61795-22-0

Basic information

• Product Name: Benzene, 1,1'-(1-azido-1,2-ethenediyl)bis-
• CAS NO: 61795-22-0
• Molecular Formula: C14H11N3
• Molecular Weight: 221.261
• Mol File: 61795-22-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1-azido-1,2-ethenediyl)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1-azido-1,2-ethenediyl)bis-(61795-22-0)
• EPA Substance Registry System: Benzene, 1,1'-(1-azido-1,2-ethenediyl)bis-(61795-22-0)

Safety Data

• Hazardous Substances Data: 61795-22-0(Hazardous Substances Data)

Upstream product

• 588-59-0 stilbene 
• 4098-15-1 (1-azido-2-iodoethane-1,2-diyl)dibenzene 
• 13440-24-9 1,2-dibromo-1,2-diphenylethane 
• 501-65-5 diphenyl acetylene 

Downstream Products

• 154669-95-1 3,3,3-trifluoro-1,2-diphenylpropan-1-one 
• 97195-28-3 N-(2-oxo-1,2-diphenylethyl)formamide 
• 5651-59-2 3,4-dihydro-1H-benzo[c]chromene-1,6(2H)-dione 
• 6318-74-7 2-amino-4,5-diphenylthiazole 
• 93325-15-6 2,5-diphenyl-pyrrole-3-carboxylic acid 
• 74065-55-7 2,5-diphenyl-pyrrole-3,4-dicarboxylic acid 
• 17799-61-0 3,4-dimethyl-2,5-diphenyl-1H-pyrrole 
• 67421-66-3 2,5-diphenyl-1H-pyrrole-3-carbonitrile 
• 85814-61-5 1-(2,5-diphenyl-1H-pyrrol-3-yl)ethanone 
• 65474-26-2 ethyl 2,5-diphenyl-1H-pyrrole-3-carboxylate 
• 13901-74-1 methyl 2,5-diphenyl-1H-pyrrole-3-carboxylate 
• 1629159-61-0 methyl 4-benzoyl-2,5-diphenyl-1H-pyrrole-3-carboxylate 
• 66092-09-9 diethyl 2,5-diphenyl-1H-pyrrole-3,4-dicarboxylate 
• 13901-70-7 dimethyl 2,5-diphenyl-1H-pyrrole-3,4-dicarboxylate 

Relevant articles and documents

Electrochemical Synthesis of O-Phthalimide Oximes from α-Azido Styrenes via Radical Sequence: Generation, Addition and Recombination of Imide-N-Oxyl and Iminyl Radicals with C?O/N?O Bonds Formation

Electrochemically induced radical-initiated reaction of vinyl azides with N-hydroxyphthalimide resulting O-phthalimide oximes with challenging for organic chemistry N?O-N fragment has been discovered. The developed approach introduces in synthesis electrochemically generated O-centered imide-N-oxyl radicals as the coupling components. Sequential formation of C?O and N?O bonds was achieved via generation and selective addition of imide-N-oxyl radicals, followed by recombination with iminyl radicals. A wide range of O-phthalimide oximes was obtained with the yields up to 84percent. (Figure presented.).

Self-Catalyzed Rapid Synthesis of N-Acylated/ N-Formylated α-Aminoketones and N-Hydroxymethylated Formamides from 3-Aryl-2 H-Azirines and 2-Me/Ph-3-Aryl-2 H-Azirines

A rapid and effective method has been established for the synthesis of N-acylated α-aminoketone derivatives by the reaction of 3-aryl-2H-azirines and highly substituted 2-Me/Ph-3-aryl-2H-azirines with various carboxylic acids under ambient air within 10 min at room temperature. N-Trifluoroacetylated α-aminoketones with different substituents have been reported in the presence of trifluoroacetic acid. This protocol is equally effective to synthesize N-formylated α-aminoketone and N-hydroxymethylated formamide derivatives.

Photoredox-catalysed redox-neutral trifluoromethylation of vinyl azides for the synthesis of α-trifluoromethylated ketones

A redox-neutral, mild, and simple protocol is developed for the synthesis of α-trifluoromethylated ketones from vinyl azides under transition-metal-free conditions. In the presence of organic photoredox catalyst N-methyl-9-mesityl acridinium and sodium trifluoromethanesulfinate, a broad range of substituted vinyl azides were found to react smoothly upon visible-light irradiation, readily furnishing the corresponding products in satisfied yields.