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4610-69-9

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4610-69-9 Usage

Description

cis-Ethyl Cinnamate (contains up to 10% Ethyl dihydrocinnamate) is a colorless oil compound with the CAS number 4610-69-9. It is primarily used in organic synthesis and is known for its unique chemical properties.

Uses

Used in Organic Synthesis:
cis-Ethyl Cinnamate (contains up to 10% Ethyl dihydrocinnamate) is used as a key intermediate in the synthesis of various organic compounds. Its chemical properties make it a versatile building block for creating a wide range of molecules with different applications across various industries.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, cis-Ethyl Cinnamate (contains up to 10% Ethyl dihydrocinnamate) is used as a starting material for the development of new drugs. Its unique chemical structure allows for the creation of novel therapeutic agents with potential applications in treating various diseases and medical conditions.
Used in Flavor and Fragrance Industry:
cis-Ethyl Cinnamate (contains up to 10% Ethyl dihydrocinnamate) is also utilized in the flavor and fragrance industry due to its distinct aromatic properties. It serves as a valuable component in the formulation of various scents and flavors, contributing to the overall sensory experience of consumer products.
Used in Chemical Research:
In the field of chemical research, cis-Ethyl Cinnamate (contains up to 10% Ethyl dihydrocinnamate) is employed as a model compound for studying various reaction mechanisms and exploring new synthetic routes. Its unique properties make it an ideal candidate for understanding the behavior of similar compounds and developing innovative methodologies in organic chemistry.

Check Digit Verification of cas no

The CAS Registry Mumber 4610-69-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,6,1 and 0 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 4610-69:
(6*4)+(5*6)+(4*1)+(3*0)+(2*6)+(1*9)=79
79 % 10 = 9
So 4610-69-9 is a valid CAS Registry Number.

4610-69-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name ethyl (Z)-cinnamate

1.2 Other means of identification

Product number -
Other names cis-Ethyl Cinnamate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:4610-69-9 SDS

4610-69-9Relevant articles and documents

Schrock,Osborne

, p. 2143,2144, 2146 (1976)

Synthesis and characterization of isomeric 2,5-dimethyl-6-phenyl-3-cyclohexene-1-methanol analogs

Coppola, Gary M.,Damon, Robert E.,Shapiro, Michael J.,Gunderson, Karl G.,Kolpak, Michael X.

, p. 75 - 80 (2000)

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Synthesis of new adamantyl-imine palladium(II) complexes and their application in Mizoroki-Heck and Suzuki-Miyaura C[sbnd]C cross-coupling reactions

Makhubela, Banothile C. E.,Matsheku, Asanda C.,Maumela, Munaka C.

, (2021/06/18)

Improving carbon–carbon cross-coupling reactions is an ongoing process and finding the most versatile and stable catalyst precursors has been of great interest. Ligand design has been proven to be important since it is responsible for providing electron density and steric saturation around the metal centre, thus contributing towards the stereo-electronic properties. The adamantyl moiety has been used to generate highly bulky and electron-rich ligands for application in palladium-catalysed cross-coupling reactions. Accordingly, we have prepared some Schiff-base adamantyl ligands (L1-L3) and complexed them with [PdCl2(MeCN)2] to afford the (pre)catalysts C1-C3, which were successfully applied in Mizoroki-Heck and Suzuki-Miyaura carbon–carbon cross-coupling reactions. The cross-coupling reaction products were obtained in good yields using 0.5 mol % Pd catalyst loading. C2 and C3 showed remarkable activity in the Mizoroki-Heck coupling reactions involving substrates with substituents on the olefin and aryl halide (including 4-Cl, 4-CH3, -CO2Me and -CO2Et). We also, observed that the Suzuki-Miyaura cross-coupling system was active towards challenging activated and deactivated aryl chlorides, with to up 70% conversions recorded. The mercury poisoning tests conducted revealed that the catalysts act as homogenous molecular active species in the Mizoroki-Heck reactions and act as both homogenous and heterogeneous catalysts in the Suzuki-Miyaura cross-coupling reactions.

Z-Selective phosphine promoted 1,4-reduction of ynoates and propynoic amides in the presence of water

Drikermann, Denis,Kupfer, Stephan,Seifert, Fabian,Steinmetzer, Johannes,Vilotijevic, Ivan,Zi, You

supporting information, p. 6092 - 6097 (2021/07/21)

Phosphine-mediated reductions of substituted propynoic esters and amides in the presence of water yield the partially reduced α,β-unsaturated esters and amides with highZ-selectivity. The competitivein situ ZtoE-isomerization of the product in some cases lowers theZtoEratios of the isolated α,β-unsaturated carbonyl products. Reaction time and the amounts of phosphine and water in the reaction mixture are the key experimental factors which control the selectivity by preventing or reducing the rates ofZ- toE-product isomerization. Close reaction monitoring enables isolation of theZ-alkenes with high selectivities. The computational results suggest that the reactions could be highlyZ-selective owing to the stereoselective formation of theE-P-hydroxyphosphorane intermediate.

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