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Tris[N-phenylformamidomethyl]amine, also known as tris(N-phenylformamidomethyl)amine or TNP-F3, is a chemical compound with the molecular formula C21H24N4O3. It is a trivalent amine derivative, where three N-phenylformamidomethyl groups are attached to a central nitrogen atom. tris[N-phenylformamidomethyl]amine is often used as a ligand in coordination chemistry, particularly in the formation of metal complexes. It is known for its ability to chelate metal ions, which can be useful in various applications such as catalysis, sensing, and materials science. The compound's structure provides a stable platform for metal binding, and its phenyl groups can participate in π-π interactions, which can influence the properties of the resulting complexes.

51912-07-3

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51912-07-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 51912-07-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,1,9,1 and 2 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 51912-07:
(7*5)+(6*1)+(5*9)+(4*1)+(3*2)+(2*0)+(1*7)=103
103 % 10 = 3
So 51912-07-3 is a valid CAS Registry Number.

51912-07-3Downstream Products

51912-07-3Relevant academic research and scientific papers

Reactions of Trimethylsilylmethyl Azide with Aromatic Acid Derivatives Catalyzed by Fluoride Ion

Nishiyama, Kozaburo,Mikuni, Hioruki,Harada, Mari

, p. 3381 - 3382 (1985)

The treatment of an aromatic acid halide with trimethylsilylmethyl azide (TMSMA) in the presence of potassium fluoride and crown ether gave triazine, methanediamine, and benzamide derivatives, while the reaction of acid anhydride with TMSMA gave tertiary amine together with methanediamine and benzamide under similar conditions.

Outer-sphere coordination chemistry: Amido-ammonium ligands as highly selective tetrachloridozinc(II)ate extractants

Turkington, Jennifer R.,Cocalia, Violina,Kendall, Katrina,Morrison, Carole A.,Richardson, Patricia,Sassi, Thomas,Tasker, Peter A.,Bailey, Philip J.,Sole, Kathryn C.

, p. 12805 - 12819 (2013/02/22)

Eight new amido functionalized reagents, L1-L8, have been synthesized containing the sequence of atoms R2N-CH 2-NR′-CO-R″, which upon protonation forms a six-membered chelate with a hydrogen bond between the ter

Reactions of (benzamidomethyl)triethylammonium chloride with some inorganic nucleophiles in aqueous media

Popovski, Emil,Bogdanov, Jane,Najdoski, Metodija,Hey-Hawkins, Evamarie

, p. 279 - 285 (2007/10/03)

A variety of benzamidomethyl derivatives were prepared in water under alkaline conditions (pH>9) via reaction of (benzamidomethyl)triethylammonium chloride (1) with different inorganic nucleophiles. Reaction of 1 with hydroxylamine did not give the expect

Benzamidomethylation with (benzamidomethyl)triethylammonium chloride. 2. A simple method for benzamidomethylation of thiols, amines and carboxylic acids

Popovski, Emil,Klisarova, Ljiljana,Vikic-Topic, Drazen

, p. 927 - 936 (2007/10/03)

Thiols and amines were benzamidomethylated in water solution at room temperature with (benzamidomethyl)triethylammonium chloride (1) in the presence of a small quantity of triethylamine (pH>9). Benzamidomethyl thioethers (3a-d) and (benzamidomethyl)amines or di(benzamidomethyl)amines (5) were obtained in high yields (>90%) as well as S(CH2NHBz)2 in a reaction of 1 with Na2S. Benzamidomethyl esters RCOOCH 2NHBz were obtained (60-75%) in reactions of carboxylic acids with 1 in chloroform or dioxane.

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