58321-79-2

Basic information

• Product Name: (Z)-2-Nitro-1-phenyl-1-propene
• Synonyms: (Z)-1-Phenyl-2-nitro-1-propene;(Z)-2-Nitro-1-phenyl-1-propene;[(Z)-2-Nitro-1-propenyl]benzene;[(Z)-2-nitroprop-1-enyl]benzene
• CAS NO: 58321-79-2
• Molecular Formula: C₉H₉NO₂
• Molecular Weight: 163.17
• Mol File: 58321-79-2.mol
• Article Data: 61

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (Z)-2-Nitro-1-phenyl-1-propene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-2-Nitro-1-phenyl-1-propene(58321-79-2)
• EPA Substance Registry System: (Z)-2-Nitro-1-phenyl-1-propene(58321-79-2)

Safety Data

• Hazardous Substances Data: 58321-79-2(Hazardous Substances Data)

Upstream product

• 79-24-3 Nitroethane 
• 100-52-7 benzaldehyde 
• 26251-08-1 2-nitro-1-phenylpropan-1-ol 
• 60593-26-2 (1-nitroethyl)-phosphonic acid diethyl ester 
• 66618-80-2 acetic acid-((1RS,2RS)-2-nitro-1-phenyl-propyl ester) 
• 637-50-3 1-phenylpropene 
• 705-60-2 1-phenyl-2-nitroprop-1-ene 
• 705-60-2 (2-nitroprop-1-enyl)benzene 
• 66618-80-2 1-phenyl-2-nitro-1-propanol acetate 
• 873-66-5 1-propenylbenzene 
• 1895-97-2 2-methyl-3-phenylacrylic acid 
• 766-90-5 cis-1-phenyl-1-propylene 
• 90558-08-0 2,3-dinitro-3-phenyl propane 
• 75-52-5 nitromethane 

Downstream Products

• 408314-96-5 5-methyl-5-nitro-4-phenyl-4,5-dihydro-1H-pyrazole 
• 93159-92-3 (2-oxo-1-phenyl-propyl)-malonic acid diethyl ester 
• 546103-01-9 2-acetyl-4-nitro-3-phenyl-valeric acid ethyl ester 
• 92851-01-9 (2-nitro-1-phenyl-propyl)-phenyl sulfide 
• 28612-56-8 4-[8-(2-nitro-1-phenyl-propyl)-cyclooct-1-enyl]-morpholine 
• 28557-75-7 3-methyl-7a-morpholin-4-yl-4-phenyl-4,4a,5,6,7,7a-hexahydro-cyclopenta[e][1,2]oxazine 2-oxide 
• 4345-49-7 3,5-dimethyl-4-phenyl-1H-pyrazole 
• 120290-02-0 2,4-dinitro-3-phenylpentane 
• 120290-02-0 2,4-dinitro-3-phenylpentane 
• 86770-62-9 4a,5,6,7,8,8a-hexahydro-3-methyl-8-oxo-8a-(1-piperidinyl)-4-phenyl-4H-1,2-benzoxazine N-oxide 
• 86770-63-0 4a,5,6,7,8,8a-hexahydro-3-methyl-8-oxo-4-phenyl-8a-(1-pyrrolidinyl)-4H-1,2-benzoxazine N-oxide 
• 83465-95-6 (4R,4aS,6S,8aS)-6-tert-Butyl-3-methyl-4-phenyl-8a-pyrrolidin-1-yl-4a,5,6,7,8,8a-hexahydro-4H-benzo[e][1,2]oxazine 2-oxide 

Relevant articles and documents

Dipolar HCP materials as alternatives to DMF solvent for azide-based synthesis

Hypercrosslinked polymers HCP-DMF and HCP-DMF-SO3H containing abundant and flexible DMF moieties were designed and synthesized. Benefitting from the solvation microenvironment provided by the pseudo-DMF moities, the polar HCPs manifested outstanding performances in the conversions of NaN3 to benzylic azides and 1,2,3-triazoles in EtOH (95%), respectively, avoiding the use of risky DMF and improving the separation processes of the products.

Catalyst- and Substituent-Controlled Switching of Chemoselectivity for the Enantioselective Synthesis of Fully Substituted Cyclobutane Derivatives via 2 + 2 Annulation of Vinylogous Ketone Enolates and Nitroalkene

The first regioselective, diastereoselective, and enantioselective organocatalyzed Michael-Michael cascade of vinylogous ketone enolates and nitroalkenes for the construction of fully substituted cyclobutanes is achieved by the deployment of the appropriate chiral squaramide catalyst and the pertinent substituent on the substrate. The domino reaction provided cyclobutanes with four contiguous stereocenters, including a quaternary center in good yields with diastereomeric ratio of >20:1 and with enantioselectivities of mostly up to 98% enantiomeric excess (ee). The structures and the absolute configurations of the adducts were confirmed by single-crystal X-ray crystallographic analyses of the appropriate products.

Electronic effect of substituents on anilines favors 1,4-addition to: Trans -β-nitrostyrenes: Access to N -substituted 3-arylindoles and 3-arylindoles

A simple and an efficient method for the regioselective synthesis of N-alkyl/aryl/H 3-arylindole derivatives from N-substituted anilines and trans-β-nitrostyrenes has been described using 10 mol% of bismuth(iii) triflate as a catalyst in acetonitrile at 80 °C. The present protocol profits from the formation of new C-C and C-N bonds, broad substrate scope and moderate to good yields.