635-67-6Relevant articles and documents
13C NMR Study of Derivatives of Dibenzobarrelene, Anthraquinone and Anthracene
Sieckmann, Ralf
, p. 264 - 266 (1991)
Carbon-13 chemical shifts of 22 derivatives of dibenzobarrelene, anthraquinone and anthracene are reported, each of which includes a symmetrical ortho-benzene moiety.The assignment of the chemical shifts of the aromatic carbons of these derivatives was achieved by correlation with the corresponding 13C chemical shifts of ortho-disubstituted benzenes.
4-Imidazol-1-yl-butane-1-sulfonic acid ionic liquid: Synthesis, structural analysis, physical properties and catalytic application as dual solvent-catalyst
Khaligh, Nader Ghaffari,Mihankhah, Taraneh,Johan, Mohd Rafie,Juan, Joon Ching
, p. 866 - 878 (2019/07/12)
4-Imidazol-1-yl-butane-1-sulfonic acid (ImBu-SO3H) has been successfully synthetized and fully characterized by FT-IR and high-resolution NMR spectroscopy (1H, 13C). The “plausible” alternative structures of ImBu-SO3H were discussed on the basis of its NMR data. The ionic liquid showed interesting dual solvent-catalyst property, which was studied experimentally for the acetylation of a variety of functionalized alcohols, phenols, thiols, amines and α-tocopherol (α-CTP) as the most active form of vitamin E with acetic anhydride and which provided good yields within a short reaction time. ImBu-SO3H was successfully recycled by product extraction with an average recovered yield of 82% for 5 subsequent runs. The catalytic activity of the recycled ImBu-SO3H showed almost no loss even after five consecutive runs.
Preparation method of aryl carboxylate compound based on alkenyl carboxylate ester exchange reaction
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Paragraph 0058; 0059; 0060, (2018/10/11)
The invention provides a preparation method of an aryl carboxylate compound based on alkenyl carboxylate ester exchange reaction and belongs to the technical field of pharmaceutical chemical intermediates and related chemistry. According to the method, phenol and alkenyl carboxylate are used as raw materials and green and efficient synthesis of the aryl carboxylate compound is realized under the catalysis effect of alkali. The method has the advantages of high selectivity, moderate reaction conditions, good functional group compatibility, wide substrate range, environment friendliness and thelike. The aryl carboxylate compound is an important organic synthetic intermediate and has very wide application in the fields of organic synthesis and pharmacology, so that the preparation method hasvery great application value and social economic benefits.