4442-82-4

Basic information

• Product Name: 2-cyclohexyl-1-phenyl-
• CAS NO: 4442-82-4
• Molecular Formula: C14H20O
• Molecular Weight: 204.312
• Mol File: 4442-82-4.mol
• Article Data: 7

Chemical Properties

• Melting Point: 54-56 °C
• Boiling Point: 142-143 °C(Press: 3 Torr)
• Density: 1.0239 g/cm3(Temp: 0 °C)
• CAS DataBase Reference: 2-cyclohexyl-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-cyclohexyl-1-phenyl-(4442-82-4)
• EPA Substance Registry System: 2-cyclohexyl-1-phenyl-(4442-82-4)

Safety Data

• Hazardous Substances Data: 4442-82-4(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 2550-36-9 Cyclohexylmethyl bromide 
• 71-43-2 benzene 
• 98-86-2 acetophenone 
• 108-93-0 cyclohexanol 
• 13735-81-4 1-styrenyloxytrimethylsilane 
• 5452-52-8 2-cyclohexylidene-1-phenyl-1-ethanone 
• 57213-26-0 1-(2-oxo-2-phenylethyl)cyclohexanol 
• 108-94-1 cyclohexanone 
• 35166-78-0 cyclohexylmethyl magnesium bromide 
• 108-86-1 bromobenzene 
• 695-12-5 vinylcyclohexane 
• 100-42-5 styrene 
• 126812-30-4 1,3-dioxoisoindolin-2-yl cyclohexanecarboxylate 

Downstream Products

• 18869-27-7 (2-cyclohexylvinyl)benzene 
• 5653-09-8 2-cyclohexyl-1-phenylethan-1-one 
• 166281-60-3 3-(2-Cyclohexyl-1-phenylethyl)-4-hydroxycoumarin 
• 18869-27-7 (E)-(2-cyclohexylvinyl)benzene 

Relevant articles and documents

Asymmetric transfer hydrogenation of unsaturated ketones; factors influencing 1,4- vs 1,2- regio- and enantioselectivity, and alkene vs alkyne directing effects

A detailed study has been completed on the asymmetric transfer hydrogenation (ATH) of a series of enones using Ru(II) catalysts. Electron-rich rings adjacent to the C[dbnd]O group reduce the level of C[dbnd]O reduction compared to C[dbnd]C. The ATH reaction can readily discriminate between double and triple bonds adjacent to ketones, reducing the double bond but leaving a triple bond intact in the major product.

Nickel-Catalyzed Stereoselective Arylboration of Unactivated Alkenes

A Ni-catalyzed method for arylboration is disclosed. The method allows for highly stereoselective arylboration of unactivated alkenes. The reactions utilize a simple Ni-catalyst and work with a broad range of alkenes and aryl bromides. The products represent useful intermediates for chemical synthesis due to the versatility of the C-B bond. Preliminary mechanistic details of the method are also disclosed.

Clean borrowing hydrogen methodology using hydrotalcite supported copper catalyst

The catalytic activity of Mg-Al hydrotalcite supported copper catalyst was investigated for clean CC and CN bond forming reactions using alcohols as alkylating agent via borrowing hydrogen methodology. The catalyst showed excellent conversion of ketone and amine substrates (71-99%) to alkylated products with high selectivity in alkylation reactions.