49615-87-4

Basic information

• Product Name: (4-BROMO-PHENYL)-OXO-ACETALDEHYDE OXIME
• Synonyms: (4-BROMO-PHENYL)-OXO-ACETALDEHYDE OXIME
• CAS NO: 49615-87-4
• Molecular Formula: C₈H₆BrNO₂
• Molecular Weight: 228.04
• Mol File: 49615-87-4.mol
• Article Data: 2

Chemical Properties

• Melting Point: 148 °C
• Boiling Point: 373.0±44.0 °C(Predicted)
• Appearance: /
• Density: 1.57±0.1 g/cm3(Predicted)
• PKA: 8.14±0.10(Predicted)
• CAS DataBase Reference: (4-BROMO-PHENYL)-OXO-ACETALDEHYDE OXIME(CAS DataBase Reference)
• NIST Chemistry Reference: (4-BROMO-PHENYL)-OXO-ACETALDEHYDE OXIME(49615-87-4)
• EPA Substance Registry System: (4-BROMO-PHENYL)-OXO-ACETALDEHYDE OXIME(49615-87-4)

Safety Data

• Hazardous Substances Data: 49615-87-4(Hazardous Substances Data)

Upstream product

• 99-90-1 para-bromoacetophenone 
• 110-46-3 isopentyl nitrite 
• 126629-81-0 methyl 3-(4-bromophenyl)-3-oxopropanoate 
• 71559-14-3 2-azido-1-(4-bromophenyl)ethanone 

Downstream Products

• 77851-92-4 Cu(p-BrC₆H₄COCHNO)2 
• 49615-71-6 4-(4-bromophenyl)-1,2,5-oxadiazol-3-amine 
• 5467-72-1 α-amino-4-bromoacetophenone hydrochloride 
• 80352-42-7 1-(4-bromophenyl)-2,2-dihydroxyethanone 
• 41147-82-4 4-Bromophenylethanolamine 
• 86435-90-7 (4-bromo-phenyl)-glyoxal dioxime 

Relevant articles and documents

Site-selective conversion of azido groups at carbonyl α-positions into oxime groups leading triazide to a triple click conjugation scaffold

This paper reports the selective conversion of alkyl azido groups at the carbonyl α-position into oximes through β-elimination of dinitrogen, followed by transoximation. With this method and diazo conversion, a triazido molecule was transformed into a triple click conjugation scaffold allowing one-pot four-component coupling.