6553-72-6Relevant academic research and scientific papers
TEMPERATURE CONTROLLED SELECTIVITY IN METHYLCYCLOPENTANE CARBONYLATION IN HF-SbF5
Culmann, Jean-Christophe,Cherry, Ghassan,Jost, Roland,Sommer, Jean
, p. 701 - 704 (2007/10/02)
Protolytic ionization of methylcyclopentane in HF-SbF5, followed by carbonylation at atmospheric pressure yields either methyl cyclopentane- or cyclohexaneoxocarbenium ions depending on the reaction temperature.An example of kinetic versus thermodynamic control.
ETHOXYCARBONYLATION OF CYCLOHEXANOL BY ETHYL FORMATE UNDER CONDITIONS OF CATALYSIS BY SULFURIC ACID
Ordyan, M. B.,Stepanyan, A. A.,Pirozhkov, S. D.,Manukyan, Sh. M.,Grigoryan, V. S.,Lapidus, A. L.
, p. 2290 - 2292 (2007/10/02)
The catalytic ethoxycarbonylation of cyclohexanol by ethyl formate in the presence of concentrated sulfuric acid at 25-55 deg C and atmospheric pressure was investigated.The products are cyclohexanecarboxylic and 1-methyl-1-cyclopentanecarboxylic acid and their ethyl esters.A reaction mechanism is proposed.
