5170-76-3

Basic information

• Product Name: Benzenemethanol, a-(1-methylethylidene)-, acetate
• CAS NO: 5170-76-3
• Molecular Formula: C12H14O2
• Molecular Weight: 190.242
• Mol File: 5170-76-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-(1-methylethylidene)-, acetate(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-(1-methylethylidene)-, acetate(5170-76-3)
• EPA Substance Registry System: Benzenemethanol, a-(1-methylethylidene)-, acetate(5170-76-3)

Safety Data

• Hazardous Substances Data: 5170-76-3(Hazardous Substances Data)

Upstream product

• 39158-85-5 2-methyl-1-phenyl-1-trimethylsiloxy-1-propene 
• 75-36-5 acetyl chloride 
• 10409-54-8 2-bromo-2-methyl-1-phenyl-propan-1-one 
• 108-24-7 acetic anhydride 
• 611-70-1 phenyl isopropyl ketone 
• 108-22-5 Isopropenyl acetate 

Downstream Products

• 54266-23-8 (t-C₄H₉)2SbOC(C₆H₅)C(CH₃)2 
• 769-60-8 2-methyl-1-phenylprop-2-en-1-one 
• 39158-85-5 2-methyl-1-phenyl-1-trimethylsiloxy-1-propene 
• 100649-48-7 2-methyl-1-phenylpropan-1-one-2-d 
• 611-70-1 phenyl isopropyl ketone 
• 7476-41-7 2-methyl-1-oxo-1-phenylpropan-2-yl acetate 
• 127-19-5 N,N-dimethyl acetamide 
• 7473-98-5 2-hydroxy-2-methylpropiophenone 
• 71057-10-8 2-fluoro-2-methyl-1-phenylpropan-1-one 

Relevant articles and documents

Iodine(III)-Mediated Oxidative Hydrolysis of Haloalkenes: Access to α-Halo Ketones by a Release-and-Catch Mechanism

An unprecedented iodine(III)-mediated oxidative transposition of vinyl halides has been accomplished. The products obtained, α-halo ketones, are useful and polyvalent synthetic precursors. There are only a handful of reported examples of the direct conversion of vinyl halides to their corresponding α-halo carbonyl compounds. Insights into the mechanism and demonstration that this synthetic transformation can be done under enantioselective conditions are reported.

First catalytic C-acylation of enoxysilanes: An efficient route to β-diketones

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ACYLATION OF α-BROMINATED KETONES IN THE PRESENCE OF ZINC

The acylation of α-bromo ketones in the presence of zinc takes place preferentially at the O-reaction center of the intermediate organozinc compound.