61470-34-6

Basic information

• Product Name: butyl 3-(trichlorostannyl)propionate
• Synonyms: butyl 3-(trichlorostannyl)propionate;3-(Trichlorostannyl)propanoic acid butyl ester;3-(Trichlorostannyl)propionic acid butyl ester;Einecs 262-808-1;Propanoic acid, 3-(trichlorostannyl)-, butyl ester
• CAS NO: 61470-34-6
• Molecular Formula: C₇H₁₃Cl₃O₂Sn
• Molecular Weight: 354.24592
• EINECS: 262-808-1
• Mol File: 61470-34-6.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 329.4°C at 760 mmHg
• Flash Point: 153°C
• Appearance: /
• Vapor Pressure: 0.000178mmHg at 25°C
• CAS DataBase Reference: butyl 3-(trichlorostannyl)propionate(CAS DataBase Reference)
• NIST Chemistry Reference: butyl 3-(trichlorostannyl)propionate(61470-34-6)
• EPA Substance Registry System: butyl 3-(trichlorostannyl)propionate(61470-34-6)

Safety Data

• Hazardous Substances Data: 61470-34-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C7H13O2.3ClH.Sn/c1-3-5-6-9-7(8)4-2;;;;/h2-6H2,1H3;3*1H;/q;;;;+3/p-3/rC7H13Cl3O2Sn/c1-2-3-5-12-7(11)4-6-13(8,9)10/h2-6H2,1H3

Upstream product

• 61470-33-5 (C₄H₉OCOCH₂CH₂)2SnCl₂ 
• 7646-78-8 tin(IV) chloride 
• 59586-13-9 methyl 3-(trichlorostannyl)propanoate 
• 71-36-3 butan-1-ol 
• 141-32-2 acrylic acid n-butyl ester 
• 7647-01-0 hydrogenchloride 
• 7440-31-5 tin 

Relevant articles and documents

The transesterification reaction of β-methoxycarbonylethyltin trichloride and its dimethylsulfoxide adduct with alcohols

The transesterification reaction of ss-methoxycarbonylethyltin trichloride and its dimethylsulfoxide adduct with alcohols is reported and the possible mechanism is suggested. A series of ss-alkoxycarbonylethyltin trichlorides and their dimethyl-sulfoxide adducts were synthesized and characterized by means of elemental analyses, IR and 1H NMR spectra and an X-ray single crystal diffraction study.

REDISTRIBUTION REACTIONS OF β-CARBOALKOXYETHYLTIN COMPOUNDS

Carboalkoxyethyltin compounds undergo redistribution reactions at faster rates than similar unsubstituted alkyltin compounds.In redistribution reactions between SnCl4 and carboalkoxyethyltin compounds stable intermolecular complexes are formed.Rate enhancement is explained in terms of intra- and intermolecular coordination effects.Where strong intermolecular coordination effects are observed, specific electrophilic cleavage of the carboalkoxyethyl group can occur in preference to alkyl cleavage in mixed carboalkoxyethylalkyltin compounds.The presence of a β-ester function can catalyse both alkyl/chlorine and alkyl/alkyl' exchange reactions.