Heterocycles p. 461 - 464 (1998)
Update date:2022-08-11
Topics:
Shibuya, Isao
Gama, Yasuo
Shimizu, Masao
The title reaction with ethanol and phenol gave tetraethyl and tetraphenyl orthocarbonate, respectively, in good yields. Diols, such as benzene-1,2-dimethanol, wieso-hydrobenzoin, and cathecol, afforded spiro orthocarbonic acid esters. In the same manner, 2-anilinoethanol, N-methylanthranilic acid, and salicylic acid led to some novel spirobicycles.
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