78433-55-3

Upstream product

• 6061-13-8 (2S,3S)-3-methylaspartic acid 
• 642-92-2 D,L-threo-β-methylaspartic acid 
• 78479-15-9 (2S,3R)-threo-3-methylbutane-1,2,4-triol 1,2-acetonide 4-benzyl ether 
• 50460-80-5 (2S,3S)-2-Hydroxy-3-methyl-bernsteinsaeuredimethylester 
• 69743-60-8 (2S,3R)-threo-3-methylbutane-1,2,4-triol 1,2-acetonide 
• 77333-42-7 (2S,3R)-threo-3-methylbutane-1,2,4-triol 
• 78433-53-1 (2S,3S)-dimethyl threo-3-methylmalate THP ether 
• 86562-33-6 (2S,3R)-threo-3-methylbutane-1,2,4-triol 2-THP ether 
• 13398-41-9 (2S, 3S)-threo-β-methylmalic acid 
• 78479-16-0 (2S,3R)-threo-3-methylbutane-1,2,4-triol 4-benzyl ether 
• 98-59-9 p-toluenesulfonyl chloride 
• 59005-41-3 (S)-4-Benzyloxy-3-methyl-butane-1,2-diol 

Downstream Products

• 78433-56-4 (2R,3S)-3,4-epoxy-2-methyl-1-butanol benzyl ether 
• 72598-35-7 (-)-serricornin 
• 78433-57-5 (2R,3R)-threo-2-methylpentane-1,3-diol 1-benzyl ether 
• 72485-37-1 (4R,6S,7S)-7-acetoxy-4,6-dimethyl-3-nonanone 
• 82335-98-6 serricornin acetate <(4S,6R,7R)-4,6-dimethyl-7-acetoxy-3-nonanone> 
• 83997-86-8 serricornin acetate <(4S,6S,7S)-4,6-dimethyl-7-acetoxy-3-nonanone> 
• 86562-34-7 (2R,3R)-threo-2-methylpentane-1,3-diol 1-benzyl ether 3-THP ether 
• 86535-17-3 (2R,3R)-threo-2-methylpentane-1,3-diol 1-tosylate 
• 86535-19-5 2-methyl-3-pentanol (R)-(+)-MTPA ester 
• 86535-18-4 2-methyl-3-pentanol (S)-(-)-MTPA ester 
• 86562-36-9 (2R,3R)-threo-2-methylpentane-1,3-diol 3-THP ether 1-tosylate 
• 72522-40-8 (4RS,6R,7R)-threo-serricornin 
• 78433-60-0 (2R,3R)-3-((tert-butyldimethylsilyl)oxy)-2-methylpentyl 4-methylbenzenesulfonate 
• 78433-58-6 ((1R,2R)-3-Benzyloxy-1-ethyl-2-methyl-propoxy)-tert-butyl-dimethyl-silane 

Relevant academic research and scientific papers

THE NITRO-ALDOL REACTION OF α-KETOALDEHYDES WITH NITROALKANES YIELDS α-DIKETONES

The reaction of α-ketoaldehydes with nitroalkanes at pH 9 yields nitro-aldols, which eliminate nitrite to form α-diketones.

SYNTHESIS AND ABSOLUTE STEREOCHEMISTRY OF SERRICORNIN

The absolute stereochemistry of serricornin (4,6-dimethyl-7-hydroxy-3-nonanone) was established as 4S, 6S, 7S by synthesizing both (4S, 6S, 7S)-isomer and its antipode.Only the natural enantiomer was bioactive.by

DETERMINATION OF THE ABSOLUTE CONFIGURATION AT C-6 AND C-7 SERRICORNIN (4,6-DIMETHYL-7-HYDROXY-3-NONANONE), THE SEX PHEROMONE OF THE CIGARETTE BEETLE

The absolute configuration at C-6 and C-7 of serricornin was established as (6S, 7S) by synthesizing its (6R, 7S)-erythro and (6R, 7R)-threo isomers.