110320-68-8

Basic information

• Product Name: methyl 2-benzyloxyhexanoate
• Synonyms: methyl 2-benzyloxyhexanoate
• CAS NO: 110320-68-8
• Molecular Weight: 236.311
• Mol File: 110320-68-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 2-benzyloxyhexanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-benzyloxyhexanoate(110320-68-8)
• EPA Substance Registry System: methyl 2-benzyloxyhexanoate(110320-68-8)

Safety Data

• Hazardous Substances Data: 110320-68-8(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 616-05-7 2-bromohexanoic acid 
• 20194-18-7 sodium phenyl-methanolate 
• 68756-64-9 2-hydroxyhexanoic acid methyl ester 
• 100-39-0 benzyl bromide 
• 636-36-2 rac-2-hydroxyhexanoic acid 

Downstream Products

• 6920-22-5 (2S)-hexane-1,2-diol 
• 66832-04-0 methyl 6-benzyloxy-5-hydroxy-3-oxodecanoate 
• 54620-78-9 6-(1'-benzyloxypentyl)-5,6-dihydro-4-methoxypyran-2-one 
• 136850-73-2 6-(1'-benzyloxypentyl)-5,6-dihydropyran-2,4(3H)-dione 
• 106225-84-7 2-(1'-benzyloxypentyl)-2,3-dihydro-6-methoxypyran-4-one 
• 54620-78-9 6-(1'-benzyloxypentyl)-5,6-dihydro-4-methoxypyran-2-one 
• 70326-39-5 α-benzyloxyhexanal 
• 141554-36-1 2-(benzyloxy)hexan-1-ol 
• 110352-59-5 methyl (S)-2-benzyloxyhexanoate 

Relevant articles and documents

High Diastereoselection in the Aldol Reaction of the Bistrimethylsilyl Enol Ether of Methyl Acetoacetate with 2-Benzyloxyhexanal: Synthesis of (-)-Pestalotin

Aldol condensation of the bistrimethylsilyl enol ether of methyl acetoacetate, compound 2, with 2-benzyloxyhexanal 3c affords highly selectively (99:1) the syn-aldol adduct 4c in the presence of titanium tetrachloride.The stereocontrolled synthesis of (-)-pestalotin 7 has been achieved.