51770-93-5

Upstream product

• 35523-91-2 2,4-dimethylphenyl azide 
• 769-53-9 N,N,2,4-tetramethylaniline 
• 13021-13-1 N,2,4-trimethylaniline 
• 70853-94-0 N-(2,4-dimethylphenyl)hydroxylamine 
• 95-68-1 2,4-Xylidine 
• 917-54-4 methyllithium 
• 553-97-9 2-Methyl-1,4-benzoquinone 
• 75-16-1 methylmagnesium bromide 
• 75-09-2 dichloromethane 
• 7722-84-1 dihydrogen peroxide 
• 108-38-3 m-xylene 
• 407-25-0 trifluoroacetic anhydride 
• 89-87-2 2,4-dimethylnitrobenzene 
• 105-67-9 2,4-Xylenol 

Downstream Products

• 615-90-7 2,5-dimethylhydroquinone 
• 105-67-9 2,4-Xylenol 
• 137-18-8 2,5-Dimethyl-1,4-benzoquinone 
• 15191-36-3 2-bromo-4,6-dimethylphenol 
• 74571-80-5 5-bromo-2,4-dimethylphenol 
• 56961-14-9 5-chloro-2,4-dimethylphenol 
• 6641-04-9 6-chloro-2,4-dimethylphenol 
• 502186-53-0 3-chloro-2,5-dimethyl-hydroquinone 
• 26567-10-2 2,2'-dihydroxy-3,3',5,5'-tetramethylbiphenyl 
• 1349842-43-8 tert-butyl (1,3-dimethyl-4-oxocyclohexa-2,5-dien-1-yl) malonate 

Relevant academic research and scientific papers

Oxidative de-aromatization of para-alkyl phenols into para-peroxyquinols and para-quinols mediated by oxone as a source of singlet oxygen

(Chemical Equation Presented) Easy does it: Easily handled and environmentally safe oxone generates singlet oxygen which effects the simple and selective oxidative de-aromatization of para-alkyl phenols 1 into para-peroxyquinols 2 under very mild conditions with good to excellent yields. A one-pot access to para-quinols 3 from 1 is also possible after treatment of the crude reaction mixture with sodium thiosulfate.

Novel one-pot synthesis of acetoxy-2,4-cyclohexadienones

A new, simple, one-pot method for the oxidative acetylation of some substituted phenols leading to acetoxycyclohexa-2,4-dienones is described. A novel diacetoxycyclohexadienone 12 has also been prepared using the present method from 2-hydroxymethyl phenol (salicyl alcohol). Copyright Taylor & Francis, Inc.

A Simple and Efficient Procedure for the Preparation of p-Quinols by Hypervalent Iodine Oxidation of Phenols and Phenol Tripropylsilyl Ethers

Oxidation of para-substituted phenols with benzene (BTIB) in aqueous acetonitrile at 0 deg C gives p-quinols in moderate to good yields; higher yields are obtained when tripropylsilyl ethers of phenols are used.

Selective Reactions of Carbanions with p-Quinones. The Aggregate Model

Additions of carbanions to unsymmetrical p-quinones can be achieved at either carbonyl carbon by a judicious choice of reaction conditions.