5447-64-3Relevant academic research and scientific papers
THE FACILE ADDITION OF FLUOROSULFURIC ACID TO AN EPOXIDE
Poorker, Carol S.,Kagan, Jacques
, p. 6405 - 6408 (1985)
Fluorosulfuric acid, a very poor nucleophile, was found to add to several epoxides, yielding 1,3,2-dioxathiolane 2,2-dioxides.These cyclic sulfates could also be obtained by reacting the epoxides with sulfur trioxide.The intermediacy of the fluorosulfate of a 1,2-diol, which readily cyclized in base, has been demonstrated in one case.
Synthesis of novel α,α′,β-trisubstituted β-lactones
Barbaud, Christel,Guerrouache, Mohamed,Guérin, Philippe
, p. 9513 - 9515 (2007/10/03)
A concise and efficient synthesis of α,α′,β-trisubstituted β-lactones is presented. These novel lactones are easily obtained in five steps and will be dedicated to anionic ring opening polymerization.
