59058-17-2Relevant academic research and scientific papers
In situ generated (Hypo)iodite catalysts for the direct α-oxyacylation of carbonyl compounds with carboxylic acids
Uyanik, Muhammet,Suzuki, Daisuke,Yasui, Takeshi,Ishihara, Kazuaki
supporting information; experimental part, p. 5331 - 5334 (2011/07/08)
It′s the iodine: The intra- and intermolecular title reaction is catalyzed by an in situ generated ammonium (hypo)iodite species. Either H 2O2 or tert-butyl hydroperoxide (TBHP) can be used as an environmentally benign oxidant and a wide range of substrates react to give the corresponding α-acyloxycarbonyl compounds in good to excellent yields.
A general method for the α-acyloxylation of carbonyl compounds
Beshara, Cory S.,Hall, Adrian,Jenkins, Robert L.,Jones, Kerri L.,Jones, Teyrnon C.,Killeen, Niall M.,Taylor, Paul H.,Thomas, Stephen P.,Tomkinson, Nicholas C. O.
, p. 5729 - 5732 (2007/10/03)
(Chemical Equation Presented) A simple, one-pot method for the α-acyloxylation of carbonyl compounds that proceeds at room temperature in the presence of both moisture and air has been developed. Treatment of a variety of aldehydes and both cyclic and acy
The first synthesis of threo- and erythro-(E)-4,5-dihydroxydec-2-enals carbonyls related to the peroxidation of liver microsomal lipids
Allevi, Pietro,Cajone, Francesco,Ciuffreda, Pierangela,Anastasia, Mario
, p. 1347 - 1350 (2007/10/02)
The first synthesis of threo and erythro (E)-4,5-dihydroxydec-2-enals, aldehydes related to the lipid peroxidation is accomplished by reaction of α-benzoyloxheptanal with the Grignard reagent of 3,3-diethoxy-1-propyne and lithium aluminium hydride reducti
RESOLUTION AND DETERMINATION OF ENANTIOMERIC EXCESSES OF CHIRAL ALDEHYDES VIA CHIRAL IMIDAZOLIDINES
Mangeney, P.,Alexakis, A.,Normant, J. F.
, p. 2677 - 2680 (2007/10/02)
Enantiomeric purity of chiral aldehydes was determined by NMR analysis of derived imidazolidines.The diastereomeric imidazolidines were easily separated by silica gel column and converted into enantiomerically pure aldehyde by acid hydrolysis.
