59304-30-2Relevant articles and documents
Method for preparing acridine derivative
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Paragraph 0014-0018, (2019/07/16)
The invention relates to a method for preparing an acridine derivative, and specifically relates to a method for preparing the acridine derivative from an organic azide compound and a benzene compoundunder the action of an acid. According to the method disclosed by the invention, no transition metal catalyst is used, and the acridine derivative with an anthracene structure is obtained from a simple and easily-available raw material through simple operation steps.
Nitrogen anthracene class compound and its synthetic method and application (by machine translation)
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Paragraph 0051-0054, (2018/05/16)
The invention discloses a formula (2) shown in nitrogen anthracene class of compound and its synthetic method, high Iodized salt as reaction raw material, in the inorganic nitrogen reagent, additive, water, alkali, under the action of the metal catalyst, in the 80 - 150 °C conditions, reacts in a solvent 12 - 60 hours to obtain various nitrogen anthracene class compounds. The invention by post method of introducing nitrogen atoms, to avoid the early stage in the reaction of the nitrogen heterocyclic to metal catalyst of the reaction conditions such as not compatibility; in addition, high Iodized salt in the full utilization of the two aryl, shows that the method of the invention atom economy. Prepared by the method of the invention can be further applied [...] compound of the fluorescent indicator acridine orange synthesis. (by machine translation)
Rh(III)-Catalyzed bilateral cyclization of aldehydes with nitrosos toward unsymmetrical acridines proceeding with C-H functionalization enabled by a transient directing group
Hu, Weiming,Zheng, Qingheng,Sun, Song,Cheng, Jiang
, p. 6263 - 6266 (2017/07/07)
A Rh(iii)-catalyzed bilateral cyclization was developed for the efficient construction of acridines proceeding with C-H functionalization whereby in situ formation and removal of an imino transient directing group in the presence of catalytic amount of BnNH2 are achieved. In this transformation, a sequential Rh(iii)-catalyzed C-H amination, cyclization, and aromatization process was involved.