54551-72-3

Upstream product

• 42445-05-6 2-bromo-2-(4-chlorophenyl)-1-(4-methoxyphenyl)ethanone 
• 52578-11-7 2-(4-chlorophenyl)-1-(4-methoxyphenyl)ethanone 
• 104-88-1 4-chlorobenzaldehyde 
• 75748-09-3 (4-methoxybenzoyl)trimethylsilane 
• 24588-72-5 2-(4-methoxyphenyl)-1,3-dithiane 
• 1569272-02-1 (4-chlorophenyl)(2-(4-methoxyphenyl)-1,3-dithian-2-yl)methanol 
• 123-11-5 4-methoxy-benzaldehyde 
• 100-66-3 methoxybenzene 
• 1878-66-6 4-chlorophenylacetic Acid 

Downstream Products

• 54945-17-4 1-(4-chlorophenyl)-2-(4-methoxyphenyl)-ethane-1,2-dione 
• 121905-27-9 1-p-methoxyphenyl-2-p-chlorophenyl-2-chloroethanone 
• 104-88-1 4-chlorobenzaldehyde 
• 100-09-4 4-methoxybenzoic acid 
• 464153-68-2 4-(4-chlorophenyl)-5-(4-methoxyphenyl)-1H-imidazole-2(3H)-thione 
• 1415020-23-3 5-(4-chlorophenyl)-4-(4-methoxyphenyl)-2-(methylthio)-1H-imidazole 
• 1446909-43-8 5-(4-chlorophenyl)-4-(4-methoxyphenyl)-1-methyl-2-(methylthio)-1H-imidazole 
• 1569271-72-2 (S)-ethyl 2-(4-chlorophenyl)-2-(4-methoxyphenyl)acetate 
• 1569271-60-8 ethyl 2-(4-chlorophenyl)-2-(4-methoxyphenyl)acetate 

Relevant academic research and scientific papers

Visible Light Enabled Formal Cross Silyl Benzoin Reaction as an Access to α-Hydroxyketones

In this work, a visible-light enabled coupling of acylsilanes with aldehydes to give a range of cross-benzoin type products α-hydroxyketones is described. The reaction could proceed at ambient temperature, with the irradiation of low energy visible light, and without addition of photosensitizer or any other additives. (Figure presented.).

Preparation and Application of α-Imino Ketones through One-Pot Tandem Reactions Based on Heyns Rearrangement

α-Imino ketone is a useful building block for the preparation of α-amino ketones and α-amino alcohols. However, its preparation has been seldomly seen. Herein, a metal-free and operationally simple strategy has been developed to generate α-imino ketones with high regioselectivity. Meanwhile, the method allowed for the preparation of various N,O-ketals with high regioselectivities and diastereoselectivities through cascade reactions in one pot.

Synthesis of chiral α-diarylacetic esters by stereospecific 1,2-aryl migration promoted by in situ generated acetals from benzoins

A simple protocol for the synthesis of α-diarylacetic esters from benzoins is described. In situ generated acetal assists rapid 1,2-aryl migration in a stereospecific manner, paving the way to make enantioenriched α-diarylacetic esters from easily accessi

Convenient and regiospecific method for synthesis of 4,5-diaryl-1-methyl-2- (methylthio)-1H-imidazole

A convenient, high-yielding, regiospecific synthesis of 1H-imidazole-2-thiones ring has been developed. In addition, a series of 4,5-diaryl-1-methyl-2-(methylthio)-1H-imidazoles 8 were synthesized and characterized. The structure of regioisomers was confirmed through nuclear Overhauser effect spectroscopy and NMR spectroscopy. Copyright