81329-28-4

Basic information

• Product Name: Benzonitrile, 4-(1-phenylethenyl)-
• CAS NO: 81329-28-4
• Molecular Formula: C15H11N
• Molecular Weight: 205.259
• Mol File: 81329-28-4.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Benzonitrile, 4-(1-phenylethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzonitrile, 4-(1-phenylethenyl)-(81329-28-4)
• EPA Substance Registry System: Benzonitrile, 4-(1-phenylethenyl)-(81329-28-4)

Safety Data

• Hazardous Substances Data: 81329-28-4(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 32792-60-2 4-nitrophenyl 4-cyanobenzoate 
• 623-00-7 4-bromobenzenecarbonitrile 
• 14900-39-1 phenylvinylboronic acid 
• 1228679-31-9 (E)-N'-(1-(4-cyanophenyl)ethylidene)-4-methylbenzenesulfonohydrazide 
• 98-80-6 phenylboronic acid 
• 98-81-7 1-bromovinylbenzene 
• 623-03-0 4-Cyanochlorobenzene 
• 66107-32-2 4-cyanophenyl trifluoromethanesulfonate 
• 4545-21-5 acetophenone p-toluenesulfonylhydrazone 
• 98-85-1 1-Phenylethanol 
• 3058-39-7 4-iodobenzonitrile 
• 16002-63-4 phenylmagnesium iodide 
• 619-65-8 4-cyanobenzoic Acid 

Downstream Products

• 29265-82-5 p-methoxycarbonyl-1,1-diphenylethylene 
• 150253-69-3 4-(1-phenylcyclopropyl)benzonitrile 
• 81329-22-8 cis-1,2-di-(p-cyanophenyl)-1,2-diphenylcyclopropane 
• 23450-31-9 4-benzylbenzonitrile 
• 1503-49-7 p-cyanobenzophenone 
• 74232-87-4 4-(3-Cyano-1-phenyl-propyl)-benzonitrile 
• 125847-21-4 1-(4-cyanophenyl)-1-phenylethane 
• 1420475-72-4 C₁₆H₁₅NO 
• 169266-95-9 4-(2-methoxy-1-phenylethyl)benzonitrile 
• 150253-70-6 N-<<4-(1-phenylcyclopropyl)phenyl>methyl>-1-naphthalenemethanamine 
• 110931-98-1 4-(1-phenylcyclopropyl)benzylamine 

Relevant articles and documents

Reactivity of Carbenes in Aqueous Nanomicelles Containing Palladium Nanoparticles

Palladium nanoparticles ligated with inexpensive triphenylphosphine and amphiphile PS-750-M are suitable for exploring the reactivity of carbenes in aqueous nanomicelles. Nanocatalyst is highly selective for metal-carbene migratory insertion, and micelle

Dehydrative Cross-Coupling of 1-Phenylethanol Catalysed by Palladium Nanoparticles Formed in situ under Acidic Conditions

A dehydrative cross-coupling of 1-phenylethanol catalysed by sugar derived, in situ formed palladium(0) nanoparticles under acidic conditions is realised. The acidic conditions allow for use of alcohols as a feedstock in metal-mediated coupling reactions via their in situ dehydration and subsequent cross-coupling. Extensive analysis of the size and morphology of the palladium nanoparticles formed in situ showed that the zero-valent metal was surrounded by hydrophilic hydroxyl groups. EDX-TEM imaging studies using a prototype silicon drift detector provided insight into the problematic role of molecular oxygen in the system. This increased understanding of the catalyst deactivation allowed for the development of the cross-coupling methodology. A 250-12,000 fold increase in molar efficiency was observed when compared to related two-step protocols that use alternative feedstocks for the palladium-mediated synthesis of stilbenes. This work opens up a new research area in which the active catalyst is formed, stabilised and regenerated by a renewable sugar.

Mn(OAc)3-Mediated Synthesis of 3-Phosphonyldihydrofurans from β-Ketophosphonates and Alkenes

A new, general method for the synthesis of 3-phosphonyldihydrofuran derivatives has been achieved through Mn(OAc)3-mediated radical cyclization between β-ketophosphonates and alkenes. This transformation allows the direct formation of C-C/C-O bonds and the construction of a dihydrofuran ring in one reaction with operational simplicity and excellent functional-group compatibility.