6304-45-6Relevant articles and documents
Phosphine-free ruthenium complex-catalyzed synthesis of mono- Or dialkylated acyl hydrazides via the borrowing hydrogen strategy
Joly, Nicolas,Bettoni, Léo,Gaillard, Sylvain,Poater, Albert,Renaud, Jean-Luc
, p. 6813 - 6825 (2021/05/29)
Herein, we report a diaminocyclopentadienone ruthenium tricarbonyl complex-catalyzed synthesis of mono- or dialkylated acyl hydrazide compounds using the borrowing hydrogen strategy in the presence of various substituted primary and secondary alcohols as alkylating reagents. Deuterium labeling experiments confirm that the alcohols were the hydride source in this cascade process. Density functional theory (DFT) calculations unveil the origin and the threshold between the mono- and dialkylation.
Quantitative structure-antifungal activity relationships of some benzohydrazides against Botrytis cinerea
Reino, Jose L.,Saiz-Urra, Liane,Hernandez-Galan, Rosario,Aran, Vicente J.,Hitchcock, Peter B.,Hanson, James R.,Gonzalez, Maykel Perez,Collado, Isidro G.
, p. 5171 - 5179 (2008/02/12)
Fourteen benzohydrazides have been synthesized and evaluated for their in vitro antifungal activity against the phytopathogenic fungus Botrytis cinerea. The best antifungal activity was observed for the N′,N′- dibenzylbenzohydrazides 3b-d and for the N-am