both aryl radical progenitor and also as single electron acceptor which elegantly enables a radical-polar crossover manifold.

Bimolecular vinylation of arenes by vinyl cations

Styrene derivatives can be easily synthesized from vinyl triflates and arenes under mild reaction conditions, using [Li][Al(OC(CF3)3)4] as a catalyst and LiHMDS as a base. This transformation is likely to involve a vinyl cation intermediate as an electrophile, which is corroborated by DFT calculations, deuterium-labeling and other control experiments. The use of an inert weakly coordinating anion is a decisive factor in this bimolecular vinylation process. This journal is