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5961-55-7

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5961-55-7 Usage

Chemical Properties

light brown powder or chunks

Uses

4-Methoxy-1-naphthonitrile is used as an intermediate in the synthesis of substituted azocin-2(1H)-ones

Check Digit Verification of cas no

The CAS Registry Mumber 5961-55-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,9,6 and 1 respectively; the second part has 2 digits, 5 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 5961-55:
(6*5)+(5*9)+(4*6)+(3*1)+(2*5)+(1*5)=117
117 % 10 = 7
So 5961-55-7 is a valid CAS Registry Number.
InChI:InChI=1/C12H9NO/c1-14-12-7-6-9(8-13)10-4-2-3-5-11(10)12/h2-7H,1H3

5961-55-7 Well-known Company Product Price

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  • Alfa Aesar

  • (L05354)  4-Methoxy-1-naphthonitrile, 98%   

  • 5961-55-7

  • 5g

  • 663.0CNY

  • Detail
  • Alfa Aesar

  • (L05354)  4-Methoxy-1-naphthonitrile, 98%   

  • 5961-55-7

  • 25g

  • 2137.0CNY

  • Detail

5961-55-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-methoxynaphthalene-1-carbonitrile

1.2 Other means of identification

Product number -
Other names 4-methoxynaphthalenecarbonitrile

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:5961-55-7 SDS

5961-55-7Relevant articles and documents

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Lorz,Baltzly

, p. 93 (1951)

-

Nickel-Catalyzed Transformation of Alkene-Tethered Oxime Ethers to Nitriles by a Traceless Directing Group Strategy

Takahashi, Yoshiyuki,Tsuji, Hiroaki,Kawatsura, Motoi

, p. 2654 - 2665 (2020/02/04)

Nickel-catalyzed transformation of alkene-tethered oxime ethers to nitriles using a traceless directing group strategy has been developed. A series of alkene-tethered oxime ethers derived from benzaldehyde and cinnamyl aldehyde derivatives were converted into the corresponding benzonitriles and cinnamonitriles in 46-98% yields using the nickel catalyst system. Control experiments showed that the alkene group tethered to an oxygen atom on the oximes via one methylene unit plays a key role as a traceless directing group during the catalysis.

Nickel-catalyzed cyanation of aryl halides and triflates using acetonitrile: Via C-CN bond cleavage assisted by 1,4-bis(trimethylsilyl)-2,3,5,6-tetramethyl-1,4-dihydropyrazine

Ueda, Yohei,Tsujimoto, Nagataka,Yurino, Taiga,Tsurugi, Hayato,Mashima, Kazushi

, p. 994 - 999 (2019/02/03)

We developed a non-toxic cyanation reaction of various aryl halides and triflates in acetonitrile using a catalyst system of [Ni(MeCN)6](BF4)2, 1,10-phenanthroline, and 1,4-bis(trimethylsilyl)-2,3,5,6-tetramethyl-1,4-dihydropyrazine (Si-Me4-DHP). Si-Me4-DHP was found to function as a reductant for generating nickel(0) species and a silylation reagent to achieve the catalytic cyanation via C-CN bond cleavage.

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