6973-73-5

Basic information

• Product Name: bis(acetyloxy)(4-chlorophenyl)-lambda~3~-iodane
• Synonyms: Diacetoxy(4-chlorophenyl)-lambda~3~-iodane; iodine, bis(acetyloxy)(4-chlorophenyl)-
• CAS NO: 6973-73-5
• Molecular Formula: C₁₀H₁₀ClIO₄
• Molecular Weight: 356.5415
• Mol File: 6973-73-5.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: bis(acetyloxy)(4-chlorophenyl)-lambda~3~-iodane(CAS DataBase Reference)
• NIST Chemistry Reference: bis(acetyloxy)(4-chlorophenyl)-lambda~3~-iodane(6973-73-5)
• EPA Substance Registry System: bis(acetyloxy)(4-chlorophenyl)-lambda~3~-iodane(6973-73-5)

Safety Data

• Hazardous Substances Data: 6973-73-5(Hazardous Substances Data)

Upstream product

• 79-21-0 peracetic acid 
• 637-87-6 1-Chloro-4-iodobenzene 
• 108-24-7 acetic anhydride 
• 64-19-7 acetic acid 
• 127-09-3 sodium acetate 
• 108-90-7 chlorobenzene 

Downstream Products

• 51571-28-9 4-[bis(trifluoroacetoxy)iodo]-1-chlororobenzene 
• 637-87-6 1-Chloro-4-iodobenzene 
• 64-19-7 acetic acid 
• 490-83-5 L-dehydroascorbic acid 
• 59696-00-3 (4-chlorophenyl)(4-fluorophenyl)iodonium chloride 
• 1382354-96-2 (2-(2-(t-butoxycarbonylamino)ethyl)phenyl)(4-chlorophenyl)iodonium p-toluenesulfonate 
• 1382355-06-7 (2-(2-(benzyloxycarbonylamino)ethyl)phenyl)(4-chlorophenyl)iodonium p-toluenesulfonate 
• 1382355-16-9 (2-(2-acetamidoethyl)phenyl)(4-chlorophenyl)iodonium p-toluenesulfonate 
• 1382355-26-1 (2-(2-(3,3-diethylureido)ethyl)phenyl)(4-chlorophenyl)iodonium p-toluenesulfonate 
• 73178-07-1 -p-chlorobenzene 

Relevant articles and documents

Preparation and Synthetic Applicability of Imidazole-Containing Cyclic Iodonium Salts

A novel approach to the preparation of imidazole-substituted cyclic iodonium salts has been developed via the oxidative cyclization of 1-phenyl-5-iodoimidazole using a cheap and available Oxone/H2SO4 oxidative system. The structure of the new polycyclic heteroarenes has been confirmed by single-crystal X-ray diffractometry, revealing the characteristic structure features for cyclic iodonium salts. The newly produced imidazole-flanked cyclic iodonium compounds were found to readily engage in a heterocyclization reaction with elemental sulfur, affording benzo[5,1-b]imidazothiazoles in good yields.

Synthesis of O -Aroyl- N, N -dimethylhydroxylamines through Hypervalent Iodine-Mediated Amination of Carboxylic Acids with N, N -Dimethylformamide

An efficient protocol for the synthesis of O -aroyl- N, N -dimethylhydroxylamines, which are important electrophilic amination reagents, is described. The reaction between carboxylic acids and N, N -dimethylformamide is mediated by hypervalent iodine and

Tandem catalytic C(sp3)-H amination/sila-sonogashira-hagihara coupling reactions with iodine reagents

A new tandem C-N and C-C bond-forming reaction has been achieved through RhII/Pd0 catalysis. The sequence first involves an iodine(III) oxidant, then the in situ generated iodine(I) by-product is used as a coupling partner. The overall process demonstrates the synthetic value of iodoarenes produced in trivalent iodine reagent mediated oxidations. I(003) is a double agent: A tandem C-N and C-C bond-forming reaction has been achieved through RhII/Pd0 catalysis. The sequence first involves an iodine(III) oxidant, then the in situ generated iodine(I) by-product is used as a coupling partner. The overall process affords complex building blocks with high yields, and demonstrates the synthetic value of iodoarenes produced in trivalent iodine reagent mediated oxidations.