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557-31-3

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557-31-3 Usage

Chemical Properties

Different sources of media describe the Chemical Properties of 557-31-3 differently. You can refer to the following data:
1. CLEAR COLOURLESS LIQUID
2. Allyl ethyl ether is an extremely flammable liquid.

Uses

Allyl ethyl ether is used as an intermediate to manufacture other chemicals.

General Description

A liquid. Flash point below 75°F. Insoluble in water and less dense than water. Hence floats on water. Emits acrid irritating fumes when heated to high temperature. Used to make other chemicals.

Potential Exposure

Used for making other chemicals

Shipping

UN2335 Allyl ethyl ether, Hazard Class: 3; Labels: 3-Flammable liquid, 6.1-Poisonous materials

Incompatibilities

May form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Incompatible with strong acids. May form explosive peroxides during storage

Check Digit Verification of cas no

The CAS Registry Mumber 557-31-3 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 5,5 and 7 respectively; the second part has 2 digits, 3 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 557-31:
(5*5)+(4*5)+(3*7)+(2*3)+(1*1)=73
73 % 10 = 3
So 557-31-3 is a valid CAS Registry Number.
InChI:InChI=1/C5H10O/c1-3-5-6-4-2/h3H,1,4-5H2,2H3

557-31-3 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (B22276)  Allyl ethyl ether, 98%   

  • 557-31-3

  • 10g

  • 788.0CNY

  • Detail
  • Alfa Aesar

  • (B22276)  Allyl ethyl ether, 98%   

  • 557-31-3

  • 50g

  • 1699.0CNY

  • Detail
  • Aldrich

  • (238228)  Allylethylether  95%

  • 557-31-3

  • 238228-10G

  • 1,272.96CNY

  • Detail
  • Aldrich

  • (238228)  Allylethylether  95%

  • 557-31-3

  • 238228-50G

  • 4,619.16CNY

  • Detail

557-31-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name ALLYL ETHYL ETHER

1.2 Other means of identification

Product number -
Other names 3-ethoxyprop-1-ene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:557-31-3 SDS

557-31-3Relevant articles and documents

-

Benedict,D.R. et al.

, p. 428 - 429 (1979)

-

Hydrogen-bond-activated palladium-catalyzed allylic alkylation via allylic alkyl ethers: Challenging leaving groups

Huo, Xiaohong,Quan, Mao,Yang, Guoqiang,Zhao, Xiaohu,Liu, Delong,Liu, Yangang,Zhang, Wanbin

supporting information, p. 1570 - 1573 (2014/04/17)

C-O bond cleavage of allylic alkyl ether was realized in a Pd-catalyzed hydrogen-bond-activated allylic alkylation using only alcohol solvents. This procedure does not require any additives and proceeds with high regioselectivity. The applicability of this transformation to a variety of functionalized allylic ether substrates was also investigated. Furthermore, this methodology can be easily extended to the asymmetric synthesis of enantiopure products (99% ee).

Rate and product studies on the solvolyses of allyl chloroformate

Koh, Han Joong,Kang, Suk Jin

, p. 4117 - 4121 (2013/08/23)

The solvolysis rate constants of allyl chloroformate (CH 2=CHCH2OCOCl, 3) in 30 different solvents are well correlated with the extended Grunwald-Winstein equation, using the NT solvent nucleophilicity scale and YCl solvent ionizing scale, with the sensitivity values of 0.93 ± 0.05 and 0.41 ± 0.02 for l and m, respectively. These l and m values can be considered to support a S N2 reaction pathway. The activation enthalpies (ΔH≠) were 12.5 to 13.4 kcal·mol-1 and the activation entropies (ΔS≠) were -34.4 to -37.3 cal·mol-1·K -1, which is also consistent with the proposed bimolecular reaction mechanism. The solvent kinetic isotope effect (SKIE, kMeOH/k MeOD) of 2.16 was also in accord with the SN2 mechanism. The values of product selectivity (S) for the solvolyses of 3 in alcohol/water mixtures was 1.3 to 3.9, which is also consistent with the proposed bimolecular reaction mechanism.

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