56119-91-6

Basic information

• Product Name: 1H-Pyrazole, 3-(4-methoxyphenyl)-1-methyl-5-phenyl-
• CAS NO: 56119-91-6
• Molecular Formula: C17H16N2O
• Molecular Weight: 264.327
• Mol File: 56119-91-6.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 1H-Pyrazole, 3-(4-methoxyphenyl)-1-methyl-5-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Pyrazole, 3-(4-methoxyphenyl)-1-methyl-5-phenyl-(56119-91-6)
• EPA Substance Registry System: 1H-Pyrazole, 3-(4-methoxyphenyl)-1-methyl-5-phenyl-(56119-91-6)

Safety Data

• Hazardous Substances Data: 56119-91-6(Hazardous Substances Data)

Upstream product

• 60-34-4 methylhydrazine 
• 20442-66-4 3-(4-methoxyphenyl)-1-phenylprop-2-yn-1-one 
• 16616-43-6 1-(4-methoxy-phenyl)-3-phenyl-propynone 
• 696-62-8 para-iodoanisole 
• 536-74-3 phenylacetylene 
• 413582-56-6 N-methyl-N'-(4'-methoxybenzylidene)-4-methylbenzenesulfonohydrazide 
• 591-50-4 iodobenzene 
• 201230-82-2 carbon monoxide 
• 100-07-2 4-methoxy-benzoyl chloride 
• 959-23-9 4'-methoxychalcone 
• 768-60-5 4-methoxyphenylacetylen 
• 86389-36-8 3-(4-methoxyphenyl)-1-methyl-5-phenyl-4,5-dihydro-1H-pyrazole 
• 1226790-02-8 3,3-dibromo-1-(4-methoxyphenyl)prop-2-en-1-one 
• 57-14-7 N,N-Dimethylhydrazine 

Downstream Products

• 1270943-09-3 3-(4-methoxyphenyl)-1-methyl-5-phenyl-4-p-tolyl-1H-pyrazole 
• 1270943-10-6 3,4-bis(4-methoxyphenyl)-1-methyl-5-phenyl-1H-pyrazole 
• 1270943-14-0 4-(3-(4-methoxyphenyl)-1-methyl-5-phenyl-1H-pyrazol-4-yl)pyridine 
• 1270943-00-4 4-chloro-3-(4-methoxyphenyl)-1-methyl-5-phenyl-1H-pyrazole 
• 1270943-03-7 4-bromo-3-(4-methoxyphenyl)-1-methyl-5-phenyl-1H-pyrazole 
• 1270943-06-0 4-(3-(4-methoxyphenyl)-1-methyl-5-phenyl-1H-pyrazol-4-yl)benzaldehyde 

Relevant articles and documents

Preparation method for pyrazole

The invention relates to a preparation method for pyrazole, belonging to the field of organic chemistry. The preparation method disclosed in the invention realizes preparation of pyrazole through a cyclization reaction of N-alkylated phenylsulfonylhydrazone with terminal alkyne. The reaction has good function group tolerance and high yield and is applicable to a wide range of substrates.

Regioselective synthesis of 1,3,5-Trisubstituted Pyrazoles from N-Alkylated Tosylhydrazones and terminal Alkynes

An efficient synthesis of 1,3,5-trisubstituted pyrazoles from Nalkylated tosylhydrazones and terminal alkynes was developed. The protocol was applied to a wide range of substrates and demonstrated excellent tolerance to a variety of substituents, includin

The preparation of substituted pyrazoles from β,β-dibromo-enones by a tandem condensation/Suzuki-Miyaura cross-coupling process

Two consecutive tandem processes are described for the regioselective, two-step synthesis of 1,3,5-trisubstituted pyrazoles from α- hydroxyketones. The first, a tandem MnO2-mediated oxidation/Ramirez olefination reaction, provides a facile route to β,β-dibromo-enones. These valuable 1,3-dicarbonyl synthons can then be converted into 1,3,5-trisubstituted pyrazoles via a second tandem hydrazine condensation/Suzuki-Miyaura cross-coupling reaction. Using these procedures, a range of aryl and alkyl α-hydroxyketones have been transformed regioselectively into 1,3,5-trisubstituted pyrazoles. Georg Thieme Verlag Stuttgart.