6907-68-2

Basic information

• Product Name: N-(acetamido-phenyl-methyl)acetamide
• Synonyms: N-(acetamido-phenyl-methyl)acetamide;N,N'-(Phenylmethylene)bis(acetamide);N-(ACETYLAMINOPHENYLMETHYL)ACETAMIDE
• CAS NO: 6907-68-2
• Molecular Formula: C₁₁H₁₄N₂O₂
• Molecular Weight: 206.2411
• Mol File: 6907-68-2.mol
• Article Data: 23

Chemical Properties

• Boiling Point: 510.3 °C at 760 mmHg
• Flash Point: 225 °C
• Appearance: /
• Density: 1.118 g/cm³
• CAS DataBase Reference: N-(acetamido-phenyl-methyl)acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(acetamido-phenyl-methyl)acetamide(6907-68-2)
• EPA Substance Registry System: N-(acetamido-phenyl-methyl)acetamide(6907-68-2)

Safety Data

• Hazardous Substances Data: 6907-68-2(Hazardous Substances Data)

Usage

General Description

N-(acetamido-phenyl-methyl)acetamide, also known as Acetamiprid, is a neonicotinoid insecticide used primarily in agriculture to control pests such as aphids, leafhoppers, and whiteflies. It works by disrupting the functioning of the central nervous system in insects, ultimately leading to paralysis and death. Acetamiprid is also used in commercial and residential settings for controlling pests such as ants, cockroaches, and bed bugs. However, there are concerns about its potential impact on non-target organisms, including bees and other beneficial insects, as well as its potential for environmental persistence and accumulation. Consequently, its use is regulated in many countries to minimize adverse effects on non-target organisms and the environment.

Upstream product

• 100-52-7 benzaldehyde 
• 75-05-8 acetonitrile 
• 100-51-6 benzyl alcohol 
• 30615-17-9 (n-C₃H₇)2BNHCOCH₃ 
• 1198-98-7 5-methyl-3-phenyl-1,2,4-oxadiazole 
• 108-24-7 acetic anhydride 
• 60-35-5 acetamide 
• 6425-08-7 4,4'-(phenylmethylene)bismorpholine 
• 10575-97-0 N-benzyl-N-nitrosoacetamide 
• 774-48-1 (diethoxymethyl)benzene 

Downstream Products

• 101579-72-0 N-[(1,4-diacetyl-3,6-dioxo-piperazin-2-yl)-phenyl-methyl]-acetamide 
• 93025-98-0 (α-acetylamino-benzyl)-malonic acid diethyl ester 
• 64489-97-0 N-(2,4,6-Trimethylbenzhydryl)-acetamid 
• 64489-96-9 N-(2,3,4,5,6-Pentamethylbenzhydryl)-acetamid 
• 39057-68-6 tert-butyl-(2-methyl-4-phenyl-oxazol-5-yl)-amine 
• 2046-08-4 5-(acetylamino-phenyl-methyl)-5-methyl-3-phenyl-2-thioxo-thiazolidin-4-one 
• 16684-63-2 2-benzylidene-1,1-dioxo-1,4-dihydro-2H-1λ⁶-benzo[1,4]thiazin-3-one 
• 16684-62-1 2-(acetylamino-phenyl-methyl)-1,1-dioxo-1,4-dihydro-2H-1λ⁶-benzo[1,4]thiazin-3-one 
• 100970-02-3 4-Nitro-2-<α-acetamino-benzyl>-phenol 
• 93406-74-7 4-Methoxy-3-<α-acetamino-benzyl>-toluol 
• 856329-45-8 5-(acetylamino-phenyl-methyl)-5-methyl-2-thioxo-thiazolidin-4-one 
• 100719-18-4 dimethyl 2-(acetylaminophenylmethyl)malonate 
• 5342-92-7 N-[(phenyl)(2-hydroxynaphthalen-1-yl)methyl]acetamide 
• 93406-68-9 N-(2-hydroxy-3,5-dimethyl-benzhydryl)-acetamide 

Relevant articles and documents

Gold nanoparticles deposited on MnO2 nanorods modified graphene oxide composite: A potential ternary nanocatalyst for efficient synthesis of betti bases and bisamides

The decoration of novel nanostructures such as nano particle and nanorod on the surface of graphene oxide (GO) generate potential heterogeneous nanocatalyst. Highlighting this, in the present work, we have designed a ternary GO-MnO2-Au nanocomposite by decorating MnO2nanorods on the surface of graphene oxide via hydrothermal method, followed by deposition of Au nanoparticles on GO-MnO2 surface. The prepared nanocomposite was thoroughly characterised by different instrumental techniques such as X-Ray diffraction (XRD),Fourier transform infrared spectroscopy (FTIR),Raman spectroscopy, Field emission scanning electron microscopy (FESEM), Transmission electron microscopy (TEM), High resolution Transmission electron microscopy (HRTEM), X-Ray photo electron spectroscopy (XPS), N2 adsorption desorption Brunauer–Emmett–Teller (BET) isotherm and Inductively coupled plasma - optical emission spectrometry (ICP-OES). FESEM and TEM images demonstrated that the MnO2 forms rod like structure having diameter of 60–100 nm and are uniformly distributed over the GO surface. HRTEM image clearly signifies gold (Au) nanoparticles having diameter of 7 ± 1.9 nm homogeneously distributed throughout the GO-MnO2 surface. Elementary state of Au and tetravalent nature of Mn as well as reduction of functional group after the decoration was confirmed from XPS studies. The catalyst GO-MnO2-Au was found to be the superior catalyst for synthesis of biologically active molecules such as Betti bases and Bisamides. The high catalytic activity of the materials can be attributed to the small and homogeneous distribution of gold nanoparticles, high redox potential of rod shaped MnO2 and the synergistic effect between GO, MnO2 and Au. All the reaction conditions were optimised by varying catalyst dosage, effect of solvent and temperature. The GO-MnO2-Au was easily recycled with minimal leaching and the product yield was found to be 85–90% after 4th cycle demonstrating the stability and durability of our nanocomposite.

Synthesis, characterization and application of nano-N,N,N′,N′-tetramethyl-N-(silica-n-propyl)-N′-sulfo-ethane-1,2-diaminium chloride as a highly efficient catalyst for the preparation of N,N′-alkylidene bisamides

Abstract: A novel mesoporous nanomaterial, namely nano-N,N,N′,N′-tetramethyl-N-(silica-n-propyl)-N′-sulfo-ethane-1,2-diaminium chloride (nano-[TSPSED][Cl]2), was prepared, and characterized using Fourier-transform infrared spectroscopy (FT-IR), energy-dispersive X-ray spectroscopy (EDS), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), adsorption/desorption porosimetry (BET, Langmuir, BJH and adsorption/desorption isotherm), thermal gravimetric (TG), differential thermal gravimetric (DTG) and X-ray diffraction (XRD) analyses. Afterward, nano-[TSPSED][Cl]2 was used as a highly efficient and recyclable nanocatalyst for the condensation reaction of primary amides (2 eq.) with arylaldehydes (1 eq.) under solvent-free conditions to afford N,N′-alkylidene bisamides in high yields and in short times. Graphical abstract: [Figure not available: see fulltext.].

Ultrasound-promoted synthesis of symmetrical bisamides by reaction between aromatic aldehydes and amides catalysed by p-toluenesulfonic acid

Reaction between aldehydes and amides catalysed by p-toluenesulfonic acid (p-TSA), under ultrasound irradiation and ambient conditions, gives symmetrical bisamide derivatives in excellent yield and in short time.