57020-97-0Relevant academic research and scientific papers
A three-component palladium-catalyzed oxidative C-C coupling reaction: A domino process in two dimensions
Nimje, Roshan Y.,Leskinen, Mikko V.,Pihko, Petri M.
supporting information, p. 4818 - 4822 (2013/06/04)
Easy as ABC. or CBA! Indoles can be selectively functionalized twice by a catalytic oxidative three-component coupling of arylboronates and β-ketoesters. The difference in the rates (see scheme) of the competing processes are amplified under the conditions of the three-component reaction. Copyright
Palladium-catalyzed dehydrogenative β′-arylation of β-keto esters under aerobic conditions: Interplay of metal and Bronsted acids
Yip, Kai-Tai,Nimje, Roshan Y.,Leskinen, Mikko V.,Pihko, Petri M.
supporting information, p. 12590 - 12594 (2012/11/13)
The Bronsted aids: The first dehydrogenative arylation of β-keto esters with arenes under ambient aerobic conditions is described (see scheme). Under a PdII/Bronsted acid co-catalytic system, regioselective arylations with alkoxylated arenes an
