57772-77-7

Basic information

• Product Name: Benzenepropanoic acid, a-butyl-, ethyl ester
• CAS NO: 57772-77-7
• Molecular Formula: C15H22O2
• Molecular Weight: 234.338
• Mol File: 57772-77-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenepropanoic acid, a-butyl-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepropanoic acid, a-butyl-, ethyl ester(57772-77-7)
• EPA Substance Registry System: Benzenepropanoic acid, a-butyl-, ethyl ester(57772-77-7)

Safety Data

• Hazardous Substances Data: 57772-77-7(Hazardous Substances Data)

Upstream product

• 100-44-7 benzyl chloride 
• 28744-77-6 sodium diethyl-2-phenylmalonate 
• 42361-33-1 diethyl 2-benzyl-2-butylmalonate 
• 4375-38-6 benzyl-butyl-malonic acid 
• 100-52-7 benzaldehyde 
• 615-96-3 Ethyl 2-bromohexanoate 
• 302571-66-0 ethyl 2-bromo-2-butyl-3-hydroxy-3-phenylpropanoate 
• 81787-39-5 ethyl (E)-2-butyl-3-phenylpropenoate 
• 109-65-9 1-bromo-butane 
• 1009-61-6 1,4-Diacetylbenzene 
• 103-36-6 ethyl 3-phenyl-2-propenoate 
• 100-39-0 benzyl bromide 
• 133-08-4 diethyl butylmalonate 
• 13608-28-1 4,4-dimethyl-2-(2-phenylethyl)-4,5-dihydro-1,3-oxazole 

Relevant articles and documents

Synthesis of 2,3-dideuterioesters from 2-halo-3-hydroxyesters by using metallic samarium and diiodomethane

2,3-Dideuterioesters are obtained in high yield from 2-chloro-3-hydroxyesters by a sequenced elimination/reduction process promoted by samarium diiodide generated in situ from metallic samarium and diiodomethane.

Kinetic studies of the homogeneous coupling reaction between electrochemically generated aromatic radical anions and alkyl radicals

Radicals produced via the indirect reduction of alkyl halides by aromatic radical anions are likely to couple fast with the mediator. In the presence of activated olefins or good hydrogen atom donors the fate of the alkyl radicals might be changed. In this study rate constants for the coupling reaction (2) between primary, secondary and tertiary alkyl radicals and some aromatic radical anions were measured via the competition with addition of the radical to styrene or ethyl cinnamate, or via the competition with hydrogen atom transfer from thiophenol or 2-methyl-2-propanethiol to the alkyl radical. It is shown that for all the alkyl radicals and aromatic radical anions investigated so far the rate constant for coupling is close to 1 × 109 M-1 s-1. Acta Chemica Scandinavica 1998.