62499-16-5Relevant academic research and scientific papers
One-Pot Synthesis of Trisubstituted Triazenes from Grignard Reagents and Organic Azides
Suleymanov, Abdusalom A.,Scopelliti, Rosario,Fadaei Tirani, Farzaneh,Severin, Kay
supporting information, p. 3323 - 3326 (2018/06/11)
A simple and versatile method for the preparation of linear, trisubstituted triazenes is reported. The procedure is based on the reaction of Grignard reagents with 1-azido-4-iodobutane or 4-azidobutyl-4-methylbenzenesulfonate. These organic azides enable the regioselective formation of triazenes via an intramolecular cyclization step. The new method can be used for the preparation of aryl, heteroaryl, vinyl, and alkyl triazenes. The synthetic utility of vinyl triazenes is demonstrated by acid-induced C-N, C-O, C-F, C-P, and C-S bond-forming reactions.
General and efficient synthesis of indoles through triazene-directed c-h annulation
Wang, Chengming,Sun, Huan,Fang, Yan,Huang, Yong
supporting information, p. 5795 - 5798 (2013/06/27)
Unprotected indoles are prepared with the title method, which has a wide scope for alkynes. Excellent regioselectivity was accomplished for aryl-alkyl and alkyl-alkyl disubstituted acetylenes. This reaction features an unusual 1,2 rhodium migration and ring-contraction-triggered N-N bond cleavage. It allows rapid conversion of the reaction products into several functional molecules. Copyright
