53498-47-8

Basic information

• Product Name: N-(4-VINYL-PHENYL)-ACETAMIDE
• Synonyms: N-(4-VINYL-PHENYL)-ACETAMIDE;AcetaMide, N-(4-ethenylphenyl)-;N-(4-ethenylphenyl)acetamide
• CAS NO: 53498-47-8
• Molecular Formula: C₁₀H₁₁NO
• Molecular Weight: 161.20044
• Mol File: 53498-47-8.mol
• Article Data: 20

Chemical Properties

• Melting Point: 133-134 °C(Solv: isopropanol (67-63-0))
• Boiling Point: 344.8±21.0 °C(Predicted)
• Appearance: /
• Density: 1.085±0.06 g/cm3(Predicted)
• PKA: 14.91±0.70(Predicted)
• CAS DataBase Reference: N-(4-VINYL-PHENYL)-ACETAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-VINYL-PHENYL)-ACETAMIDE(53498-47-8)
• EPA Substance Registry System: N-(4-VINYL-PHENYL)-ACETAMIDE(53498-47-8)

Safety Data

• Hazardous Substances Data: 53498-47-8(Hazardous Substances Data)

Upstream product

• 1520-21-4 4-vinyl benzylamine 
• 75-36-5 acetyl chloride 
• 35447-83-7 N-(4-ethynylphenyl)acetamide 
• 74-85-1 ethene 
• 622-50-4 4-Acetamido-1-iodobenzene 
• 108-05-4 vinyl acetate 
• 103-88-8 4-bromoacetanilide 
• 3663-34-1 N-(4-ethylphenyl)acetamide 
• 2719-21-3 4-(N-acetylamino)acetophenone 
• 79-10-7 acrylic acid 
• 2554-06-5 2,4,6,8-tetramethyl-2,4,6,8-tetravinyl-cyclotetrasiloxane 
• 539-03-7 N-(4-chlorophenyl)acetamide 
• 141-78-6 ethyl acetate 
• 100-13-0 4-nitrostyrene 

Downstream Products

• 1201553-46-9 N-(4-(undecan-2-yl)phenyl)acetamide 
• 1224713-78-3 N-{4-[(E)-2-(3,5-dimethoxyphenyl)ethenyl]phenyl}acetamide 
• 823804-72-4 N-[4-[(1E)-2-(3,5-dihydroxyphenyl)ethenyl]phenyl]acetamide 
• 122-85-0 para-acetamidobenzaldehyde 
• 122240-37-3 (C₆H₅)3SnCH₂CH₂C₆H₄-p-NHCOCH₃ 

Relevant articles and documents

Nickel-Catalyzed Reductive Cross-Coupling of Aryl Bromides with Vinyl Acetate in Dimethyl Isosorbide as a Sustainable Solvent

A nickel-catalyzed reductive cross-coupling has been achieved using (hetero)aryl bromides and vinyl acetate as the coupling partners. This mild, applicable method provides a reliable access to a variety of vinyl arenes, heteroarenes, and benzoheterocycles, which should expand the chemical space of precursors to fine chemicals and polymers. Importantly, a sustainable solvent, dimethyl isosorbide, is used, making this protocol more attractive from the point of view of green chemistry.

Exploring the nitro group reduction in low-solubility oligo-phenylenevinylene systems: Rapid synthesis of amino derivatives

A small series of amino oligo-phenylenevinylenes (OPVs) were successfully synthesized from their nitro-analogs in a rapid, simple, and highly efficient fashion employing a sodium sulfide/pyridine system as a reducing agent. In this research, classic and sustainable reduction methodologies including NH4HCO2/Zn and a choline chloride/tin (II) chloride deep eutectic solvent (DES) were also evaluated, showing degradation products, incomplete reactivity, and product isolation difficulties in all cases. The straightforward Na2S/pyridine synthetic protocol proved to maintain the E-E stereochemistry of the OPV backbone that has been previously assembled by the Mizoroki–Heck cross-coupling reaction. Also, the optoelectronic properties were determined and discussed, considering the amino group insertion in these conjugated systems as a contribution for future construction of novel materials with applications in supramolecular electronics, light harvesting, and photocatalysis.

First Sustainable Aziridination of Olefins Using Recyclable Copper-Immobilized Magnetic Nanoparticles

The first copper-catalyzed aziridination of olefins using recyclable magnetic nanoparticles is described. Magnetic nanoparticles were modified with dopamine and used as a support to coordinate copper. The methodology was optimized with styrene as olefin a