4513-75-1Relevant academic research and scientific papers
Silver(I) ion-mediated desulfurization-condensation of carbon disulfide with some hydroxyl compounds
Shibuya, Isao,Gama, Yasuo,Shimizu, Masao
, p. 461 - 464 (1998)
The title reaction with ethanol and phenol gave tetraethyl and tetraphenyl orthocarbonate, respectively, in good yields. Diols, such as benzene-1,2-dimethanol, wieso-hydrobenzoin, and cathecol, afforded spiro orthocarbonic acid esters. In the same manner, 2-anilinoethanol, N-methylanthranilic acid, and salicylic acid led to some novel spirobicycles.
Method for making diaryl carbonate
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, (2008/06/13)
Diaryl carbonate is prepared by hydrolysis of a tetraaryl orthocarbonate in the presence of an acid catalyst. The tetraaryl orthocarbonate is synthesized by a reaction between carbon disulfide and a cuprous phenate; the cuprous phenate can be made from cuprous chloride and the corresponding alkali metal phenate. The process may be integrated with recycle of by-products.
SYNTHESIS OF ARYL ORTHOCARBONATES
Narasimhamurthy, N.,Samuelson, A. G.
, p. 991 - 992 (2007/10/02)
A simple and efficient method of preparing tetraaryl orthocarbonates from copper phenoxide and carbon disulfide is described.
Some Reactions of Trichloromethanesulfenyl Chloride with Alcohols and Thiols
Islam, Nafisa B.,Kwart, Harold,Khan, S.
, p. 509 - 512 (2007/10/02)
Four new trichloromethyl disulfides, four alkyl orthocarbonates, and two trithiocarbonates have been synthesized and have been characterized by physical, spectral, and analytical properties.
