60785-27-5Relevant academic research and scientific papers
Olefin cross-metathesis with vinyl halides
Sashuk, Volodymyr,Samojlowicz, Cezary,Szadkowska, Anna,Grela, Karol
, p. 2468 - 2470 (2008/12/23)
The first successful example of olefin cross-metathesis with chloroalkenes is reported. The Royal Society of Chemistry.
REGIOSPECIFIC HYDROGEN CHLORIDE ELIMINATION FROM α,β-DICHLOROALKYL PHENYL SULPHIDES
Bellesia, Franco,Ghelfi, Franco,Pagnoni, Ugo Maria,Pinetti, Adriano
, p. 337 - 340 (2007/10/02)
α,β-Dichloroalkyl phenyl sulphides undergo regiospecific hydrogen chloride eliminations to afford α- or β-chloro-1-alkenyl phenyl sulphides in good yields.
HIGH-TEMPERATURE ORGANIC SYNTHESIS. XXXIX. GAS-PHASE REACTION OF THIOPHENOL WITH 1,2-DICHLOROETHENE
Ivanova, N. D.,Korchevin, N. A.,Sigalov, M. V.,Keiko, V. V.,Deryagina, E. N.,Voronkov, M. G.
, p. 572 - 575 (2007/10/02)
Thiophenol reacts with 1,2-dichloroethene (a 3:1 mixture of E and Z isomers) in the gas phase at 400-550 deg C forming phenyl β-chlorovinyl sulfide (E and Z isomers, 1:1) with an overall yield of up to 84percent.The products from its further thermal transformations are benzothiophene. 3-chlorobenzothiophene, 1,2-bis(phenylthio)ethene (a mixture of stereoisomers), and 3-phenylthiobenzothiophene
NEW SYNTHESIS OF VINYL SELENIDES NUCLEOPHILIC SUBSTITUTIONS OF UNACTIVATED VINYL HALIDES BY SELENIDE ANIONS
Tiecco, M.,Testaferri, L.,Tingoli, M.,Chianelli, D.,Montanucci, M.
, p. 4975 - 4978 (2007/10/02)
Alkyl and aryl selenide anions react with unactivated vinyl halides, in dipolar aprotic solvents, to give alkyl or aryl vinyl selenides in good yields.These reactions are stereospecific and occur with retention of configuration.
