54797-42-1

Basic information

• Product Name: Ethanone, 2-(1-oxopropoxy)-1-phenyl-
• CAS NO: 54797-42-1
• Molecular Formula: C11H12O3
• Molecular Weight: 192.214
• Mol File: 54797-42-1.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-(1-oxopropoxy)-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-(1-oxopropoxy)-1-phenyl-(54797-42-1)
• EPA Substance Registry System: Ethanone, 2-(1-oxopropoxy)-1-phenyl-(54797-42-1)

Safety Data

• Hazardous Substances Data: 54797-42-1(Hazardous Substances Data)

Upstream product

• 123-62-6 propionic acid anhydride 
• 582-24-1 1-phenyl-2-hydroxyethanone 
• 802294-64-0 propionic acid 
• 70-11-1 α-bromoacetophenone 
• 98-88-4 benzoyl chloride 
• 108-18-9 diisopropylamine 
• 536-74-3 phenylacetylene 
• 92520-07-5 1-Phenyl-1-(N-propionylamino-)-ethen 
• 98-86-2 acetophenone 
• 75-75-2 methanesulfonic acid 
• 3282-32-4 2-diazo-acetophenone 
• 5659-14-3 4-[(Z)-ethylidene]-3-methyloxetan-2-one 
• 2243-35-8 2-acetoxyacetophenone 
• 137-40-6 sodium proprionate 

Downstream Products

• 25779-13-9 (S)-1-phenyl-1,2-ethanediol 
• 115482-85-4 (+)-2-(propanoyloxy)-2-phenylethanol 
• 115482-82-1 (S)-(+)-2-(propanoyloxy)-1-phenylethanol 
• 582-24-1 1-phenyl-2-hydroxyethanone 
• 214778-19-5 2-ethyl-4-phenyloxazole 
• 138877-10-8 (R)-2-hydroxy-2-phenylethyl propionate 
• 73035-26-4 ethyl 6-amino-5-cyano-2,4-diphenyl-4H-pyran-3-carboxylate 
• 16355-00-3 (R)-1-phenyl-1,2-ethanediol 

Relevant articles and documents

Novel and efficient transformation of enamides into α-acyloxy ketones via an acyl intramolecular migration process

Hydrogen peroxide and anhydride mediated transformation of enamides to afford substituted α-acyloxy ketones is described. This transition-metal-free cascade reaction has a broad substrate scope and high efficiency. The acyl intramolecular migration procedure successfully achieved this acyloxylation process under mild conditions and increased the atom efficiency.

Straightforward and highly efficient synthesis of α-acetoxy ketones through gold-catalyzed intermolecular oxidation of terminal alkynes

A variety of terminal alkynes were efficiently converted into the corresponding α-acetoxy ketones through gold-catalyzed intermolecular oxidation in the presence of 8-methylquinoline 1-oxide as the oxidant. The reaction probably proceeds through an α-oxo gold carbene intermolecular O-H insertion.

The reaction of terminal alkynes with PhI(OAc)2: a convenient procedure for the preparation of α-acyloxy ketones

Treatment of terminal alkynes with PhI(OAc)2 in different acids at 70 °C provided the corresponding α-acyloxy ketones in good to excellent yields. A plausible mechanism has been proposed based on the experimental results.