62834-89-3

Basic information

• Product Name: 2-Propen-1-one, 2-methyl-1-(4-methylphenyl)-
• CAS NO: 62834-89-3
• Molecular Formula: C11H12O
• Molecular Weight: 160.216
• Mol File: 62834-89-3.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2-Propen-1-one, 2-methyl-1-(4-methylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propen-1-one, 2-methyl-1-(4-methylphenyl)-(62834-89-3)
• EPA Substance Registry System: 2-Propen-1-one, 2-methyl-1-(4-methylphenyl)-(62834-89-3)

Safety Data

• Hazardous Substances Data: 62834-89-3(Hazardous Substances Data)

Upstream product

• 874-60-2 4-methyl-benzoyl chloride 
• 124-38-9 carbon dioxide 
• 1450-08-4 (α-4-methylbenzoylethylidene)triphenylphosphorane 
• 67499-62-1 Tolperisone hydrochloride 
• 25574-04-3 1-p-tolyl-1-propanol 
• 100-97-0 hexamethylenetetramine 
• 5337-93-9 4'-methylpropiophenone 
• 106-38-7 para-bromotoluene 
• 92207-33-5 3-hydroxy-2-methyl-1-(p-tolyl)propan-1-one 
• 50-00-0 formaldehyd 
• 557-93-7 2-bromoprop-1-ene 
• 99-94-5 p-Toluic acid 

Downstream Products

• 116981-03-4 ((Z)-3-Iodo-2-methyl-1-p-tolyl-propenyloxy)-trimethyl-silane 
• 1226911-82-5 1-(4-methyl-phenyl)-2-methylallyl alcohol 
• 1629211-99-9 C₃₃H₄₂N₂O 
• 1629211-95-5 C₂₉H₃₄N₂O 
• 116981-08-9 (3-Iodomethyl-3,5-dimethyl-2,6-di-p-tolyl-3,4-dihydro-2H-pyran-2-yloxy)-trimethyl-silane 

Relevant articles and documents

Transition-Metal-Free Reductive Deoxygenative Olefination with CO2

A new transition-metal-free reductive deoxygenative olefination of phosphorus ylides with CO2, an abundant and sustainable C1 chemical feedstock, is described. This catalytic CO2 fixation afforded β-unsubstituted acrylates and vinyl ketones in good yields with broad scope and good functional group tolerance under mild reaction conditions. Cost-effective and easily handled polymethylhydrosiloxane was used as a reductant. Bis(silyl)acetal was proved to be the key intermediate in this reductive functionalization of CO2.

Supported Gold Nanoparticles for Efficient α-Oxygenation of Secondary and Tertiary Amines into Amides

Although the α-oxygenation of amines is a highly attractive method for the synthesis of amides, efficient catalysts suited to a wide range of secondary and tertiary alkyl amines using O2as the terminal oxidant have no precedent. This report describes a novel, green α-oxygenation of a wide range of linear and cyclic secondary and tertiary amines mediated by gold nanoparticles supported on alumina (Au/Al2O3). The observed catalysis was truly heterogeneous, and the catalyst could be reused. The present α-oxygenation utilizes O2as the terminal oxidant and water as the oxygen atom source of amides. The method generates water as the only theoretical by-product, which highlights the environmentally benign nature of the present reaction. Additionally, the present α-oxygenation provides a convenient method for the synthesis of18O-labeled amides using H218O as the oxygen source.

Synthesis of α-indanones via intramolecular direct arylation with cyclopropanol-derived homoenolates

A palladium-catalysed, tandem cyclopropanol rearrangement and direct arylation approach for the synthesis of 1-indanones is reported. The reaction is generally high yielding, uses oxygen as the terminal oxidant and tolerates a range of functional groups on the aryl ring.