
Tetrahedron Letters p. 6405 - 6408 (1985)
Update date:2022-08-11
Topics:
Poorker, Carol S.
Kagan, Jacques
Fluorosulfuric acid, a very poor nucleophile, was found to add to several epoxides, yielding 1,3,2-dioxathiolane 2,2-dioxides.These cyclic sulfates could also be obtained by reacting the epoxides with sulfur trioxide.The intermediacy of the fluorosulfate of a 1,2-diol, which readily cyclized in base, has been demonstrated in one case.
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