65469-88-7

Basic information

• Product Name: 1,3-Butanediol, 1-phenyl-
• CAS NO: 65469-88-7
• Molecular Formula: C10H14O2
• Molecular Weight: 166.22
• Mol File: 65469-88-7.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: 1,3-Butanediol, 1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Butanediol, 1-phenyl-(65469-88-7)
• EPA Substance Registry System: 1,3-Butanediol, 1-phenyl-(65469-88-7)

Safety Data

• Hazardous Substances Data: 65469-88-7(Hazardous Substances Data)

Usage

Type of compound

Diol

Structural feature

Phenyl group attached to the first carbon of the butanediol molecule

Industrial applications

Solvent
Chemical intermediate in the production of other chemicals

Pharmaceutical use

Intermediate in the synthesis of certain drugs

Personal care products

Used in formulation

Plastics and polymers

Used as a plasticizer in manufacturing

Safety

Relatively safe for use in applications, but proper handling and storage procedures should be followed

Upstream product

• 107-89-1 acetaldol 
• 16002-63-4 phenylmagnesium iodide 
• 100-52-7 benzaldehyde 
• 127-00-4 1-Chloro-2-propanol 
• 93-91-4 1-phenylbutan-1,3-dione 
• 13505-39-0 3-hydroxy-1-phenyl-butan-1-one 
• 1896-62-4 (E)-benzalacetone 
• 583037-48-3 6-methyl-4-phenyl-1,3-dioxan-2-on 
• 100-42-5 styrene 
• 80735-94-0 1-Phenyl-3-buten-1-ol 
• 195887-57-1 1,1-dibromo-2-dimethyl(vinyl)siloxy-2-phenylethane 
• 287411-54-5 [(4-(dimethyl-o-bromophenyl)silyloxy-butan-2-oxy)diphenylsilyl]trimethylsilane 
• 60-29-7 diethyl ether 
• 64-17-5 ethanol 

Downstream Products

• 34688-55-6 1,3-diacetoxy-1-phenyl-butane 
• 2344-70-9 1-phenyl-3-butanol 
• 59456-20-1 (rac)-(3-iodobutyl)benzeze 
• 40698-67-7 2,4-dimethyl-6-phenyl-1,3-dioxane 
• 98-85-1 1-Phenylethanol 
• 93-91-4 1-phenylbutan-1,3-dione 
• 13505-39-0 3-hydroxy-1-phenyl-butan-1-one 
• 81418-07-7 2,2-Di-tert-butyl-4-methyl-6-phenyl-[1,3,2]dioxasilinane 

Relevant articles and documents

Long-chain syn-1-phenylalkane-1,3-diyl diacetates, related phenylalkane derivatives, and sec-alcohols, all possessing dominantly iso-branched chain termini, and 2/3-methyl-branched fatty acids from Primula veris L. (Primulaceae) wax

Herein, the results of the first study of non-flavonoid constituents of aboveground surface-wax washings of Primula veris L. (Primulaceae) are presented. Chromatography of the washings yielded a minor fraction composed of n-, iso-, and anteiso-series of l

Photocatalysis with Quantum Dots and Visible Light: Selective and Efficient Oxidation of Alcohols to Carbonyl Compounds through a Radical Relay Process in Water

Selective oxidation of alcohols to aldehydes/ketones has been achieved with the help of 3-mercaptopropionic acid (MPA)-capped CdSe quantum dot (MPA-CdSe QD) and visible light. Visible-light-prompted electron-transfer reaction initiates the oxidation. The thiyl radical generated from the thiolate anion adsorbed on a CdSe QD plays a key role by abstracting the hydrogen atom from the C?H bond of the alcohol (R1CH(OH)R2). The reaction shows high efficiency, good functional group tolerance, and high site-selectivity in polyhydroxy compounds. The generality and selectivity reported here offer a new opportunity for further applications of QDs in organic transformations.

C-O hydrogenolysis catalyzed by Pd-PMHS nanoparticles in the company of chloroarenes

Catalytic Pd(OAc)2 and polymethylhydrosiloxane (PMHS), in conjunction with aqueous KF, and a catalytic amount of an aromatic chloride, effects the chemo-, regio-, and stereoselective deoxygenation of benzylic oxygenated substrates at room temperature in THF. Preliminary mechanistic experiments suggest the process to involve palladium-nanoparticle-catalyzed hydrosilylation followed by C-O reduction. The chloroarene additive appears to facilitate the hydrogenolysis process through the slow controlled release of HCl.