61052-15-1

Basic information

• Product Name: (E)-ethyl 3-(2,4-dimethylphenyl)acrylate
• Synonyms: (E)-ethyl 3-(2,4-dimethylphenyl)acrylate
• CAS NO: 61052-15-1
• Molecular Weight: 204.269
• Mol File: 61052-15-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (E)-ethyl 3-(2,4-dimethylphenyl)acrylate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-ethyl 3-(2,4-dimethylphenyl)acrylate(61052-15-1)
• EPA Substance Registry System: (E)-ethyl 3-(2,4-dimethylphenyl)acrylate(61052-15-1)

Safety Data

• Hazardous Substances Data: 61052-15-1(Hazardous Substances Data)

Upstream product

• 141-78-6 ethyl acetate 
• 15764-16-6 2,4-dimethylbenzaldehyde 
• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 623-73-4 diazoacetic acid ethyl ester 
• 16308-92-2 2,4-dimethylbenzyl alcohol 
• 105-36-2 ethyl bromoacetate 
• 64-17-5 ethanol 
• 1685-80-9 2,4-dimethylcinnamic acid 

Downstream Products

• 54443-82-2 C₁₁H₁₄O 
• 54443-82-2 2,4-dimethyl-cinnamyl alcohol 
• 1202576-63-3 (3S)-3-(4-{[(1R)-4,6-dimethyl-2,3-dihydro-1H-inden-1-yl]oxy}phenyl)-3-ethoxypropionic acid 
• 1202578-18-4 (3S)-3-(4-{[(1R)-4,6-Dimethyl-2,3-dihydro-1H-inden-1-yl]oxy}phenyl)-3-ethoxypropan-1-ol 
• 1202578-17-3 {[(3S)-3-(4-{[(1R)-4,6-Dimethyl-2,3-dihydro-1H-inden-1-yl]oxy}phenyl)-3-ethoxypropyl]oxy}(triisopropyl)silane 
• 1685-81-0 4,6-dimethyl-2,3-dihydro-1H-inden-1-one 
• 1811-85-4 3-(2,4-dimethylphenyl)propionic acid 

Relevant articles and documents

Method for synthesizing photoactive bromohydrin compound

The invention discloses a method for synthesizing a photoactive bromohydrin compound, which comprises the following steps: reacting cinnamyl alcohol as shown in a formula I, benzamide bromide as shown in a formula II, a quinine derivative, L-camphorsulfonic acid and water in a first organic solvent to obtain the bromohydrin compound as shown in a formula III. According to the method, raw materials are easy to synthesize, reaction conditions are mild, operation is easy and convenient, the yield reaches up to 47%-87%, enantioselectivity can generally reach 80% or above, and the highest point can even reach 95%.

SYNTHESIS OF FUNCTIONALIZED AND UNFUNCTIONALIZED OLEFINS VIA CROSS AND RING-CLOSING METATHESIS

The invention is directed to the cross-metathesis and ring-closing metathesis reactions between geminal disubstituted olefins and terminal olefins, wherein the reaction employs a Ruthenium or Osmium metal carbene complex. Specifically, the invention relates to the synthesis of alpha-functionalized or unfunctionalized olefins via intermolecular cross-metathesis and intramolecular ring-closing metathesis using a ruthenium alkylidene complex. The catalysts preferably used in the invention are of the general formulawherein:M is ruthenium or osmium;X and Xare each independently an anionic ligand;L is a neutral electron donor ligand; and,R, RR, R, R, and Rare each independently hydrogen or a substituent selected from the group consisting of C1-C20 alkyl, C2-C20 alkenyl, C2-C20 alkynyl, aryl, C1-C20 carboxylate, C1-C20 alkoxy, C2-C20 alkenyloxy, C2-C20 alkynyloxy, aryloxy, C2-C20 alkoxycarbonyl, C1-C20 alkylthio, C1-C20 alkylsulfonyl and C1-C20 alkylsulfinyl.

A newly-designed PE-supported arsine for efficient and practical catalytic Wittig olefination

A newly designed PE-supported arsine has been developed as an excellent catalyst for catalytic Wittig-type olefination. Simple ketones, in particular inactive ketones prove to be suitable substrates for the first time. This reaction provides an easy access to di-, tri-, and tetra-substituted olefins in high yield.